ORBi: Jérôme Christine - Electrochemical synthesis and characterization of the electronic structure of new conjugated polymers from dithienylene vinylene derivatives

Reference : Electrochemical synthesis and characterization of the electronic structure of new conjug...


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/17466

Title :	Electrochemical synthesis and characterization of the electronic structure of new conjugated polymers from dithienylene vinylene derivatives
Language :	English
Author, co-author :	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Maertens, Christophe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Mertens, Marc [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Quattrocchi, C. [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
	Lazzaroni, Roberto [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
	Brédas, Jean-Luc [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
Publication date :	Nov-1996
Journal title :	Synthetic Metals
Publisher :	Elsevier Science Sa
Volume :	83
Issue/season :	2
Pages :	103-109
Audience :	International
ISSN :	0379-6779
City :	Lausanne
Keywords :	[en] electropolymerization ; conjugated polymer
Abstract :	[en] Highly conjugated thiophene derivatives, based on thienylene vinylene and thienylene vinylene phenylene units, have been synthesized in order to examine: (i) the effect of such regular conjugated monomer structures on polymer formation; and (ii) the optical and electrochemical properties of the corresponding macromolecules. The all-trans monomers have been prepared by a Wittig reaction. The polymers have then been synthesized electrochemically. The polymers are electrochromic and can be reversibly doped both oxidatively and reductively. Their electrochemical behavior and optical properties have been analyzed on the basis of a series of quantum-chemical calculations.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; The European Commission ; IBM
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/17466
DOI :	10.1016/S0379-6779(97)80062-8
Other URL :	http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TY7-3VSH0RS-3C-1&_cdi=5611&_user=532038&_orig=search&_coverDate=11%2F30%2F1996&_sk=999169997&view=c&wchp=dGLzVlz-zSkzV&md5=7b717dfe760c395a5eb2f957a7938dc8&ie=/sdarticle.pdf
	http://www.elsevier.com/wps/find/journaldescription.cws_home/504105/description#description
Mentions required by the publisher for OA :	The authors acknowledge Synthetic Metals (Elsevier) for allowing them to archive this paper.

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