First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters

Grignard, Bruno; Schmeits, Stephanie; Riva, Raphaël; Detrembleur, Christophe; Lecomte, Philippe; Jérôme, Christine

doi:10.1039/b822924d

Article (Scientific journals)

First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters

Grignard, Bruno; Schmeits, Stephanie; Riva, Raphaël et al.

2009 • In Green Chemistry, 11, p. 1525-1529

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/18962

DOI
10.1039/b822924d

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Keywords :

green technology; supercritical carbon dioxide; click chemistry; copper-mediated Huisgen's cycloaddition; aliphatic polyester; polymer functionalization

Abstract :

[en] The modification of aliphatic polyesters by the copper(I) catalyzed azide-alkyne cycloaddition (CuAAC) was successfully implemented in supercritical carbon dioxide (scCO2). Due to the remarkable properties of scCO2, the CuAAC reaction turned out to be quantitative even though the aliphatic polyesters used in this work were insoluble in scCO2. Interestingly enough, the conditions were mild enough to prevent polymer degradation from occurring and finally, efficient removal of the catalyst (>96%) was achieved by scCO2 extraction.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Schmeits, Stephanie ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Riva, Raphaël ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Lecomte, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

First example of “click” copper(I) catalyzed azide-alkyne cycloaddition in supercritical carbon dioxide: Application to the functionalization of aliphatic polyesters

Publication date :

November 2009

Journal title :

Green Chemistry

ISSN :

1463-9262

eISSN :

1463-9270

Publisher :

Royal Society of Chemistry

Volume :

Pages :

1525-1529

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.rsc.org/Publishing/Journals/GC/article.asp?doi=b822924d

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
The "Région Wallonne" and the "Fonds Européen de Développement Régional" (FEDER) in the frame of the SINOPLISS project

Available on ORBi :

since 18 August 2009

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