Reference : Interpolymer radical coupling: A toolbox complementary to controlled radical polymerizat...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/123798
Interpolymer radical coupling: A toolbox complementary to controlled radical polymerization
English
Debuigne, Antoine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Hurtgen, Marie [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Detrembleur, Christophe mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Barner-Kowollik, Christopher [Karlsruhe Institute of Technology (KIT), Germany > Institut für Technische Chemie und Polymerchemie > Preparative Macromolecular Chemistry > >]
Junkers, Thomas [University of Hasselt, Belgium > Institute for Materials Research (IMO) > Polymer Reaction Design Group > >]
Jul-2012
Progress in Polymer Science
Elsevier Science
37
7
1004-1030
Yes (verified by ORBi)
International
0079-6700
[en] radical coupling ; radical polymerization ; cobalt-mediated radical coupling (CMRC) ; review
[en] The current review focuses on the relevance and practical benefit of interpolymer radical coupling methods. The latter are developing rapidly and constitute a perfectly complementary macromolecular engineering toolbox to the controlled radical polymerization techniques (CRP). Indeed, all structures formed by CRP are likely to be prone to radical coupling reactions, which multiply the available synthetic possibilities. Basically, the coupling systems can be divided in two main categories. The first one, including the atom transfer radical coupling (ATRC), silane radical atom abstraction (SRAA) and cobalt-mediated radical coupling (CMRC), relies on the recombination of macroradicals produced from a dormant species. The second one, including atom transfer nitroxide radical coupling (ATNRC), single electron transfer nitroxide radical coupling (SETNRC), enhanced spin capturing polymerization (ESCP) and nitrone/nitroso mediated radical coupling (NMRC), makes use of a radical scavenger in order to promote the conjugation of the polymer chains. More than a compilation of macromolecular engineering achievements, the present review additionally aims to emphasize the particularities, synthetic potential and present limitations of each system.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; Fonds Wetenschappelijk Onderzoek - FWO ; The Karlsruhe Institute of Technology
Researchers
http://hdl.handle.net/2268/123798
10.1016/j.progpolymsci.2012.01.003
http://pdn.sciencedirect.com/science?_ob=MiamiImageURL&_cid=271613&_user=532038&_pii=S0079670012000160&_check=y&_origin=browse&_zone=rslt_list_item&_coverDate=2012-07-31&wchp=dGLbVlS-zSkzV&md5=2370bb3f84ff329fd62d5653ef99f99c&pid=1-s2.0-S0079670012000160-main.pdf

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