Reference : Intermolecular interactions in poly(vinylidene fluoride) and ε-caprolactam mixtures
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/15540
Intermolecular interactions in poly(vinylidene fluoride) and ε-caprolactam mixtures
English
Liu, Zehui [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Maréchal, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Nov-1996
Polymer
Elsevier Sci Ltd
37
23
5317-5320
Yes (verified by ORBi)
International
0032-3861
Oxford
[en] Mixtures of poly(vinylidene fluoride) (PVDF) and caprolactam (CPL) have been investigated as models for possible cross-interactions between vinylidene fluoride and amide structural units, that might account for the very fine phase morphology previously observed in PVDF/polyamide 6 blends. Over the entire composition range, the PVDF/CPL mixtures are monophase above the PVDF melting temperature. From the depression of the PVDF melting point, a negative interaction energy density, B, has been calculated that, however, depends on both temperature and CPL concentration. Mutual solubility of PVDF and CPL and negative B values are consistent with specific intermolecular interactions whose nature is discussed.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Researchers
http://hdl.handle.net/2268/15540
10.1016/0032-3861(96)00423-5
http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TXW-3VT9FYD-12-2&_cdi=5601&_user=532038&_orig=search&_coverDate=11%2F30%2F1996&_sk=999629976&view=c&wchp=dGLbVlz-zSkWA&md5=e506b886b4320a877d8c88672f992921&ie=/sdarticle.pdf
http://www.elsevier.com/wps/find/journaldescription.cws_home/30466/description#description
The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.

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