Article (Scientific journals)
Aromatic chlorination of toluene and of anisole using clay-supported iron(III) chloride and m-chloroperbenzoic Acid - A biomimetic approach
Delaude, Lionel; Laszlo, Pierre
1990In Catalysis Letters, 5 (1), p. 35-44
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Keywords :
Biomimetic Aromatic Chlorination; Toluene; Anisole; Clay Supported Iron(III) Chloride; m-Chloroperbenzoic Acid
Abstract :
[en] n the presence of meta-chloroperbenzoic acid, clay-supported ferric chloride is an efficient aromatic chlorinating agent for toluene and anisole. Influence of various experimental factors such as the nature of the solvent, the peracid or the metallic cation were investigated. These reactions represent a laboratory equivalent to biological halogenations through oxidation of halide ions by peroxidases in the presence of hydrogen peroxide.
Disciplines :
Chemistry
Author, co-author :
Delaude, Lionel  ;  Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Laszlo, Pierre ;  Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Aromatic chlorination of toluene and of anisole using clay-supported iron(III) chloride and m-chloroperbenzoic Acid - A biomimetic approach
Publication date :
1990
Journal title :
Catalysis Letters
ISSN :
1011-372X
eISSN :
1572-879X
Publisher :
Springer Science & Business Media B.V.
Volume :
5
Issue :
1
Pages :
35-44
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 26 June 2009

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