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Quadrupole splitting and isomer shifts in Te oxides investigated using nuclear forward scattering
Klobes, B.; Barrier, N.; Vertruyen, Bénédicte et al.
2014In Hyperfine Interactions, 226 (1-3), p. 713-719
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Keywords :
Lone-pair; Nuclear forward scattering; Quadrupole splitting
Abstract :
[en] Nuclear forward scattering by 125Te is a viable alternative to conventional 125Te Mössbauer spectroscopy avoiding all source related issues. Using reference compounds with known hyperfine parameters and Te oxides exhibiting stereochemically active lone pairs, we show that nuclear forward scattering by 125Te can be reliably used to extract quadrupole splitting energy and relative isomer shift. The rough correlation between Te-Ocoordination and quadrupole splitting energy as put forward by Takeda and Greenwood (J. Chem. Soc. Dalton, 2207, 1975), is corroborated by the presented results. © 2014 Springer Science+Business Media Dordrecht.
Disciplines :
Chemistry
Author, co-author :
Klobes, B.;  Jülich Centre for Neutron Science JCNS and Peter Grünberg Institute PGI, JARA-FIT, Forschungszentrum Jülich GmbH, D-52425 Jülich, Germany
Barrier, N.;  Laboratoire CRISMAT, UMR 6508 CNRS ENSICAEN, 6 bd Maréchal Juin, 14050 Caen Cedex 4, France
Vertruyen, Bénédicte  ;  Université de Liège - ULiège > Département de chimie (sciences) > Chimie inorganique structurale
Martin, Christine;  CNRS Ensicaen > Laboratoire Crismat
Hermann, Raphaël ;  Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)
Language :
English
Title :
Quadrupole splitting and isomer shifts in Te oxides investigated using nuclear forward scattering
Publication date :
2014
Event name :
32nd International Conference on the Applications of the Mössbauer Effect (ICAME 2013)
Event place :
Opatija, Croatia
Event date :
1-6 September 2013
Audience :
International
Journal title :
Hyperfine Interactions
ISSN :
0304-3843
eISSN :
1572-9540
Publisher :
Kluwer Academic Publishers
Volume :
226
Issue :
1-3
Pages :
713-719
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
ESRF - European Synchrotron Radiation Facility
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