[en] Careful control of experimental conditions in the cathodic electropolymerization of acrylonitrile allows the grafting of thin polymer films, on conducting surfaces offering electrons easily mobilized at a relatively low potential. Matching relative polarity and donicity of solvent and monomer expands the applicability of this methodology to the whole class of (meth)acrylic monomers, paving the way to many new and useful multiphase materials.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Baute, Noëlle; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Martinot, Lucien ; Université de Liège - ULiège > Département de chimie (sciences) > Radiochimie
Mertens, Marc; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Bonding electropolymerization: a new electron-transfer strategy for the tailoring of performant polymer-based composites
L. E. A. Berlouis, D. J. Schiffrin, Trans. Inst. Met. Finish. 64, 42 (1986)
W. Yuan, J. O. Iroh, Trends Polym. Sci. 1(12), 388 (1993)
K. K. Kanazawa, A. F. Diaz, W. D. Gill, P. M. Grant, G. B. Street, G. P. Gardini, J. F. Kwak, Synth. Met. 1, 329 (1979)
G. Mengoli, Adv. Polym. Sci. 33, 2 (1979)
G. Lécayon et al., Eur. Patent No. 00.38244 (1981)
G. Lécayon et al., Chem. Phys. Lett. 91, 506 (1982); La Recherche 19, 888 (1988); and subsequent papers
G. Lécayon et al., Chem. Phys. Lett. 91, 506 (1982); La Recherche 19, 888 (1988); and subsequent papers
M.N. Baizer, US Patent No. 3245889
S.N. Bhadami; R. Ansari; S.K.S Gupta, J. Appl. Polym. Sci. 44, 121 (1992)
B. Yurttas, L. Toppare, U. Akbulut, J. Macromol. Sci. A25(2), 219 (1988)
M. Mertens, C. Calberg, L. Martinot, R. Jérôme, Macromolecules 29, 4910 (1996)
C. Calberg, M. Mertens, N. Baute, R. Jérôme, V. Carlier, M. Sclavons, R. Legras, J. Polym. Sci., Part B, Polym. Phys. in press
J. Tanguy, G. Deniau, G. Lalazer, G. Lécayon, J. Electroanal. Chem. 417, 175 (1996)
M. Mertens, R. Jérôme, L. Martinot, Belg. Appl. 09700608 (1997)
M. Mertens, C. Calberg, N. Baute, R. Jérôme, L. Martinot, J. Electroanal. Chem., in press (1997)
V. Gutmann, "The Donor-Acceptor Approach to Molecular Interactions", Plenum Press, New York 1978
N. Baute, Ph. Dubois, L. Martinot, M. Mertens, Ph. Teyssié, R. Jérôme, submitted for publication
M. Mertens, L. Martinot, C. Calberg, R. Jérôme, J. Schrijnemackers, Belg. Patent Appl. 09300322 (1993); U.S. Patent Appl. 08221378 (1994); L. Martinot, M. Mertens, L. Lopes, C. Calberg, P. Faak, M. Krausch, J. Guillaume, G. Ghitti, J. Marien, J. Riga, R. Jérôme, J. Schrijnemackers, Radiochimica Acta 75, 111 (1996)
M. Mertens, L. Martinot, C. Calberg, R. Jérôme, J. Schrijnemackers, Belg. Patent Appl. 09300322 (1993); U.S. Patent Appl. 08221378 (1994); L. Martinot, M. Mertens, L. Lopes, C. Calberg, P. Faak, M. Krausch, J. Guillaume, G. Ghitti, J. Marien, J. Riga, R. Jérôme, J. Schrijnemackers, Radiochimica Acta 75, 111 (1996)
M. Mertens, L. Martinot, C. Calberg, R. Jérôme, J. Schrijnemackers, Belg. Patent Appl. 09300322 (1993); U.S. Patent Appl. 08221378 (1994); L. Martinot, M. Mertens, L. Lopes, C. Calberg, P. Faak, M. Krausch, J. Guillaume, G. Ghitti, J. Marien, J. Riga, R. Jérôme, J. Schrijnemackers, Radiochimica Acta 75, 111 (1996)
