Ghoniem, A.F. (2011) Needs, resources and climate change: clean and efficient conversion technologies. Prog. Energy Combust. Sci., 37(1), 15-51.
International Partnership for Hydrogen and Fuel Cells in the Economy (2016) IPHE Communiqué: Hydrogen and Fuel Cells: A Clean, Real, and Global Opportunity. Available at http://www.iphe.net/docs/Communique%202015-12-01%20Final.pdf (accessed 30, May 2016).
Vielstich, W., Lamm, A., and Gasteiger, H.A. (2003) Handbook of Fuel Cells, vol. 1-4, John Wiley & Sons, Ltd, Chichester.
Gasteiger, H.A., Vielstich, W., and Yokokawa, H. (2009) Handbook of Fuel Cells, vol. 5-6, John Wiley & Sons, Ltd, Chichester.
Dubau, L., Castanheira, L., Chatenet, M., Maillard, F., Dillet, J., Maranzana, G., Abbou, S., Lottin, O., De Moor, G., El Kaddouri, A., Bas, C., Flandin, L., Rossinot, E., and Caqué, N. (2014) Carbon corrosion induced by membrane failure: the weak link of PEMFC long-term performance. Int. J. Hydrogen Energy, 39(36), 21902-21914.
Dubau, L., Castanheira, L., Maillard, F., Chatenet, M., Lottin, O., Maranzana, G., Dillet, J., Lamibrac, A., Perrin, J.C., Moukheiber, E., Elkaddouri, A., De Moor, G., Bas, C., Flandin, L., and Caqué, N. (2014) A review of PEM fuel cell durability: materials degradation, local heterogeneities of aging and possible mitigation strategies. WIREs Energy Environ., 3, 540-560.
Cleghorn, S.J.C., Mayfield, D.K., Moore, D.A., Moore, J.C., Rusch, G., Sherman, T.W., Sisofo, N.T., and Beuscher, U. (2006) A polymer electrolyte fuel cell life test: 3 years of continuous operation. J. Power Sources, 158(1), 446-454.
Yu, E.H., Wang, X., Krewer, U., Li, L., and Scott, K. (2012) Direct oxidation alkaline fuel cells: from materials to systems. Energy Environ. Sci., 5(2), 5668-5680.
Demirci, U.B. (2007) Direct liquid-feed fuel cells: thermodynamic and environmental concerns. J. Power Sources, 169(2), 239-246.
Demirci, U.B., Miele, P., and Garin, F. (2011) Catalysis in hydrolysis of sodium borohydride and ammonia borane, and electrocatalysis in oxidation of sodium borohydride. Catal. Today, 170(1), 1-2.
Pecsok, R.L. (1953) Polarographic studies on the oxidation and hydrolysis of sodium borohydride. J. Am. Chem. Soc, 75, 2862-2864.
Gardiner, J.A. and Collat, J.W. (1965) Kinetics of the stepwise hydrolysis of tetrahydroborate ion. J. Am. Chem. Soc., 87, 1692.
Mochalov, K.N., Khain, V.S., and Gilmansh, G. (1965) A generalized scheme for hydrolysis of borohydride ion and diborane. Dokl. Akad. Nauk SSSR, 162(3), 613.
Morris, J.H., Gysling, H.J., and Reed, D. (1985) Electrochemistry of boron compounds. Chem. Rev., 85, 51.
Kreevoy, M.M. and Jacobson, R.W. (1979) The rate of decomposition of sodium borohydride in basic aqueous solutions. Ventron Alembic, 15,2-3.
Li, Z.P., Liu, B.H., Arai, K., Asaba, K., and Suda, S. (2004) Evaluation of alkaline borohydride solutions as the fuel for fuel cell. J. Power Sources, 126 (1-2), 28-33.
Ponce de Leon, C. and Walsh, F.C. (2015) Direct and indirect borohydride fuel cells, in Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier.
Hua, D., Hanxi, Y., Xinping, A., and Chuansin, C. (2003) Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst. Int. J. Hydrogen Energy, 28(10), 1095-1100.
Wu, C., Zhang, H., and Yi, B. (2004) Hydrogen generation from catalytic hydrolysis of sodium borohydride for proton exchange membrane fuel cells. Catal. Today, 93-95, 477-483.
Amendola, S.C., Onnerud, P., Kelly, M.T., Petillo, P.J., Sharp-Goldman, S.L., and Binder, M. (1999) A novel high power density borohydride-air cell. J. Power Sources, 84(1), 130-133.
Miley, G.H., Luo, N., Mather, J., Burton, R., Hawkins, G., Gu, L., Byrd, E., Gimlin, R., Shrestha, P.J., Benavides, G., Laystrom, J., and Carroll, D. (2007) Direct NaBH4/H2O2 fuel cells. J. Power Sources, 165(2), 509-516.
Ponce de León, C., Walsh, F.C., Rose, A., Lakeman, J.B., Browning, D.J., and Reeve, R.W. (2007) A direct borohydride-acid peroxide fuel cell. J. Power Sources, 164(2), 441-448.
Urian, R.C. (2010) Air independent fuel cells utilizing borohydride and hydrogen peroxide. Paper presented at the Materials Research Society Symposium Proceedings.
de Vooys, A.C.A., Koper, M.T.M., van Santen, R.A., and van Veen, J.A.R. (2001) The role of adsorbates in the electrochemical oxidation of ammonia on noble and transition metal electrodes. J. Electroanal. Chem., 506(2), 127-137.
Vidal-Iglesias, F.J., Solla-Gullón, J., Feliu, J.M., Baltruschat, H., and Aldaz, A. (2006) DEMS study of ammonia oxidation on platinum basal planes. J. Electroanal. Chem., 588(2), 331-338.
Rosca, V., Duca, M., DeGroot, M.T., and Koper, M.T.M. (2009) Nitrogen cycle electrocatalysis. Chem. Rev., 109(6), 2209-2244.
Nagle, L.C. and Rohan, J.F. (2006) Ammonia borane oxidation at gold microelectrodes in alkaline solutions. J. Electrochem. Soc., 153(11), C773-C776.
Demirci, U.B. (2015) The hydrogen cycle with the hydrolysis of sodium borohydride: a statistical approach for highlighting the scientific/technical issues to prioritize in the field. Int. J. Hydrogen Energy, 40(6), 2673-2691.
Li, Z.P., Liu, B.H., Morigasaki, N., and Suda, S. (2003) Preparation of potassium borohydride by a mechano-chemical reaction of saline hydrides with dehydrated borate through ball milling. J. Alloys Compd., 354 (1-2), 243-247.
Schlesinger, H.I., Brown, H.C., and Finholt, A.E. (1953) The preparation of sodium borohydride by the high temperature reaction of sodium hydride with borate esters. J. Am. Chem. Soc., 75(1), 205-209.
Schubert, F. and Lang, K. (1960) Neue wege zur herstellung von natriumboranat und dessen verwendung. Angew. Chem., 72(24), 994-1000.
Cloutier, C.R., Alfantazi, A., and Gyenge, E. (2007) Physicochemical properties of alkaline aqueous sodium metaborate solutions. J. Fuel Cell Sci. Tech., 4(1), 88-98.
Serov,A.,Aziznia,A.,Benhangi,P.H.,Artyushkova,K.,Atanassov,P.,andGyenge, E. (2013) Borohydride-tolerant oxygen electroreduction catalyst for mixed-reactant Swiss-roll direct borohydride fuel cells. J. Mater. Chem. A, 1(45), 14384-14391.
Aziznia, A., Oloman, C.W., and Gyenge, E.L. (2014) Experimental advances and preliminary mathematical modeling of the Swiss-roll mixed-reactant direct borohydride fuel cell. J. Power Sources, 265, 201-213.
Wang, A. and Gyenge, E.L. (2015) Borohydride electro-oxidation in a molten alkali hydroxide eutectic mixture and a novel borohydride-periodate battery. J. Power Sources, 282, 169-173.
Suda, S. (2003) Aqueous borohydride solutions, in Handbook of Fuel Cells Fundamentals, Technology and Applications, vol. 3 (eds W. Vielstich, H.A. Gasteiger, and A. Lamm), John Wiley & Sons, Ltd, Chichester, pp. 115-120.
Jamard, R., Latour, A., Salomon, J., Capron, P., and Martinent-Beaumont, A. (2008) Study of fuel efficiency in a direct borohydride fuel cell. J. Power Sources, 176(1), 287-292.
Chatenet, M., Lima, F.H.B., and Ticianelli, E.A. (2010) Gold is not a Faradaic- efficient borohydride oxidation electrocatalyst: an online electrochemical mass spectrometry study. J. Electrochem. Soc., 157(5), B697-B704.
Krishnan, P., Yang, T.-H., Advani, S.G., and Prasad, A.K. (2008) Rotating ring- disc electrode investigation of borohydride electro-oxidation. J. Power Sources, 182(1), 106-111.
Finkelstein, D.A., Mota, N.D., Cohen, J.L., and Abruña, H.D. (2009) Rotating disk electrode investigation of BH4 and BH3OH electro-oxidation at Pt and Au: implications for BH4 fuel cells. J. Phys. Chem. C, 113(45), 19700-19712.
Lima, F.H.B., Pasqualeti, A.M., Molina Concha, M.B., Chatenet, M., and Ticianelli, E.A. (2012) Borohydride electrooxidation on Au and Pt electrodes. Electrochim. Acta, 84, 202-212.
Pasqualeti, A.M., Olu, P.-Y., Chatenet, M., and Lima, F.H.B. (2015) Borohydride electrooxidation on carbon-supported noble metal nanoparticles: insights into hydrogen and hydroxyborane formation. ACS Catalysis, 5(5), 2778-2787.
Simões, M., Baranton, S., and Coutanceau, C. (2009) Electrooxidation of sodium borohydride at Pd, An, and PdxAu1-x carbon-supported nanocatalysts. J. Phys. Chem. C, 113(30), 13369-13376.
Simões, M., Baranton, S., and Coutanceau, C. (2010) Infiuence of bismuth on the structure and activity of Pt and Pd nanocatalysts for the direct electrooxidation of NaBH4. Electrochim. Acta, 56(1), 580-591.
Olu, P.-Y., Deschamps, F., Caldarella, G., Chatenet, M., and Job, N. (2015) Investigation of platinum and palladium as potential anodic catalysts for direct borohydride and ammonia borane fuel cells. J. Power Sources, 297, 492-503.
Merino-Jimenez, I., Leon, C.P.D., and Walsh, F.C. (2014) The effect of surfactants on the kinetics of borohydride oxidation and hydrolysis in the DBFC. Electrochim. Acta, 133, 539-545.
Tegou, A., Armyanov, S., Valova, E., Steenhaut, O., Hubin, A., Kokkinidis, G., and Sotiropoulos, S. (2009) Mixed platinum-gold electrocatalysts for borohydride oxidation prepared by the galvanic replacement of nickel deposits. J. Electroanal. Chem., 634(2), 104-110.
Chatenet, M., Micoud, F., Roche, I., and Chainet, E. (2006) Kinetics of sodium borohydride direct oxidation and oxygen reduction in sodium hydroxide electrolyte, Part I. BH4 electro-oxidation on Au and Ag catalysts. Electrochim. Acta, 51(25), 5459-5467.
Yi, L., Wei, W., Zhao, C., Tian, L., Liu, J., and Wang, X. (2015) Enhanced activity of Au-Fe/C anodic electrocatalyst for direct borohydride-hydrogen peroxide fuel cell. J. Power Sources, 285, 325-333.
Geng, X., Zhang, H., Ma, Y., and Zhong, H. (2010) Borohydride electrochemical oxidation on carbon-supported Pt-modified Au nanoparticles. J. Power Sources, 195(6), 1583-1588.
Couturier, G., Kirk, D.W., Hyde, P.J., and Srinivasan, S. (1987) Electrocatalysis of the hydrogen oxidation and of the oxygen reduction reactions of Pt and some alloys in alkaline medium. Electrochim. Acta, 32(7), 995-1005.
Olu P.-Y., Job N, Chatenet M. (2016) Evaluation of anode (electro)catalytic materials for the direct borohydride fuel cell: Methods and benchmarks. J Power Sources 327, 235-257.
Olu, P.-Y., Gilles, B., Job, N., and Chatenet, M. (2014) Infiuence of the surface morphology of smooth platinum electrodes for the sodium borohydride oxidation reaction. Electrochem. Commun., 43,47-50.
Briega-Martos, V., Herrero, E., and Feliu, J.M. (2015) Borohydride electro-oxidation on Pt single crystal electrodes. Electrochem. Commun., 51, 144-147.
Finkelstein, D.A., Letcher, C.D., Jones, D.J., Sandberg, L.M.,Watts, D.J., and Abruña, H.D. (2013) Self-poisoning during BH4 oxidation at Pt and Au, and in situ poison removal procedures for BH4 fuel cells. J. Phys. Chem. C, 117(4), 1571-1581.
Olu, P.-Y., Barros, C., Job, N., and Chatenet, M. (2014) Electrooxidation of NaBH4 in alkaline medium on well-defined Pt nanoparticles deposited onto fiat glassy carbon substrate: evaluation of the effects of Pt nanoparticle size, inter-particle distance, and loading. Electrocatalysis, 5(3), 288-300.
Molina Concha, B., Chatenet, M., Ticianelli, E.A., and Lima, F.H.B. (2011) In situ infrared study of the mechanism of the borohydride oxidation reaction on smooth Pt electrode. J. Phys. Chem. C, 115(25), 12439-12447.
Rostamikia, G. and Janik, M.J. (2010) First principles mechanistic study of borohydride oxidation over the Pt(111) surface. Electrochim. Acta, 55, 1175-1183.
Lam, V.W.S., Kannangara, D.C.W., Alfantazi, A., and Gyenge, E.L. (2011) Electrochemical quartz crystal microbalance study of borohydride electro-oxidation on Pt: the effect of borohydride concentration and thiourea adsorption. J. Phys. Chem. C, 115(6), 2727-2737.
Rostamikia, G., Mendoza, A.J., Hickner, M.A., and Janik, M.J. (2011) First- principles based microkinetic modeling of borohydride oxidation on a Au(111) electrode. J. Power Sources, 196(22), 9228-9237.
Escaño, M.C.S., Arevalo, R.L., Gyenge, E., and Kasai, H. (2014) Electrocatalysis of borohydride oxidation: a review of density functional theory approach combined with experimental validation. J. Phys-Condens. Mat., 26(35), 353001.
Olu, P.-Y., Bonnefont, A., Rouhet, M., Bozdech, S., Job, N., Chatenet, M., and Savinova, E. (2015) Insights into the potential dependence of the borohydride electrooxidation reaction mechanism on platinum nanoparticles supported on ordered carbon nanomaterials. Electrochim. Acta, 179, 637-646.
Molina Concha, B., Chatenet, M., Coutanceau, C., and Hahn, F. (2009) In situ infrared study of the borohydride oxidation reaction. Electrochem. Commun., 11 (1), 223-226.
Molina Concha, B., Chatenet, M., Maillard, F., Ticianelli, E.A., Lima, F.H.B., and de Lima, R.B. (2010) In situ infrared study of the mechanism of the borohydride oxidation reaction. Phys. Chem. Chem. Phys., 12(37), 11507-11516.
Jusys, Z. and Behm, R.J. (2015) Borohydride electrooxidation over Pt/C, AuPt/C and Au/C catalysts: partial reaction pathways and mixed potential formation. Electrochem. Commun., 60,9-12.
Molina Concha, B. and Chatenet, M. (2009) Direct oxidation of sodium borohydride on Pt, Ag and alloyed Pt-Ag electrodes in basic media. Part I: bulk electrodes. Electrochim. Acta, 54, 6119-6129.
Molina Concha, B. and Chatenet, M. (2009) Direct oxidation of sodium borohydride on Pt,Ag and alloyed Pt-Ag electrodes in basic media. Part II: carbon supported nanoparticles. Electrochim. Acta, 54, 6130-6139.
Gyenge, E., Atwan, M., and Northwood, D. (2006) Electrocatalysis of borohydride oxidation on colloidal Pt and Pt-alloys (Pt-Ir, Pt-Ni, and Pt-Au) and application for direct borohydride fuel cell anodes. J. Electrochem. Soc., 153(1), A150-A158.
Martins, J.I., Nunes, M.C., Koch, R., Martins, L., and Bazzaoui, M. (2007) Electrochemical oxidation of borohydride on platinum electrodes: the infiuence of thiourea in direct fuel cells. Electrochim. Acta, 52(23), 6443-6449.
Martins, J.I. and Nunes, M.C. (2008) Comparison of the electrochemical oxidation of borohydride and dimethylamine borane on platinum electrodes: implication for direct fuel cells. J. Power Sources, 175(1), 244-249.
Gyenge, E. (2004) Electrooxidation of borohydride on platinum and gold electrodes: implications for direct borohydride fuel cells. Electrochim. Acta, 49(6), 965-978.
Freitas, K.S., Molina Concha, B., Ticianelli, E.A., and Chatenet, M. (2011) Mass transport effects in the borohydride oxidation reaction: infiuence of the residence time on the reaction onset and Faradaic efficiency. Catal. Today, 170 (1), 110-119.
Chatenet,M.,Molina Concha,M.B., El-Kissi, N., Parrour, G., and Diard, J.-P. (2009) Direct rotating ring-disk measurement of the sodium borohydride diffusion coefficient in sodium hydroxide solutions. Electrochim. Acta, 54(18), 4426-4435.
Parrour, G., Chatenet, M., and Diard, J.-P. (2010) Electrochemical impedance spectroscopy study of borohydride oxidation reaction on gold: towards a EE mechanism. Electrochim. Acta, 55, 9113-9124.
Oliveira, V.L., Sibert, E., Soldo-Olivier, Y., Ticianelli, E.A., and Chatenet, M. (2016) Borohydride electrooxidation reaction on Pt(111) and Pt(111) modified by a pseudomorphic Pd monolayer. Electrochim. Acta, 190, 790-796.
Liu, B.H., Li, Z.P., Arai, K., and Suda, S. (2005) Performance improvement of a micro borohydride fuel cell operating at ambient conditions. Electrochim. Acta, 50(18), 3719-3725.
Cheng, H. and Scott, K. (2006) Investigation of Ti mesh-supported anodes for direct borohydride fuel cells. J. Appl. Electrochem., 36(12), 1361-1366.
Cheng, H. and Scott, K. (2006) Infiuence of operation conditions on direct borohydride fuel cell performance. J. Power Sources, 160(1), 407-412.
Nagle, L.C. and Rohan, J.F. (2005) Investigation of DMAB oxidation at a gold microelectrode in base. Electrochem. Solid State Lett., 8(5), C77-C80.
Molina Concha, B.M., Chatenet, M., Lima, F.H.B., and Ticianelli, E.A. (2013) In situ Fourier transform infrared spectroscopy and on-line differential electrochemical mass spectrometry study of the NH3BH3 oxidation reaction on gold electrodes. Electrochim. Acta, 89, 607-615.
Homma, T., Tamaki, A., Nakai, H., and Osaka, T. (2003) Molecular orbital study on the reaction process of dimethylamine borane as a reductant for electroless deposition. J. Electroanal. Chem., 559, 131-136.
Oliveira, V.L., Sibert, E., Soldo-Olivier, Y., Ticianelli, E.A., and Chatenet, M. (2016) Investigation of the electrochemical oxidation reaction of the borohydride anion in palladium layers on Pt(111) Electrochim. Acta., 209, 360-368.
Kim, C., Kim, K.-J., and Ha, M.Y. (2008) Performance enhancement of a direct borohydride fuel cell in practical running conditions. J. Power Sources, 180(1), 154-161.
Merino-Jiménez, I., Ponce De León, C., Shah, A.A., and Walsh, F.C. (2012) Developments in direct borohydride fuel cells and remaining challenges. J. Power Sources, 219, 339-357.
Boyaci San, F.G., Okur, O., Iyigün Karadag ,E. , T., Isik-Gulsac, I., and Okumus (2014) Evaluation of operating conditions on DBFC performance with PtRu anode catalyst by response surface method. Energy, 71, 160-169.
Li, G.R., Wang, Q.Q., Liu, B.H., and Li, Z.P. (2015) Porous carbon as anode catalyst support to improve borohydride utilization in a direct borohydride fuel cell. Fuel Cells, 15(2), 270-277.
Geng, X., Zhang, H., Ye, W., Ma, Y., and Zhong, H. (2008) Ni-Pt/C as anode electrocatalyst for a direct borohydride fuel cell. J. Power Sources, 185(2), 627-632.
Jamard, R., Salomon, J., Martinent-Beaumont, A., and Coutanceau, C. (2009) Life time test in direct borohydride fuel cell system. J. Power Sources, 193(2), 779-787.
Li, Z.P., Liu, B.H., Zhu, J.K., and Suda, S. (2006) Depression of hydrogen evolution during operation of a direct borohydride fuel cell. J. Power Sources, 163(1), 555-559.
Park, K.T., Jung, U.H., Jeong, S.U., and Kim, S.H. (2006) Infiuence of anode diffusion layer properties on performance of direct borohydride fuel cell. J. Power Sources, 162(1), 192-197.
Chen, D., Yu, S., Liu, X., and Li, X. (2015) Porous polybenzimidazole membranes with excellent chemical stability and ion conductivity for direct borohydride fuel cells. J. Power Sources, 282, 323-327.
Duteanu, N., Vlachogiannopoulos, G., Shivhare, M., Yu, E., and Scott, K. (2007) A parametric study of a platinum ruthenium anode in a direct borohydride fuel cell. J. Appl. Electrochem., 37(9), 1085-1091.
Ma, J., Sahai, Y., and Buchheit, R.G. (2012) Evaluation of multivalent phosphate cross-linked chitosan biopolymer membrane for direct borohydride fuel cells. J. Power Sources, 202,18-27.
Choudhury, N.A., Ma, J., and Sahai, Y. (2012) High performance and eco-friendly chitosan hydrogel membrane electrolytes for direct borohydride fuel cells. J. Power Sources, 210, 358-365.
Yang, X., Liu, Y., Li, S., Wei, X., Wang, L., and Chen, Y. (2012) A direct borohydride fuel cell with a polymer fiber membrane and non-noble metal catalysts. Sci. Rep., 2,1-5.
Qin, H., Lao, S., Liu, Z., Zhu, J., and Li, Z. (2010) Effects of heat treatment on the structure, morphology and electrocatalytic activity of cobalt hydroxide electrocatalyst. Int. J. Hydrogen Energy, 35(5), 1872-1878.
Zadick, A., Dubau, L., Chatenet, M., Demirci, U., Serov, A., and Atanassov, P. (2015) Instability of commercial Pt/C and Pd/C electrocatalysts in alkaline media. ECS Transactions, 69(17), 553-558.
Zadick, A., Dubau, L., Sergent, N., Berthomé, G., and Chatenet, M. (2015) Huge instability of Pt/C catalysts in alkaline medium. ACS Catal., 5(8), 4819-4824.
Zadick A, Dubau L, Demirci UB, Chatenet M. (2016) Effects of Pd Nanoparticle Size and Solution Reducer Strength on Pd/C Electrocatalyst Stability in Alkaline Electrolyte. J Electrochem Soc, 163(8), F781-F787.
