Reference : Electrochemical synthesis and characterization of the electronic structure of new con...
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/17466
Electrochemical synthesis and characterization of the electronic structure of new conjugated polymers from dithienylene vinylene derivatives
English
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Maertens, Christophe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Mertens, Marc [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Quattrocchi, C. [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
Lazzaroni, Roberto [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
Brédas, Jean-Luc [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
Nov-1996
Synthetic Metals
Elsevier Science Sa
83
2
103-109
Yes (verified by ORBi)
International
0379-6779
Lausanne
[en] electropolymerization ; conjugated polymer
[en] Highly conjugated thiophene derivatives, based on thienylene vinylene and thienylene vinylene phenylene units, have been synthesized in order to examine: (i) the effect of such regular conjugated monomer structures on polymer formation; and (ii) the optical and electrochemical properties of the corresponding macromolecules. The all-trans monomers have been prepared by a Wittig reaction. The polymers have then been synthesized electrochemically. The polymers are electrochromic and can be reversibly doped both oxidatively and reductively. Their electrochemical behavior and optical properties have been analyzed on the basis of a series of quantum-chemical calculations.
Center for Education and Research on Macromolecules (CERM)
Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; The European Commission ; IBM
Researchers
http://hdl.handle.net/2268/17466
10.1016/S0379-6779(97)80062-8
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TY7-3VSH0RS-3C-1&_cdi=5611&_user=532038&_orig=search&_coverDate=11%2F30%2F1996&_sk=999169997&view=c&wchp=dGLzVlz-zSkzV&md5=7b717dfe760c395a5eb2f957a7938dc8&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/504105/description#description
The authors acknowledge Synthetic Metals (Elsevier) for allowing them to archive this paper.

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