ORBi: Delaude Lionel - Coupling and carbonylation of iodoaromatics and terminal alkynes or alkynols catalyzed by a dimeric palladium hydroxide

Reference : Coupling and carbonylation of iodoaromatics and terminal alkynes or alkynols catalyzed b...


	Document type :	Scientific journals : Other
	Discipline(s) :	Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/15452

Title :	Coupling and carbonylation of iodoaromatics and terminal alkynes or alkynols catalyzed by a dimeric palladium hydroxide
Language :	English
Author, co-author :	Delaude, Lionel [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
	Masdeu, Anna M. [ > > ]
	Alper, Howard [ > > ]
Publication date :	1994
Journal title :	Synthesis
Publisher :	Georg Thieme Verlag Stuttgart
Issue/season :	11
Pages :	1149-1151
Peer reviewed :	Yes (verified by ORBi)
Audience :	International
ISSN :	0039-7881
e-ISSN :	1437-210X
City :	Stuttgart
Country :	Germany
Keywords :	[en] Dimeric Palladium Hydroxide ; Acetylenic Ketones
Abstract :	[en] The palladium(II) complex [(Ph(3)P)Pd(Ph)mu-OH)](2) is an effective catalyst for the coupling and carbonylation of alkynes and iodoarenes to give acetylenic ketones in 63-94% yields. Acetylenic hydroxy ketones were formed using secondary or tertiary alkynols as reactants.
Permalink :	http://hdl.handle.net/2268/15452
DOI :	10.1055/s-1994-25660

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