Reference : Radical coupling of polymers formed by cobalt-mediated radical polymerization
Parts of books : Contribution to collective works
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/123802
Radical coupling of polymers formed by cobalt-mediated radical polymerization
English
Debuigne, Antoine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Hurtgen, Marie [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [Université de Liège - ULg > > Centre d'études et de rech. sur les macromolécules (CERM) >]
20-Mar-2012
Progress in controlled radical polymerization: mechanisms and techniques
Matyjaszewski, Krzysztof
Sumerlin, Brent
Tsarevsky, Nicolas V.
The American Chemical Society, Division Polymer Chemistry
ACS Symposium series
217-230
9780841226999
[en] radical polymerization ; cobalt-mediated radical coupling (CMRC) ; radical coupling
[en] Considerable progress has been recently made in cobalt-mediated radical polymerization (CMRP), a controlled radical polymerization system based on the temporary deactivation of the polymer chains by a cobalt complex, like the improvement of the mechanistic understanding, the extension to a range of monomers and the preparation of novel architectures. However, the real breakthrough in this field concerns the development of efficient radical coupling methods for polymer precursors preformed by CMRP. This book chapter aims to describe the general principle and main characteristics of such radical coupling techniques involving dienes, nitrones, fullerenes or carbon nanotubes. Well-defined and complex architectures obtained by these techniques are provided in order to illustrate their potential for macromolecular engineering.
Center for Education and Research on Macromolecules (CERM)
Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS
Researchers
http://hdl.handle.net/2268/123802
10.1021/bk-2012-1100.ch014
http://pubs.acs.org/doi/abs/10.1021/bk-2012-1100.ch014

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