Article (Scientific journals)
Bolaamphiphiles Derived from Alkenyl L-rhamnosides and Alkenyl D-xylosides: Importance of the Hydrophilic Head
Gatard, Sylvain; Nasir, Mehmet Nail; Deleu, Magali et al.
2013In Molecules, 18 (5), p. 6101-6112
Peer Reviewed verified by ORBi
 

Files


Full Text
molecules-18-06101 (3).pdf
Publisher postprint (322.45 kB)
Uniquement le résumé de l'article
Download

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
rhamnose; glycosylation; metathesis; surfactant; bolaform; interfacial properties
Abstract :
[en] The two step synthesis of a new bolaamphiphile derived from alkenyl L-rhamnosides was described. The general synthetic strategy of bolaamphiphiles derived from L-rhamnose was based on a previous work describing the synthesis of bolaamphiphiles derived from D-xylose. The conformational properties of this new compound were investigated by FTIR spectroscopy in an aqueous film in order to obtain a reference for further studies about the membrane-interacting properties. Moreover, the surface activity of this new bolaamphiphile was analyzed by Langmuir balance technology and was compared with that of the analogous bolaamphiphile derived from alkenyl D-xylosides. The findings indicate that the rhamnoside-based bolaform has an increased surface activity and a better ability to form aggregates than xyloside-based one.
Disciplines :
Biochemistry, biophysics & molecular biology
Author, co-author :
Gatard, Sylvain 
Nasir, Mehmet Nail  ;  Université de Liège - ULiège > Chimie et bio-industries > Chimie biologique industrielle
Deleu, Magali  ;  Université de Liège - ULiège > Chimie et bio-industries > Chimie biologique industrielle
Legrand, Vincent
Bouquillon, Sandrine
 These authors have contributed equally to this work.
Language :
English
Title :
Bolaamphiphiles Derived from Alkenyl L-rhamnosides and Alkenyl D-xylosides: Importance of the Hydrophilic Head
Publication date :
2013
Journal title :
Molecules
eISSN :
1420-3049
Publisher :
MDPI, Basel, Switzerland
Volume :
18
Issue :
5
Pages :
6101-6112
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 29 April 2013

Statistics


Number of views
61 (16 by ULiège)
Number of downloads
215 (10 by ULiège)

Scopus citations®
 
16
Scopus citations®
without self-citations
8
OpenCitations
 
15

Bibliography


Similar publications



Contact ORBi