Reference : Preparation of Spherical Submicronic Barium Zirconate particles in Highly Basic Solut...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
http://hdl.handle.net/2268/112437
Preparation of Spherical Submicronic Barium Zirconate particles in Highly Basic Solution below 100°C
English
Boschini, Frédéric mailto [Université de Liège - ULg > Département de chimie (sciences) > Plateforme APTIS >]
Cloots, Rudi mailto [Université de Liège - ULg > Département de chimie (sciences) > LCIS - GreenMAT >]
Vertruyen, Bénédicte mailto [Université de Liège - ULg > Département de chimie (sciences) > Chimie inorganique structurale >]
2011
IOP Conference Series: Materials Science and Engineering
IOP Publishing
Yes (verified by ORBi)
International
1757-8981
1757-899X
Bristol
[en] Synthesis ; barium zirconate ; submicronic particles
[en] In this study, a new method has been developed to produce pure crystalline BaZrO3 powders from Ba+Zr solution or weakly soluble reactants by using precipitation route in highly basic aqueous solution. The influence of several synthesis parameters is studied. At high OH- concentration ([NaOH] = 20 mol/l), it is possible to obtain the well-crystallized stoichiometric perovskite phase at relatively low temperature (~80°C), after a short reaction time (15 minutes) and without requiring any precaution to avoid the presence of CO2. This synthesis method yields spherical particles, whose size can be controlled by changing the concentration of the Ba+Zr solution. No calcination treatment is necessary since the precipitate is crystalline. Suitable choice of the synthesis parameters ([NaOH] = 20 mol/l, [Ba+Zr] = 1 mol/l, reaction time = 15 minutes) yields a sub-micron precipitate.
http://hdl.handle.net/2268/112437

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