Reference : Halato-telechelic polymers. VI. Viscoelastic properties of solutions of alkaline earth α...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/16773
Halato-telechelic polymers. VI. Viscoelastic properties of solutions of alkaline earth α, ω-dicarboxylatopolybutadiene
English
Broze, Guy [University of Liège (ULg) > Department of Chemistry > Laboratory of Macromolecular Chemistry and Organic Catalysis > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Laboratory of Macromolecular Chemistry and Organic Catalysis > >]
Teyssié, Philippe [University of Liège (ULg) > Department of Chemistry > Laboratory of Macromolecular Chemistry and Organic Catalysis > >]
Marco, Claude [University of Mons-Hainaut (UMH) > > Laboratory of Materials Science > >]
Jun-1983
Macromolecules
American Chemical Society
16
6
996-1000
Yes (verified by ORBi)
International
0024-9297
Washington
DC
[en] halatotelechelic polymer
[en] Alkaline earth alpha,omega-dicarboxylatopolybutadienesd issolved in a nonpolar solvent (an= 4600) display an attractive thermorheological simplicity and exhibit a secondary relaxation characteristic of the ionic component. The shear-thickening character of these solutions is to be outlined. Their deformation mechanism is controlled by the stability and the mean size of the ionic multiplets formed by the carboxylate end groups. The electrostatic origin of the viscoelastic behavior observed is well established by its dependence on solvent, temperature, and cation size.
Center for Education and Research on Macromolecules (CERM)
UNIBRA, Belgium ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Researchers
http://hdl.handle.net/2268/16773
10.1021/ma00240a033
http://pubs.acs.org/doi/pdf/10.1021/ma00240a033

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