Self-assembly of amine terminated alkylthiol and alkyldithiol films on a polycrystalline copper substrate

Adhesion promoter; Amine functions; Biological cells; Contact angle goniometry; Copper substrates; Different protocols; Disordered structures; Dithiols; Free amines; High quality; PM-IRRAS; Polycrystalline copper; Sams; Self assembly process; Contact angle; Copper; Organic compounds; Self assembly; Substrates; Sulfur; Self assembled monolayers

Abstract :

[en] Amine terminated self-assembled monolayers on gold are widely used as adhesion promoter agent to immobilize nanostructure such as fullerene, proteins and biological cells. The reactivity of the amine function makes difficult the formation of high quality SAMs. Most studies report disordered structure with the presence of oxidized sulphur on the surface. In this work, SAMs of 11-aminoundecyl-1-thiol (NH 2-(CH 2) 11-SH) and 2-aminoundecylpropane-1,3-dithiol (NH 2-(CH 2) 11-CH-(CH 2SH) 2) have been elaborated on copper substrates, following different protocols (alkalinization during or after the self-assembly). The modification of copper by amine terminated SAMs of thiol and dithiol has been successfully achieved. The best quality of SAMs are obtained when the alkalinization to free amine is carried on after the self-assembly process. Characterizaton of the SAMs are carried out using contact angle goniometry, PM-IRRAS, XPS and CV. © 2011 The Electrochemical Society.

Disciplines :

Chemistry

Author, co-author :

Denayer, Jessica ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT

Delhalle, J.; Laboratory of Chemistry and Electrochemistry of Surfaces, Facultés Universitaires Notre-Dame de la Paix, rue de bruxelles 61, 5000 Namur, Belgium

Mekhalif, Z.; Laboratory of Chemistry and Electrochemistry of Surfaces, Facultés Universitaires Notre-Dame de la Paix, rue de bruxelles 61, 5000 Namur, Belgium

Language :

English

Title :

Self-assembly of amine terminated alkylthiol and alkyldithiol films on a polycrystalline copper substrate

Publication date :

2011

Journal title :

Journal of the Electrochemical Society

ISSN :

0013-4651

eISSN :

1945-7111

Publisher :

Electrochemical Society

Volume :

158

Issue :

Pages :

P100-P108

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 14 February 2013

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