Reference : Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (met...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/16414
Anionic polymerization of acrylic monomers. 8. Synthesis and characterization of (meth)acrylic end-functionalized polymers: macromonomers and telechelics
English
Varshney, Sunil K [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Bayard, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jacobs, Christian [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Fayt, Roger [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Teyssié, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
12-Oct-1992
Macromolecules
American Chemical Society
25
21
5578-5584
Yes (verified by ORBi)
International
0024-9297
Washington
DC
[en] anionic polymerization ; (meth)acrylate
[en] Tailor-made poly(tert-butyl acrylate) macromonomers, which are useful building blocks for the synthesis of comb or multiblock copolymers, have been successfully synthesized by deactivation of living PtBA macroanions with suitable electrophiles bearing either styrene or methacrylic unsaturation. Mono- or bifunctional initiators such as sec-butyllithium or naphthalenyllithium can be used. When these initiators were modified by LiCl as a mu-type ligand, the macroanions which are known to be living were functionalized with high efficiency. Characterization of the various macromonomers was performed using H-1 NMR spectroscopy and SEC.
Center for Education and Research on Macromolecules (CERM)
Cipari, Luxembourg ; Norsolor, France ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/16414
10.1021/ma00047a003
http://pubs.acs.org/doi/pdf/10.1021/ma00047a003

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