green technology; supercritical carbon dioxide; radical polymerization
Abstract :
[en] Highly porous materials were produced by acrylamide polymerisation templated by supercritical CO2-in-water emulsions using new fluorinated glycosurfactants. Properties of the resulting polymer scaffolds were tuned by performing dispersion polymerisations within their cavities filled with supercritical CO2.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Boyère, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Léonard, Alexandre ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Chemical Engineering
Grignard, Bruno ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Favrelle, Audrey; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Pirard, Jean-Paul ; Université de Liège - ULiège > Department of Applied Chemistry > Laboratory of Chemical Engineering
Paquot, Michel ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Unit of Biological and Industrial Chemistry
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Synthesis of microsphere-loaded porous polymers by combining emulsion and dispersion polymerisations in supercritical carbon dioxide
Publication date :
28 August 2012
Journal title :
Chemical Communications
ISSN :
1359-7345
eISSN :
1364-548X
Publisher :
Royal Society of Chemistry, Cambridge, United Kingdom
Volume :
48
Issue :
67
Pages :
8356-8358
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique The French Community of Belgium in the frame of the ARC program SUPERZYM
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