Reference : Living Anionic Homopolymerization and Block Copolymerization of 4-Vinylpyridine at "Elev...
Scientific journals : Article
Engineering, computing & technology : Materials science & engineering
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/15180
Living Anionic Homopolymerization and Block Copolymerization of 4-Vinylpyridine at "Elevated" Temperature and Its Characterization by Size Exclusion Chromatography
English
Creutz, Serge [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Teyssié, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
13-Jan-1997
Macromolecules
Amer Chemical Soc
30
1
1-5
Yes (verified by ORBi)
International
0024-9297
Washington
[en] anionic polymerization ; vinylpyridine
[en] The anionic polymerization of 4-vinylpyridine (4VP) has been investigated in 9/1 pyridine/THF at 0 °C. After characterization of the living character of 4VP polymerization, its copolymerization with tert-butyl methacrylate (tBMA) has been carried out also successfully. Their relative reactivity ratios have been determined. Solvent composition as well as temperature have been varied in order to evaluate their influence on the final molecular characteristics of the polymers. Finally, a new SEC methodology in 8/1/1 N,N-dimethylformamide/triethylamine/pyridine has been developed.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Akzo Nobel N. V.
Researchers
http://hdl.handle.net/2268/15180
10.1021/ma9610931
http://pubs.acs.org/doi/pdf/10.1021/ma9610931

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