Positive trends in Southern Hemisphere carbonyl sulfide

Kremser, Stefanie; Jones, Nicholas B.; Palm, Mathias; Lejeune, Bernard; Wang, Yuting; Smale, Dan; Deutscher, Nicholas M.

doi:10.1002/2015GL065879

Download

Article (Scientific journals)

Positive trends in Southern Hemisphere carbonyl sulfide

Kremser, Stefanie; Jones, Nicholas B.; Palm, Mathias et al.

2015 • In Geophysical Research Letters, 42, p. 9473-9480

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/2268/196664

DOI
10.1002/2015GL065879

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

2015_11_Kremser_al_GRL.pdf

Publisher postprint (704.15 kB)

Download

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

carbonyl sulfide; trends; ground-based measurements

Abstract :

[en] Transport of carbonyl sulfide (OCS) from the troposphere to the stratosphere contributes sulfur to the stratospheric aerosol layer, which reflects incoming short-wave solar radiation, cooling the climate system. Previous analyses of OCS observations have shown no significant trend, suggesting that OCS is unlikely to be a major contributor to the reported increases in stratospheric aerosol loading and indicating a balanced OCS budget. Here we present analyses of ground-based Fourier transform spectrometer measurements of OCS at three Southern Hemisphere sites spanning 34.45°S to 77.80°S. At all three sites statistically significant positive trends are seen from 2001 to 2014 with an observed overall trend in total column OCS at Wollongong of 0.73 ± 0.03%/yr, at Lauder of 0.43 ± 0.02%/yr, and at Arrival Heights of 0.45 ± 0.05%/yr. These observed trends in OCS imply that the OCS budget is not balanced and could contribute to constraints on current estimates of sources and sinks.

Disciplines :

Earth sciences & physical geography

Author, co-author :

Kremser, Stefanie

Jones, Nicholas B.

Palm, Mathias

Lejeune, Bernard ; Université de Liège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)

Wang, Yuting

Smale, Dan

Deutscher, Nicholas M.

Language :

English

Title :

Positive trends in Southern Hemisphere carbonyl sulfide

Publication date :

06 November 2015

Journal title :

Geophysical Research Letters

ISSN :

0094-8276

eISSN :

1944-8007

Publisher :

American Geophysical Union, Washington, United States - District of Columbia

Volume :

Pages :

9473-9480

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

Royal Society of New Zealand
NIWA
ARC - Australian Research Council [AU]
EU project StratoClim
German Research council

Available on ORBi :

since 12 May 2016

Statistics

Number of views

56 (7 by ULiège)

Number of downloads

121 (0 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

Bibliography

Berry, J., et al., (2013), A coupled model of the global cycles of carbonyl sulfide and CO2: A possible new window on the carbon cycle, J. Geophys. Res. Biogeosci., 118, 842-852, doi: 10.1002/jgrg.20068.
Blake, N. J., et al., (2004), Carbonyl sulfide and carbon disulfide: Large-scale distributions over the western Pacific and emissions from Asia during TRACE-P, J. Geophys. Res., 109, D15S05, doi: 10.1029/2003JD004259.
Bodeker, G. E., and, S. Kremser, (2015), Techniques for analyses of trends in GRUAN data, Atmos. Meas. Tech., 8, 1673-1684, doi: 10.5194/amt-8-1673-2015.
Brühl, C., J. Lelieveld, P. J. Crutzen, and, H. Tost, (2012), The role of carbonyl sulphide as a source of stratospheric sulphate aerosol and its impact on climate, Atmos. Chem. Phys., 12, 1239-1253.
Campbell, J. E., et al., (2008), Photosynthetic control of atmospheric carbonyl sulfide during the growing season, Science, 322, 1085-1088.
Campbell, J. E., M. E. Whelan, U. Seibt, S. J. Smith, J. A. Berry, and, T. W. Hilton, (2015), Atmospheric carbonyl sulfide sources from anthropogenic activity: Implications for carbon cycle constraints, Geophys. Res. Lett., 42, 3004-3010, doi: 10.1002/2015GL063445.
Chin, M., and, D. D. Davis, (1995), A reanalysis of carbonyl sulfide as a source of stratospheric background sulfur aerosol, J. Geophys. Res., 1000 (D5), 8993-9005, doi: 10.1029/95JD00275.
Coffey, M. T., and, J. W. Hannigan, (2010), The temporal trend of stratospheric carbonyl sulfide, J. Atmos. Chem., 67, 61-70, doi: 10.1007/s10874-011-9203-4.
Crutzen, P. J., (1976), The possible importance of CSO for the sulfate layer of the stratosphere, Geophys. Res. Lett., 3, 73-76, doi: 10.1029/GL003i002p00073.
Efron, B., and, R. Tibshirani, (1986), Bootstrap methods for standard errors, confidence intervals, and other measures of statistical accuracy, Stat. Sci., 1 (1), 54-77.
Griffith, D. W. T., N. B. Jones, and, W. A. Matthews, (1998), Interhemispheric ratio and annual cycle of carbonyl sulfide (OCS) total column from ground-based solar FTIR spectra, J. Geophys. Res., 103 (D7), 8447-8454, doi: 10.1029/97JD03462.
Hase, F., P. Demoulin, A. J. Sauval, G. C. Toon, P. F. Bernath, A. Goldman, J. W. Hannigan, and, C. P. Rinsland, (2006), An empirical line-by-line model for the infrared solar transmittance spectrum from 700 to 5000 cm-1, J. Quant. Spectros. Radiat. Transfer, 102, 450-463.
Hofmann, D. J., and, T. Deshler, (1990), Balloonborne measurements of polar stratospheric clouds and ozone at -93°C in the Arctic in February 1990, Geophys. Res. Lett., 17 (12), 2185-2188, doi: 10.1029/GL017i012p02185.
Hofmann, D., J. Barnes, M. O'Neill, M. Trudeau, and, R. Neely, (2009), Increase in background stratospheric aerosol observed with lidar at Mauna Loa Observatory and Boulder, Colorado, Geophys. Res. Lett., 36, L15808, doi: 10.1029/12009GL039008.
Jones, N. B., K. Riedel, W. Allan, S. Wood, P. I. Palmer, K. Chance, and, J. Notholt, (2009), Long-term tropospheric formaldehyde concentrations deduced from ground-based Fourier transform solar infrared measurements, Atmos. Chem. Phys., 9, 7131-7142.
Kettle, A. J., U. Kuhn, M. von Hobe, J. Kesselmeier, and, M. O. Andreae, (2002), Global budget of atmospheric carbonyl sulfide: Temporal and spatial variations of the dominant sources and sinks, J. Geophys. Res., 107 (D22), 4658, doi: 10.1029/2002JD002187.
Kohlhepp, R., et al., (2012), Observed and simulated time evolution of HCl, ClONO2, and HF total column abundances, Atmos. Chem. Phys., 12, 3527-3556.
Kuai, L., J. Worden, S. S. Kulawik, S. A. Montzka, and, J. Liu, (2014), Characterization of Aura TES carbonyl sulfide retrievals over ocean, Atmos. Meas. Tech., 7, 163-172, doi: 10.5194/amt-7-163-2014.
Marsh, D. R., M. J. Mills, D. E. Kinnison, J.-F. Lamarque, N. Calvo, and, L. M. Polvani, (2013), Climate change from 1850 to 2005 simulated in CESM1(WACCM), J. Clim., 26 (19), 7372-7391.
Montzka, S. A., P. Calvert, B. D. Hall, J. W. Elkins, T. J. Conway, P. P. Tans, and, C. Sweeney, (2007), On the global distribution, seasonality, and budget of atmospheric carbonyl sulfide (COS) and some similarities to CO2, J. Geophys. Res., 112, D09302, doi: 10.1029/2006JD007665.
Moore, D. S., and, G. P. McCabe, (2003), Introduction to the Practice of Statistics, W.H. Freeman and Company, New York.
Myhre, G., T. F. Berglen, C. E. L. Myhre, and, I. S. A. Isaksen, (2004), The radiative effect of the anthropogenic influence on the stratospheric sulfate aerosol layer, Tellus, 56 (B), 294-299.
Paton-Walsh, C., N. Jones, S. Wilson, A. Meier, N. Deutscher, D. Griffith, R. Mitchell, and, S. Campbell, (2004), Trace gas emissions from biomass burning inferred from aerosol optical depth, Geophys. Res. Lett., 31, L05116, doi: 10.1029/2003GL018973.
Pitari, G., E. Mancini, V. Rizi, and, D. Shindell, (2002), Impact of future climate change and emission changes on stratospheric aerosols and ozone, J. Atmos. Sci., 59, 414-440.
Randel, W. J., M. Park, L. Emmons, D. Kinnison, P. Bernath, K. A. Walker, C. Boone, and, H. Pumphrey, (2010), Asian monsoon transport of pollution to the stratosphere, Science, 328, 611-613.
Rinsland, C. P., et al., (1998), Northern and southern hemisphere ground-based infrared spectroscopic measurements of tropospheric carbon monoxide and ethane, J. Geophys. Res., 103 (D21), 28,197-28,217, doi: 10.1029/98JD02515.
Rinsland, C. P., L. Chiou, E. Mahieu, R. Zander, C. D. Boone, and, P. F. Bernath, (2008), Measurements of long-term changes in atmospheric OCS (carbonyl sulfide) from infrared solar observations, J. Quant. Spectros. Radiat. Transfer, 109, 2679-2686.
Rodgers, C. D., (1976), Retrieval of atmospheric temperature and composition from remote measurements of thermal radiation, Rev. Geophys. Space Phys., 14 (4), 609-624.
Rothman, L. S., et al., (2013), The HITRAN2012 molecular spectroscopic database, J. Quant. Spectros. Radiat. Transfer, 130, 4-50.
Sandoval-Soto, L., M. Stanimirov, M. von Hobe, V. Schmitt, J. Valdes, A. Wild, and, J. Kesselmeier, (2005), Global uptake of carbonyl sulfide (COS) by terrestrial vegetation: Estimates corrected by deposition velocities normalized to the uptake of carbon dioxide (CO2), Biogeosciences, 2 (2), 125-132.
Sheng, J.-X., D. K. Weisenstein, B.-P. Luo, E. Rozanov, A. Stenke, J. Anet, H. Bingemer, and, T. Peter, (2015), Global atmospheric sulfur budget under volcanically quiescent conditions: Aerosol-chemistry-climate model predictions and validation, J. Geophys. Res. Atmos., 120, 256-276, doi: 10.1002/2014JD021985.
Sturges, W. T., S. A. Penkett, J.-M. Barnola, J. Chappellaz, E. Atlas, and, V. Stroud, (2001), A long-term record of carbonyl sulfide (COS) in two hemispheres from firn air measurements, Geophys. Res. Lett., 28 (21), 4095-4098, doi: 10.1029/2001GL013958.
Suntharalingam, P., A. J. Kettle, S. M. Montzka, and, D. J. Jacob, (2008), Global 3-D model analysis of the seasonal cycle of atmospheric carbonyl sulfide: Implications for terrestrial vegetation uptake, Geophys. Res. Lett., 35, L19801, doi: 10.1029/2008GL034332.
Vernier, J.-P., et al., (2011), Major influence of tropical volcanic eruptions on the stratospheric aerosol layer during the last decade, Geophys. Res. Lett., 38, L12807, doi: 10.1029/2011GL047563.
Watts, S. F., (2000), The mass budgets of carbonyl sulfide, dimethyl sulfide, carbon disulfide and hydrogen sulfide, Atmos. Environ., 34 (5), 761-779.
Wood, S. W., et al., (2002), Validation of version 5.20 ILAS HNO3,CH4,N2O, O3, and NO2 using ground-based measurements at Arrival Heights and Kiruna, J. Geophys. Res., 107 (D24), 8208, doi: 10.1029/2001JD000581.
Zeng, G., S. W. Wood, O. Morgenstern, N. B. Jones, J. Robinson, and, D. Smale, (2012), Trends and variations in CO, C2H6, and HCN in the Southern Hemisphere point to the declining anthropogenic emissions of CO and C2H6, Atmos. Chem. Phys., 12, 7543-7555, doi: 10.5194/acp-12-7543-2012.