Reference : Retracing the evolution of monometallic ruthenium-arene catalysts for C-C bond formation
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/129704
Retracing the evolution of monometallic ruthenium-arene catalysts for C-C bond formation
English
Delaude, Lionel mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie organométallique et catalyse homogène >]
Demonceau, Albert mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique >]
2012
Dalton Transactions
Royal Society of Chemistry
41
31
9257-9268
Yes (verified by ORBi)
International
1472-7773
Cambridge
United Kingdom
[en] Atom transfer radical reactions ; C-C bond formation ; Efficient catalysts ; Experimental procedure ; Generic formula ; In-situ ; N-heterocyclic carbenes ; Olefin metathesis ; Parallel development ; Ruthenium-arene ; Olefins ; Organic compounds ; Phosphorus compounds ; Reaction kinetics ; Ruthenium ; Ruthenium compounds ; Catalysts
[en] Preformed or in situ generated monometallic ruthenium-arene complexes with the generic formula RuX2(arene)(L) (L = phosphine or N-heterocyclic carbene) are versatile and efficient catalyst precursors for olefin metathesis and atom transfer radical reactions. Their synthesis is usually accomplished using simple and straightforward experimental procedures starting from the [RuCl2(p-cymene)]2 dimer. This article retraces their evolution over the past 20 years and highlights similarities and differences with the parallel development of well-defined RuX2(CHR)(L1)(L2) ruthenium-alkylidene catalysts.
Researchers ; Professionals
http://hdl.handle.net/2268/129704
10.1039/c2dt30293d

File(s) associated to this reference

Fulltext file(s):

FileCommentaryVersionSizeAccess
Restricted access
A069.pdfPublisher postprint1.43 MBRequest copy

Bookmark and Share SFX Query

All documents in ORBi are protected by a user license.