Reference : Controlled radical polymerization of vinyl monomers catalyzed by ruthenium N-heterocycli...
Scientific congresses and symposiums : Paper published in a journal
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/15425
Controlled radical polymerization of vinyl monomers catalyzed by ruthenium N-heterocyclic carbene complexes
English
Demonceau, Albert mailto [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Delfosse, Sébastien mailto [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Richel, Aurore mailto [Université de Liège - ULg > Gembloux Agro-Bio Tech > Gembloux Agro-Bio Tech >]
Borguet, Yannick mailto [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Delaude, Lionel mailto [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Noels, Alfred mailto [Université de Liège - ULg > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences) >]
2005
Abstracts of Papers - American Chemical Society, National Meeting
Amer Chemical Soc
230
U4018-U4019
Yes
International
0065-7727
Washington
DC
[en] As part of our program devoted to the development of new metal-NHC catalyst systems, we have launched a detailed investigation on the catalytic activity of ruthenium-p-cymene complexes bearing NHC ligands for the ring opening metathesis polymerization (ROMP) of cyclic olefins and for the ATRP of vinyl monomers. We report herein on the use for ATRP of [RuCl2(p-cymene)(NHC)] complexes generated in situ by combining the [RuCl2(p-cymene)]2 dimer with an imidazolium salt and a base such as potassium tert-butoxide, cesium carbonate or aluminum isopropoxide.
http://hdl.handle.net/2268/15425

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