Reference : N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/15429
N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties
English
Dragutan, Ileana [> > > >]
Dragutan, Valerian [> > > >]
Delaude, Lionel mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Demonceau, Albert mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Noels, Alfred mailto [Université de Liège - ULg > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences) >]
2007
Revue Roumaine de Chimie
Editura Acad Romane
52
11
1013-1025
Yes
International
0035-3930
Bucuresti
Romania
[en] ruthenium complexes ; N-heterocyclic carbenes ; homogeneous precatalysts ; olefin metathesis ; cyclopropanation
[en] Synthesis of imidazol(in)-2-ylidene ruthenium complexes relevant for metathesis and related catalytic processes is described. As an attractive alternative of importance for practical applications, the in situ generation of new NHC ruthenium precatalysts, starting from the easily accessible imidazolium and imidazolinium salts, ruthenium dimer [RuCl2(p-cymene)](2) and a base, is reported in detail. The new NHC family of ruthenium complexes offers great promise as metathesis precatalysts enjoying a wide application profile in organic and polymer synthesis.
http://hdl.handle.net/2268/15429

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