Reference : Use of metallocenes in the polymerization-filling technique with production of polyolefi...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/12712
Use of metallocenes in the polymerization-filling technique with production of polyolefin-based composites
English
Alexandre, Michaël mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Martin, Eric [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Dubois, Philippe [University of Mons-Hainaut (UMH) > > Service des Matériaux Polymères et Composites > >]
Garcia-Martini, Miguel [Dow Benelux, Terneuzen, The Netherlands > > > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Aug-2000
Macromolecular Rapid Communications
Wiley-V C H Verlag Gmbh
21
13
931-936
Yes (verified by ORBi)
International
1022-1336
Weinheim
[en] alkene ; metallocene-mediated polymerization ; nanostructured material ; nanocomposite
[en] In an updated version of the polymerization-filling technique, the surface of particulate fillers has been activated by metallocenes. Homogeneously filled polyolefins have accordingly been produced by the in situ copolymerization of ethylene and α-olefins, e.g., 1-octene and 1,9-decadiene. Different fillers have been successfully used, including inorganic particles with either an acidic surface (kaolin, glass beads, silica) or a basic surface (magnesium hydroxide, wollastonite), graphite and nickel particles. Hydrogen has proved to be efficient in reducing the molecular weight of the produced polymers.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Dow Benelux
Researchers
http://hdl.handle.net/2268/12712
10.1002/1521-3927(20000801)21:13<931::AID-MARC931>3.0.CO;2-X
http://www3.interscience.wiley.com/cgi-bin/fulltext/73000554/PDFSTART

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