ORBi: Fallais Isabelle - Anionic synthesis of cyclic anhydride end-capped poly(methyl methacrylate)

Reference : Anionic synthesis of cyclic anhydride end-capped poly(methyl methacrylate)


	Document type :	Scientific journals : Article
	Discipline(s) :	Engineering, computing & technology : Materials science & engineering Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/12984

Title :	Anionic synthesis of cyclic anhydride end-capped poly(methyl methacrylate)
Language :	English
Author, co-author :	Fallais, Isabelle [Université Catholique de Louvain (UCL) > > Laboratoire de Chimie et de Physique des Hauts Polymères (POLY) > >]
	Pantoustier, Nadège [Université Catholique de Louvain (UCL) > > Laboratoire de Chimie et de Physique des Hauts Polymères (POLY) > >]
	Devaux, Jacques [Université Catholique de Louvain (UCL) > > Laboratoire de Chimie et de Physique des Hauts Polymères (POLY) > >]
	Zune, Catherine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Robert [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	Jun-2000
Journal title :	Polymer
Publisher :	Elsevier Sci Ltd
Volume :	41
Issue/season :	14
Pages :	5535-5539
Audience :	International
ISSN :	0032-3861
City :	Oxford
Keywords :	[en] anionic polymerization
Abstract :	[en] This paper reports on the anionic synthesis of poly(methyl methacrylate) chains end-capped by cyclic anhydride. The method is based on the chemical derivatization of a precursor tert-butyl diester end-group. Compared to the thermal modification, which was previously used, this method allows intermolecular coupling and polymer degradation to be avoided. But up to now, the final anhydride content remains moderate and has still to be improved.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Fonds pour la formation à la Recherche dans l'Industrie et dans l'Agriculture (Communauté française de Belgique) - FRIA
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/12984
DOI :	10.1016/S0032-3861(99)00871-X
Other URL :	http://www.sciencedirect.com/science?_ob=MImg&_imagekey=B6TXW-3YWWYVS-1D-C&_cdi=5601&_user=532038&_orig=browse&_coverDate=06%2F30%2F2000&_sk=999589985&view=c&wchp=dGLbVlW-zSkWb&md5=b103d961b3bf28675f15fa0add4d47b2&ie=/sdarticle.pdf
	http://www.elsevier.com/wps/find/journaldescription.cws_home/30466/description#description
Commentary :	The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.

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