Article (Scientific journals)
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide
Grignard, Bruno; Jérôme, Christine; Calberg, Cédric et al.
2008In European Polymer Journal, 44 (3), p. 861-871
Peer Reviewed verified by ORBi
 

Files


Full Text
Grignard B 2008 Eur Polym J 861.pdf
Author postprint (225.09 kB)
Download
Full Text Parts
Grignard B 2008 Eur Polym J 861.pdf
Publisher postprint (326.2 kB)
Request a copy

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
green technology; radical polymerization; atom transfer radical polymerization (ATRP); (meth)acrylate
Abstract :
[en] Macromolecular fluorinated ligands were prepared according to a three-step strategy that consists of the random copolymerization of heptadecafluorodecyl acrylate and 2-hydroxyethylacrylate, followed by the esterification of the pendant hydroxyl groups with acryloyl chloride and the Michael-type addition of tetraethyldiethylenetriamine onto the acrylic double bonds of the polymeric chains. These fluorinated macroligands were successfully used in the atom transfer radical polymerization of MMA catalyzed by a copper salt in a fluorinated solvent. The polymerization control was analyzed in relation to the copper salt, the initiator and the molecular weight and composition of the macroligand before being extended to the heterogeneous ATRP of MMA in scCO2.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Grignard, Bruno ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Calberg, Cédric ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide
Publication date :
March 2008
Journal title :
European Polymer Journal
ISSN :
0014-3057
eISSN :
1873-1945
Publisher :
Elsevier Science
Volume :
44
Issue :
3
Pages :
861-871
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE]
Commentary :
The authors acknowledge European Polymer Journal (Elsevier) for allowing them to archive this paper.
Available on ORBi :
since 11 April 2009

Statistics


Number of views
100 (8 by ULiège)
Number of downloads
299 (9 by ULiège)

Scopus citations®
 
32
Scopus citations®
without self-citations
25
OpenCitations
 
35

Bibliography


Similar publications



Contact ORBi