[en] A vinyl ester monomer carrying a pendant 1,2,3-triazole group is synthesized in two steps and polymerized by cobalt-mediated radical polymerization. Subsequent alkylation with N-methyl bis[(trifluoromethyl)sulfonyl]imide affords the corresponding poly(vinyl ester 1,2,3-triazolium). This unprecedented example of poly(vinyl ester ionic liquid) exhibits an ionic conductivity of 9.2 × 10(-7) S cm(-1) at 30 °C
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Obadia, M. M.; University of Lyon 1, France, Ingénierie des Matériaux Polymères (IMP, UMR CNRS 5223)
Colliat-Dangus, G.; University of Lyon 1, France, Ingénierie des Matériaux Polymères (IMP, UMR CNRS 5223)
Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Serghei, A.; University of Lyon 1, France, Ingénierie des Matériaux Polymères (IMP, UMR CNRS 5223)
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Drockenmuller, Eric; University of Lyon 1, France, Ingénierie des Matériaux Polymères (IMP, UMR CNRS 5223) > Institut Universitaire de France (IUF)
Language :
English
Title :
Poly(vinyl ester 1,2,3-triazolium)s: a new member of the poly(ionic liquid)s family
Publication date :
25 February 2015
Journal title :
Chemical Communications
ISSN :
1359-7345
eISSN :
1364-548X
Publisher :
Royal Society of Chemistry, Cambridge, United Kingdom
Volume :
51
Issue :
16
Pages :
3332-3335
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] IUF - Institut Universitaire de France [FR]
