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| Reference : Unimolecular reaction dynamics from kinetic energy release distributions.IV. Dissociatio... |
| Scientific journals : Article | |||
| Physical, chemical, mathematical & earth Sciences : Chemistry | |||
| http://hdl.handle.net/2268/122181 | |||
| Unimolecular reaction dynamics from kinetic energy release distributions.IV. Dissociation of the Pyridine ion. | |
| English | |
| [fr] La dynamique des réactions unimoléculaires à partir des distributions d'énergie cinétique. IV. La dissociation de l'ion Pyridine. | |
| Urbain, P. [> >] | |
Leyh, Bernard  [Université de Liège - ULg > Département de chimie (sciences) > Laboratoire de dynamique moléculaire >] | |
| Remacle, Françoise [Université de Liège - ULg > Département de chimie (sciences) > Laboratoire de chimie physique théorique >] | |
| 1999 | |
| International Journal of Mass Spectrometry and Ion Processes | |
| Elsevier | |
| 185-187 | |
| 155-163 | |
| Yes | |
| International | |
| 0168-1176 | |
| Amsterdam | |
| The Netherlands | |
| [en] Kinetic energy release, ; Metastable dissociation ; Maximum Entropy Method ; Phase space sampling ; Momentum gap law ; Pyridine ion | |
| [en] The kinetic energy release distribution (KERD) for the dissociation of the Pyridine ion into C4H4++HCN in the microsecond time window has been experimentally determined and theoretically analyzed by the maximum entropy method. Less energy is channeled into the reaction coordinate than the statistical estimate because of the action of the "moentum gap law". The larger the value of the relative translational momentum of the fragments, the less efficient the exploration of phase space. the fraction of phase space efficiently sampled is estimated to be of the order of 75%. | |
| Laboratoire de Dynamique Moléculaire | |
| Fonds de la Recherche Fondamentale Collective d'Initiative des Chercheurs - FRFC | |
| Researchers | |
| http://hdl.handle.net/2268/122181 |
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