ORBi: Teyssié Philippe - Living anionic polymerization of (meth)acrylic esters : new mechanistic concepts and resulting materials

Reference : Living anionic polymerization of (meth)acrylic esters : new mechanistic concepts and res...


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/14957

Title :	Living anionic polymerization of (meth)acrylic esters : new mechanistic concepts and resulting materials
Language :	English
Author, co-author :	Teyssié, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Baran, Janusz [Institute of Fundamental Chemistry, Technical University of Szczecin, Poland > > > >]
	Dubois, Philippe [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Wang, J. S. [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Yu, J. M. [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Yu, Y. [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Zundel, Thomas [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	Jul-1998
Journal title :	Macromolecular Symposia
Publisher :	Wiley-V C H Verlag Gmbh
Volume :	132
Pages :	303-307
Audience :	International
ISSN :	1022-1360
e-ISSN :	1521-3900
City :	Weinheim
Keywords :	[en] anionic polymerization
Abstract :	[en] As an illustration of the frantic development of (meth)acrylic esters anionic polymerization during the last decade, three significant breakthroughs will be presented and analyzed: - extension of the LAP (ligated anionic polymerization) concept to the practical synthesis of both high iso- or syndio high MW PMMA; - the production of "perfect" hydrocarbon gels from tailored PMMA-polybutadiene-PMMA triblock copolymers; - the use of reactivity "boosters" allowing to climb back up the nucleophilic reactivity scale, i.e. initiating styrene, dienes and (meth)acrylates polymerization with alcoholates and silanolates.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Elf Atochem ; Raychem ; Shell ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/14957

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