Reference : Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP
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Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/115190
Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP
English
Borguet, Yannick mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique]
Delaude, Lionel mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie organométallique et catalyse homogène]
Demonceau, Albert mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique]
2012
Progress in Controlled Radical Polymerization: Mechanisms and Techniques
Matyjaszewski, Krysztof
Sumerlin, Brent S.
Tsarevsky, Nicolay V.
American Chemical Society
ACS Symposium Series 1100
115-132
9780841226999
Washington
USA
[en] The catalytic activity of a series of homobimetallic ruthenium complexes of the type [(p-cymene)Ru(μ-Cl)3RuCl(L)(L′)] [L = C2H4 or a vinylidene ligand (=C=CHR); L′ = PPh3, PCy3, or an N-heterocyclic carbene ligand] was determined by investigating the atom transfer radical polymerisation of methyl methacrylate. The results clearly demonstrate that the ligands strongly affect the ability of the ruthenium complexes to favour the occurrence of a well-behaved ATRP.
Researchers ; Professionals
http://hdl.handle.net/2268/115190
10.1021/bk-2012-1100.ch008

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