Reference : Unimolecular reaction dynamics from kinetic energy release distributions.IV. Dissociatio...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/122181
Unimolecular reaction dynamics from kinetic energy release distributions.IV. Dissociation of the Pyridine ion.
English
[fr] La dynamique des réactions unimoléculaires à partir des distributions d'énergie cinétique. IV. La dissociation de l'ion Pyridine.
Urbain, P. [> >]
Leyh, Bernard mailto [Université de Liège - ULg > Département de chimie (sciences) > Laboratoire de dynamique moléculaire >]
Remacle, Françoise mailto [Université de Liège - ULg > Département de chimie (sciences) > Laboratoire de chimie physique théorique >]
1999
International Journal of Mass Spectrometry and Ion Processes
Elsevier
185-187
155-163
Yes
International
0168-1176
Amsterdam
The Netherlands
[en] Kinetic energy release, ; Metastable dissociation ; Maximum Entropy Method ; Phase space sampling ; Momentum gap law ; Pyridine ion
[en] The kinetic energy release distribution (KERD) for the dissociation of the Pyridine ion into C4H4++HCN in the microsecond time window has been experimentally determined and theoretically analyzed by the maximum entropy method. Less energy is channeled into the reaction coordinate than the statistical estimate because of the action of the "moentum gap law". The larger the value of the relative translational momentum of the fragments, the less efficient the exploration of phase space. the fraction of phase space efficiently sampled is estimated to be of the order of 75%.
Laboratoire de Dynamique Moléculaire
Fonds de la Recherche Fondamentale Collective d'Initiative des Chercheurs - FRFC
Researchers
http://hdl.handle.net/2268/122181

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