ORBi: Kermagoret Anthony - Synthesis of novel poly(N-vinyl amide)s containing copolymers by cobalt-mediated radical polymerization

Reference : Synthesis of novel poly(N-vinyl amide)s containing copolymers by cobalt-mediated radical...


	Document type :	Scientific congresses and symposiums : Poster
	Discipline(s) :	Physical, chemical, mathematical & earth Sciences : Chemistry Engineering, computing & technology : Materials science & engineering
	To cite this reference:	http://hdl.handle.net/2268/129735

Title :	Synthesis of novel poly(N-vinyl amide)s containing copolymers by cobalt-mediated radical polymerization
Language :	English
Author, co-author :	Kermagoret, Anthony [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Hurtgen, Marie [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Liu, Ji [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Willet, Nicolas [University of Liège (ULg) > Department of Chemistry > Nanochemistry and Molecular Systems (NANOCHEM) > >]
	Riva, Raphaël [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Jérôme, Christine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
	Detrembleur, Christophe [Université de Liège - ULg > > Centre d'études et de rech. sur les macromolécules (CERM) >]
	Poli, Rinaldo [University of Toulouse, France > > Laboratoire de Chimie de Coordination (LCC) > >]
	Debuigne, Antoine [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Publication date :	10-May-2012
On invitation :	No
Audience :	National
Event name :	Belgian Polymer Group (BPG) annual meeting 2012
Event date :	10/05/2012 - 11/05/2012
Event organizer :	DSM
	The "KUL"
Event place (city) :	Blankenberge
Event country :	Belgium
Keywords :	[en] radical polymerization ; cobalt-mediated radical polymerization (CMRP)
Abstract :	[en] Poly(N-vinyl amide)s are found in many applications due to their valued properties including water solubility, biocompatibility, metal-coordination ability, etc. Although N-vinyl amides are easily polymerized via radical pathways, their growing radicals are quite reactive due to the lack of stabilizing group, rendering the synthesis of well-defined poly(N-vinyl amide)s challenging. Thus, we explored the organometallic-mediated radical polymerization (OMRP) of a series of N-vinyl amides using bis(acetylacetonato)cobalt(II) as controlling agent in order to develop a platform for the precision synthesis of poly(N-vinyl amide)s.
Research units :	Center for Education and Research on Macromolecules (CERM)
Funders :	Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy
Target :	Researchers
Permalink :	http://hdl.handle.net/2268/129735
Commentary :	This poster was presented by Anthony Kermagoret

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