Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

Baute, Noëlle; Geskin, Victor M; Lazzaroni, Roberto; Brédas, Jean-Luc; Arys, Xavier; Jonas, Alain M; Legras, Roger; Poleunis, Claude; Bertrand, Patrick; Jérôme, Robert; Jérôme, Christine

doi:10.1515/epoly.2004.4.1.703

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Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

Baute, Noëlle; Geskin, Victor M; Lazzaroni, Roberto et al.

2004 • In e-Polymers, (63), p. 1-20

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/11089

DOI
10.1515/epoly.2004.4.1.703

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Keywords :

electropolymerization; electrografting

Abstract :

[en] Adherent thin polymer films have been prepared by sequential electrodeposition of ethyl acrylate (EA) and acrylonitrile (AN) onto nickel. Their composition has been studied by IR spectroscopy and time of flight-secondary ion mass spectrometry. Morphology and thickness have been analyzed by atomic force microscopy and ellipsometry, respectively, and compared to single component films of PEA and PAN. No microphase separation was detected in the mixed PEA/PAN films. These show a granular morphology comparable to that of PAN films. The grains contain the two constitutive polymers, as confirmed by the selective thermal degradation of PEA.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Baute, Noëlle; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Geskin, Victor M; University of Mons-Hainaut (UMH) > Centre de Recherche en Electronique et Photonique Moléculaires

Lazzaroni, Roberto; University of Mons-Hainaut (UMH) > Centre de Recherche en Electronique et Photonique Moléculaires

Brédas, Jean-Luc; Centre de Recherche en Electronique et Photonique Moléculaires > Centre de Recherche en Electronique et Photonique Moléculaires

Arys, Xavier; Université catholique de Louvain (UCL) > Unité de Physique et de Chimie des Hauts Polymères

Jonas, Alain M; Université catholique de Louvain (UCL) > Unité de Physique et de Chimie des Hauts Polymères

Legras, Roger; Université catholique de Louvain (UCL) > Unité de Physique et de Chimie des Hauts Polymères

Poleunis, Claude; Université catholique de Louvain (UCL) > Laboratoire de Physico-Chimie et de Physique des Matériaux (PCPM)

Bertrand, Patrick; Université catholique de Louvain (UCL) > Laboratoire de Physico-Chimie et de Physique des Matériaux (PCPM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel

Publication date :

07 October 2004

Journal title :

e-Polymers

eISSN :

1618-7229

Publisher :

European Polymer Federation, Strasbourg, France

Issue :

Pages :

1-20

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.e-polymers.org/journal/list.cfm#

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
La "Communauté Française de Belgique"
La "Région Wallone"

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