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Supercritical CO2 as an efficient medium for layered silicate organomodification: preparation of thermally stable organoclays and dispersion in polyamide 6
Naveau, Elodie; Calberg, Cédric; Detrembleur, Christophe et al.
2009In Polymer, 50 (6), p. 1438-1446
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Keywords :
nanostructured material; nanocomposite; clay; green technology; supercritical carbon dioxide; flame retardancy
Abstract :
[en] In this study, the preparation of organoclays via a new process using supercritical carbon dioxide is described. This method turns out to be very efficient with various surfactants, in particular nonwater-soluble alkylphosphonium salts. The influence of the surfactant as well as of the clay nature on the thermal stability of the organoclay is evaluated by thermogravimetric analysis. Phosphonium-based montmorillonites are up to 90 °C more stable than ammonium-based montmorillonites. Moreover, the use of hectorite adds another 40 °C of thermal stability to the phosphonium-modified clays. These organomodified clays have been melt-blended with polyamide 6 and morphology as well as fire properties of the nanocomposites are discussed, in terms of influence of the stability of organoclays. For the first time, comparison of nanocomposites based on clay organomodified by ammonium and phosphonium salts of the very same structure is reported.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Naveau, Elodie ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ;  Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Industrial Chemistry
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemsitry > Center for Education and Research on Macromolecules (CERM)
Bourbigot, S.;  Villeneuve d'Asq, France > Procédés d’Elaboration de Revêtements Fonctionnels, UMR/CNRS 8008
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Alexandre, Michaël ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Supercritical CO2 as an efficient medium for layered silicate organomodification: preparation of thermally stable organoclays and dispersion in polyamide 6
Publication date :
06 March 2009
Journal title :
Polymer
ISSN :
0032-3861
eISSN :
1873-2291
Publisher :
Elsevier Science, Oxford, United Kingdom
Volume :
50
Issue :
6
Pages :
1438-1446
Peer reviewed :
Peer Reviewed verified by ORBi
Name of the research project :
The "Région Wallonne" in the frame of the "FINECLAY" program
Funders :
BELSPO - Service Public Fédéral de Programmation Politique scientifique [BE]
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
Région wallonne [BE]
Commentary :
The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.
Available on ORBi :
since 16 June 2009

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