ORBi: Jérôme Christine - Electrochemical synthesis of new electroactive polymers from dithienylene-vinylene derivatives

Reference : Electrochemical synthesis of new electroactive polymers from dithienylene-vinylene deriv...


	Document type :	Scientific congresses and symposiums : Paper published in a journal
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/17462

Title :	Electrochemical synthesis of new electroactive polymers from dithienylene-vinylene derivatives
Language :	English
Author, co-author :	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Maertens, Christophe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Mertens, Marc [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Quattrocchi, C. [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
	Lazzaroni, Roberto [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
	Brédas, Jean-Luc [University of Mons-Hainaut (UMH) > > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires > >]
Publication date :	Jan-1997
Journal title :	Synthetic Metals
Publisher :	Elsevier Science Sa
Volume :	84
Issue/season :	1-3
Pages :	163-164
Audience :	International
ISSN :	0379-6779
City :	Lausanne
Event name :	International Conference on Science and Technology of Synthetic Metals
Event date :	28/07/1996 - 02/08/1996
Event place (city) :	Snowbird
Event country :	USA
Keywords :	[en] eletropolymerization ; conjugated polymer
Abstract :	[en] Highly conjugated thiophene derivatives, based on thienylene-vinylene and thieneylene-vinylene-phenylene units, have been synthesized in order to examine: (i) the effect of such regular conjugated monomer structures on the polymerization; (ii) the optical and electrochemical properties of the corresponding conjugated polymers. The all-trans monomers have been prepared by a Wittig reaction and the polymers have then been synthesized electrochemically. The polymers are electrochromic and can be reversibly doped both oxidatively and reductively. Their electrochemical behavior and optical properties have been analysed on the basis of quantum-chemical calculations.
Research units :	Center for Education and Research on Macromolecules (CERM)
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/17462
DOI :	10.1016/S0379-6779(97)80694-7
Other URL :	http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TY7-462BNPH-25-1&_cdi=5611&_user=532038&_orig=browse&_coverDate=01%2F31%2F1997&_sk=999159998&view=c&wchp=dGLzVzz-zSkWz&md5=61dd554bde9b7ae6eddeb7c261f63ef4&ie=/sdarticle.pdf
	http://www.elsevier.com/wps/find/journaldescription.cws_home/504105/description#description
Commentary :	The authors acknowledge Synthetic Metals (Elsevier) for allowing them to archive this paper.

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