Title : Tuning of ruthenium N-heterocyclic carbene catalysts for ATRP
Language : English
Author, co-author : Delaude, Lionel [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Delfosse, Sébastien [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Richel, Aurore [Université de Liège - ULg > Gembloux Agro-Bio Tech > Gembloux Agro-Bio Tech >]
Demonceau, Albert [Université de Liège - ULg > > Chimie macromoléculaire et catalyse organique >]
Noels, Alfred [Université de Liège - ULg > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences) >]
Publication date : 2003
Journal title : Chemical Communications
Publisher : Royal Society of Chemistry
Issue/season : 13
Pages : 1526-1527
Peer reviewed : Yes (verified by ORBi)
Audience : International
ISSN : 1359-7345
City : Cambridge
Country : United Kingdom
Abstract : [en] Depending on the substituents, R-1 and R-2, ruthenium(II) - p-cymene complexes bearing N-heterocyclic carbene ligands are either efficient catalysts for the well-controlled atom transfer radical polymerisation of methyl methacrylate and styrene, or promote a redox-initiated free-radical process.
Permalink : http://hdl.handle.net/2268/15407
DOI : 10.1039/b301733h