Reference : Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonit...
Scientific journals : Article
Physical, chemical, mathematical & earth Sciences : Chemistry
Engineering, computing & technology : Materials science & engineering
http://hdl.handle.net/2268/11089
Electrodeposition of mixed adherent thin films of poly(ethyl acrylate) and polyacrylonitrile onto nickel
English
Baute, Noëlle [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Geskin, Victor M [University of Mons-Hainaut (UMH) > > Centre de Recherche en Electronique et Photonique Moléculaires > >]
Lazzaroni, Roberto [University of Mons-Hainaut (UMH) > > Centre de Recherche en Electronique et Photonique Moléculaires > >]
Brédas, Jean-Luc [Centre de Recherche en Electronique et Photonique Moléculaires > > Centre de Recherche en Electronique et Photonique Moléculaires > >]
Arys, Xavier [Université catholique de Louvain (UCL) > > Unité de Physique et de Chimie des Hauts Polymères > >]
Jonas, Alain M [Université catholique de Louvain (UCL) > > Unité de Physique et de Chimie des Hauts Polymères > >]
Legras, Roger [Université catholique de Louvain (UCL) > > Unité de Physique et de Chimie des Hauts Polymères > >]
Poleunis, Claude [Université catholique de Louvain (UCL) > > Laboratoire de Physico-Chimie et de Physique des Matériaux (PCPM) > >]
Bertrand, Patrick [Université catholique de Louvain (UCL) > > Laboratoire de Physico-Chimie et de Physique des Matériaux (PCPM) > >]
Jérôme, Robert mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
Jérôme, Christine mailto [University of Liège (ULg) > Department of Chemistry > Center for Education and Research on Macromolecules (CERM) > >]
7-Oct-2004
e-Polymers
European Polymer Federation
63
1-20
Yes
International
1618-7229
Strasbourg
[en] electropolymerization ; electrografting
[en] Adherent thin polymer films have been prepared by sequential electrodeposition of ethyl acrylate (EA) and acrylonitrile (AN) onto nickel. Their composition has been studied by IR spectroscopy and time of flight-secondary ion mass spectrometry. Morphology and thickness have been analyzed by atomic force microscopy and ellipsometry, respectively, and compared to single component films of PEA and PAN. No microphase separation was detected in the mixed PEA/PAN films. These show a granular morphology comparable to that of PAN films. The grains contain the two constitutive polymers, as confirmed by the selective thermal degradation of PEA.
Center for Education and Research on Macromolecules (CERM)
Politique Scientifique Fédérale (Belgique) = Belgian Federal Science Policy ; Fonds de la Recherche Scientifique (Communauté française de Belgique) - F.R.S.-FNRS ; La "Communauté Française de Belgique" ; La "Région Wallone"
Researchers
http://hdl.handle.net/2268/11089
http://www.e-polymers.org/journal/list.cfm#

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