Reference : Mono- and Bimetallic Ruthenium—Arene Catalysts for Olefin Metathesis: A Survey
Parts of books : Contribution to collective works
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/14443
Mono- and Bimetallic Ruthenium—Arene Catalysts for Olefin Metathesis: A Survey
English
Borguet, Yannick mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Sauvage, Xavier [> > > >]
Demonceau, Albert mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
Delaude, Lionel mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
2010
Green Metathesis Chemistry
Dragutan, Valerian
Demonceau, Albert mailto
Dragutan, Ileana
Finkelshtein, Eugene Sh.
Springer
NATO Science for Peace and Security Series A: Chemistry and Biology
89-100
978-90-481-3431-1
Dordrecht
The Netherlands
[en] allenylidene ligand ; homogeneous catalysis ; indenylidene ligand ; N-heterocyclic carbene ; phosphine ligand ; vinylidene ligand
[en] In this chapter, we summarize the main achievements of our group toward the development of easily accessible, highly efficient ruthenium—arene catalyst precursors for olefin metathesis. Major advances in this field are presented chronologically, with an emphasis on catalyst design and mechanistic details. The first part of this survey focuses on monometallic complexes with the general formula RuCl2(p-cymene)(L), where L is a phosphine or N-heterocyclic carbene ancillary ligand. In the second part, we disclose recent developments in the synthesis and catalytic applications of homobimetallic ruthenium—arene complexes of generic formula (p-cymene)Ru(μ-Cl)3RuCl(η2-C2H4)(L) and their derivatives resulting from the substitution of the labile ethylene moiety with vinylidene, allenylidene, or indenylidene units
Researchers ; Professionals
http://hdl.handle.net/2268/14443
10.1007/978-90-481-3433-5_8

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