[en] Polymers have been widely used for the protection of metals against corrosion and for improving the performance of structural adhesive joints. In this contribution, the weakness and short-term durability of these polymer-metal interactions and some common approaches for alleviating this problem are briefly reviewed. Among the existing techniques, electrochemical processes offer the advantage of controlled interfacial reactions. Promising results have been reported by Strat-mann et al. and Le´cayon et al., who have emphasized the interest and opportunity to create strong chemical bonds between the organic coating and the metallic substrate. Their work is discussed in this review, along with results recently obtained in our group
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Baute, Noëlle; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Martinot, Lucien ; Université de Liège - ULiège > Department of Chemistry > Radiochemistry
Mertens, Marc; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Geskin, Viktor M; University of Mons-Hainaut (UMH) > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires
Lazzaroni, Roberto; University of Mons-Hainaut (UMH) > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires
Brédas, Jean-Luc; University of Mons-Hainaut (UMH) > Service de Chimie des Matériaux Nouveaux, Centre de Recherche en Electronique et Photonique Moléculaires
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Electrochemical strategies for the strengthening of polymer – metal interfaces
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
A. J. Kinloch, Adhesion and adhesives, Science and Technology, Chapman & Hall, London, 1987.
H. L. Gerhart, Ind. Eng. Chem. Prod. Res. Dev. 1978, 17, 1.
F. Deflorian, L. Fedrizzi, A. Locaspi, P. L. Bonora, Electrochim. Acta 1993, 38, 1945.
S. Maeda, T. Asai, S. Fujii, Y. Nomura, A. Nomoto, J. Adhes. Sci. Technol. 1988, 2, 271.
A. J. Kinloch, in: Polymer Surfaces and Interfaces (Eds.: W. J. Feast, H. S. Munro), New York, 1987, p. 75.
R. A. Dickie, in: Polymeric Materials for Corrosion Control (Eds.: R. A. Dickie, F. Floyd), ACS, Washington, 1986, p. 136.
J. W. Holubka, W. Chun, A. R. Krause, J. Shyu, in: Polymeric Materials for Corrosion Control (Eds.: R. A. Dickie, F. Floyd), ACS, Washington, 1986, p. 194.
E. L. Koehler, Corrosion, NACE 1977, 33, 209.
H. Leidheiser, Jr, W. Wang, L. Igetoft, Prog. Org. Coat. 1983, 11, 19.
H. Leidheiser, Jr, in: Polymeric Materials for Corrosion Control (Eds.: R. A. Dickie, F. Floyd), ACS, Washington, 1986, p. 124.
R. G. Schmidt, J. P. Bell, Adv. Polym. Sci. 1986, 75, 33-72.
A. G. Smith, R. A. Dickie, Ind. Eng. Chem. Prod. Res. Dev. 1978, 17, 42.
G. Trabanelli, V. Carassiti, Adv. Corros. Sci. Technol. 1970, 1, 147.
M. Stratmann, R. Feser, A. Leng, Electrochim. Acta 1994, 39, 1207-1214.
F. Nitschke, J. Adhesion Technol. 1990, 4, 41.
P. Benoist, G. Legeay, R. Morello, F. Poncin-Epaillard, Eur. Polym. J. 1992, 28, 1383.
K. Doblofer, Bull. Electrochem. 1992, 8, 73.
M. Stratmann, Adv. Mater. 1990, 2, 191.
C. Boiziau, G. Lécayon, La Recherche 1988, 19, 888.
R. W. Murray, Acc. Chem. Res. 1980, 13, 135.
E. Katz, H. L. Shmidt, J. Electroanal. Chem. 1993, 360, 337.
M. S. Wrighton, Science 1986, 231, 32.
E. P. Pluedemann, in Encyclopedia of Polymer Sciences and Engineering, 2nd ed., Wiley Intersciences, 1986, vol. 4, p. 284.
M. Gettings, F. S. Baker, A. J. Kinloch, J. Appl. Polym. Sci. 1977, 21, 2375.
M. Volmer, M. Stratmann, H. Viefhaus, Surf. Interf. Anal. 1990, 16, 278.
M. Volmer-Uebing, M. Stratmann, Appl. Surf. Sci. 1992, 55, 19.
R. Losch, M. Stratmann, H. Viefhaus, Electrochim. Acta 1994, 39, 1215.
M. Itoh, H. Nishihara, K. Aramaki, J. Electrochem. Soc. 1994, 141, 2018.
J. W. Breitenbach, C. Srna, Pure Appl. Chem. 1962, 4, 245.
Yamazaki, Adv. Polym. Sci. 1969, 6, 377.
G. Parravano, Organic Electrochemistry, Marcel Dekker New York, 1973, p. 947-974.
B. L. Funt, J. Tanner, Tech. Electroorg. Synth. 1975, 5, 559.
E. Dineen, T. C. Schwan, L. C. Wilson, Trans. Electrochem. Soc 1949, 96, 226.
W. B. Smith, H. G. Gilde, J. Am. Chem. Soc. 1960, 82, 659.
J. Y Yang, W. E. McEwen, J. Kleinberg, J. Am. Chem. Soc. 1957, 79, 5833.
B. L. Funt, K. C. Yu, J. Polym. Sci. 1962, 62, 359.
Yamazaki, I. Tanaka, S. Nakahama, J. Macromol. Sci. Chem 1968, A2, 1121.
F. S. Teng, R. Mahaligan, R. V. Subramanian, R. A. V. Raff, J. Electrochem. Soc. 1977, 124, 995.
G. Mengoli, Adv. Polym. Sci. 1979, 33, 1.
G. Mengoli, S. Daolio, U. Giulio, C. Polonari, J. Appl. Polym. Sci. 1979, 23, 2117.
B. K. Garg, R. A. V. Raff, R. V. Subramanian, J. Appl. Polym. Sci. 1978, 22(1), 65.
R. V. Subramanian, Adv. Polym. Sci. 1979, 33, 34.
R. Dobreva, J. Sledj, F. Schue, J. A. Alary, L'actualité Chimique, Janvier/Fevrier 1993, p. 60.
C. P. Yang, C. Y. Ting, J. Appl. Polym. Sci. 1993, 49, 1019.
K. Arlt, Electrochim. Acta 1994, 39, 1189.
G. Mengoli, B. M. Tidswell, Polymer 1975, 16, 881.
T. Asahara, M. Seno, M. Tsuchiya, Kinzunku Hyomen Gijutsu 1969, 20, 617.
L. A Korschikov, L. I. Kravtsova, V. D. Bezugly, Electrokhimiya 1974, 10, 990.
F. Bruno, M. C. Phan, J. E. Dubois, J. Chim. Phys. 1975, 72, 490.
W. Yuan, J. O. Iroh, Trends Polymer Sci. 1993, 1, 388.
R. V. Subramanian, J. J Jakubowski, Polym. Eng. Sci. 1978, 18, 590.
L. E. A Berlouis, D. J. Schriffrin, Trans. Inst. Met. Finish 1986, 64, 42.
G. Lécayon, Y. Bouizem, C. Le Gressus, C. Reynaud, C. Boiziau, C. Juret, Chem. Phys. Lett. 1982, 91, 506.
C. Boiziau, S. Leroy, C. Reynaud, G. Lécayon, C. Le Gressus, P. Viel, J. Adhesion 1987, 23, 21.
A. L. Mc Clellan, Tables of Experimental Dipole Moments, W. H. Freeman and Co., San Francisco, 1963.
P. Viel, S. de Cayeux, G. Lécayon, Surf. Interf. Anal. 1993, 20, 468.
D. Mathieu, M. Defranceschy, P. Viel, G. Lécayon, J. Delhalle, Polym. Solid Interf., Proc. Int. Conf., 1st, Institute of Physics, Bristol, 1992, p. 379.
Y. Bouizem, F. Chao, M. Costa, A. Tadjedinne, G. Lécayon, J. Electroanal. Chem. 1984, 172, 101.
P. Jonnard, F. Vergand, P. F. Staub, C. Bonnelle, G. Deniau, C. Bureau, G. Lécayon, Surf. Interface Anal. 1996, 24, 339.
J. Tansuy, P. Viel, G. Deniau, G. Lécayon, Electrochim. Acta 1993, 38, 1501.
B. L. Funt, F. D. Williams, J. Polym. Sci. 1964, A2, 865.
B. Yurttas, L. Toppare, U. Akbulut, J. Macromol. Sci. 1988, A25, 219.
S. N. Bhadani, Q. Ansari, S. K. S Gupta, J. Appl. Polym. Sci. 1992, 44, 121.
P. Viel, Ph. D. Thesis, Université de Paris VI, France, 1990.
G. Hennico, J. Delhalle, E. Younang, M. Defranceschi, G. Lécayon, C. Boiziau, Int. J. Quantum Chem., Quantum Chem. Symp. 1991, 25, 507.
G. Lécayon, C. Le Gressus, A. Le Moël, Eur. Patent no. 0038244, 1981.
G. Lécayon, A. Le Moël, C. Le Gressus; Vide, les couches minces, 1980, vol. 201, p. 638.
M. Mertens, Ph. D. Thesis, University of Liège, Belgium, 1995.
C. Fredrikson, R. Lazzaroni, J. L. Brédas, M. Mertens, R. Jérôme, Chem. Phys. Lett. 1996, 258, 356.
J. D. B. Smith, D. C. Phillips, D. H. Davies, J. Polym. Sci., Chem. Ed. 1977, 15, 1555.
C. Calberg, M. Mertens, R. Jérôme, X. Arys, A. M. Jonas, R. Legras, Thin Solid Films 1997, 310, 148-155.
R. Jérôme, M. Mertens, L. Martinot, Adv. Mater. 1995, 7, 807.
M. Mertens, C. Calberg, L. Martinot, R. Jérôme, Macromolecules 1996, 29, 4910-4918.
V. Geskin, R. Lazzaroni, M. Mertens, R. Jérôme, J. L. Brédas, J .Chem. Phys. 1996, 105, 3278.
C. Bureau, G. Deniau, P. Viel, G. Lécayon, Macromolecules 1997, 30, 333.
C. Calberg, M. Mertens, N. Baute, R. Jérôme, V. Carlier, M. Sclavons, R. Legras, J. Polym. Sci., Part B: Polym. Phys 1998, 36, 543-553.
L. Martinot, M. Mertens, L. Lopes, P. Faack, M. Krausch, J. Guillaume, G. Ghitti, J. Marien, J. Riga, R. Jérôme, J. Schrijnemackers, Radiochim. Acta 1996, 75, 111-119.
F. Houzé, L. Boyer, S. Noël, P. Viel, G. Lécayon, J-M. Bourin, Synth. Met. 1994, 62, 207.
M. Mertens, C. Calberg, R. Jérôme, L. Martinot, J. Schrijnemackers, J. Guillaume, Revue des Historiens de l'Art, des Archéologues, des Musicologues et des Orientalistes de l'Université de Liège, 1997, p. 16.
N. Baute, P. Teyssié, L. Martinot, M. Mertens, P. Dubois, R. Jérôme, Eur. J. Inorg. Chem. 1998, 1711.
X. Crispin, R. Lazzaroni, V. Geskin, N. Baute, P. Dubois, R. Jérôme, J. L. Brédas, J. Am. Chem. Soc. 1999, 121, 176.
N. Baute, L. Martinot, R. Jérôme, J. Electroanal. Chem. 1999, 472, 83.
N. Baute, Ph. D. Thesis, University of Liege, 1999.
N. Baute, V. Geskin, R. Lazzaroni, J. L. Brédas, X. Arys, A. Jonas, R. Legras, C. Poleunis, P. Bertrand, R. Jérôme, Thin Solid Films, submitted.
C. Jérôme, V. M. Geskin, R. Lazzaroni, J. L. Brédas, A. Thibaut, C. Calberg, I. Bodart, M. Mertens, L. Martinot, D. Rodrigue, J. Riga, R. Jérôme, Chem. Mater., submitted.
C. Jérôme, R. Jérôme, Angew. Chem. Int. Ed. 1998, 37, 2488.
D. E. Labaye, Ph. D. Thesis, University of Liege, in preparation.
G. Deniau, G. Lécayon, C. Bureau, J. Tanguy, in: Protective Coatings and Thin Films (Eds.: Y. Pauleau, P. B. Barna), Kluwer, Dordrecht (Proceedings of the Nato Advanced Research Workshop held in Portimao, Portugal, 1996), 1997, p. 265.
G. Deniau, G. Lécayon, P. Viel, G. Zalczer, C. Boiziau, G. Hennico, J. Delhalle, J. Chem. Soc., Perkin Trans. 2 1990, 1433.
J. Tanguy, G. Deniau, C. Auge, G. Zalczer, G. Lécayon, J. Electroanal. Chem. 1994, 337, 114.
J. Tanguy, G. Deniau, G. Zalczer, G. Lécayon, J. Electroanal. Chem. 1996, 417, 175.
G. Deniau, P. Viel, G. Lécayon, Surf. Interf. Anal. 1992, 18, 443.
