Reference : Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP

	Document type :	Parts of books : Contribution to collective works
	Discipline(s) :	Physical, chemical, mathematical & earth Sciences : Chemistry
	To cite this reference:	http://hdl.handle.net/2268/115190

Title :	Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP
Language :	English
Author, co-author :	Borguet, Yannick [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique]
	Delaude, Lionel [Université de Liège - ULg > Département de chimie (sciences) > Chimie organométallique et catalyse homogène]
	Demonceau, Albert [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique]
Publication date :	2012
Main document title :	Progress in Controlled Radical Polymerization: Mechanisms and Techniques
Editor :	Matyjaszewski, Krysztof
	Sumerlin, Brent S.
	Tsarevsky, Nicolay V.
Publisher :	American Chemical Society
Collection and collection volume :	ACS Symposium Series 1100
Pages :	115-132
ISBN :	9780841226999
City :	Washington
Country :	USA
Abstract :	[en] The catalytic activity of a series of homobimetallic ruthenium complexes of the type [(p-cymene)Ru(μ-Cl)3RuCl(L)(L′)] [L = C2H4 or a vinylidene ligand (=C=CHR); L′ = PPh3, PCy3, or an N-heterocyclic carbene ligand] was determined by investigating the atom transfer radical polymerisation of methyl methacrylate. The results clearly demonstrate that the ligands strongly affect the ability of the ruthenium complexes to favour the occurrence of a well-behaved ATRP.
Target :	Researchers ; Professionals
Permalink :	http://hdl.handle.net/2268/115190
DOI :	10.1021/bk-2012-1100.ch008

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