Full-electrochemical preparation of conducting/insulating binary polymer films

Jérôme, Christine; Geskin, V.; Lazzaroni, Roberto; Brédas, Jean-Luc; Thibaut, Anne; Calberg, Cédric; Bodart, Isabelle; Mertens, Marc; Martinot, Lucien; Rodrigue, Dominique; Riga, J.; Jérôme, Robert

doi:10.1021/cm001124d

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Article (Scientific journals)

Full-electrochemical preparation of conducting/insulating binary polymer films

Jérôme, Christine; Geskin, V.; Lazzaroni, Roberto et al.

2001 • In Chemistry of Materials, 13 (5), p. 1656-1664

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/10205

DOI
10.1021/cm001124d

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Keywords :

electropolymerization; conjugated polymer

Abstract :

[en] Binary polymer films consisting of an insulating polymer and a conducting polymer have been successfully prepared by sequential electropolymerization of the parent monomers. The insulating polymer (polyacrylonitrile or polyethylacrylate) is formed under cathodic polarization in a potential range where the growing chains are chemically grafted onto the nickel or carbon electrode. The conducting polymer (polybithiophene or polypyrrole) is formed by electrooxidation of the parent monomer. The electrochemical reactions and the electrochemical properties of the films have been analyzed by cyclic voltammetry and chronoamperometry. The influence of the main experimental parameters on the composition and morphology of the films has been investigated by X-ray photoelectron spectroscopy and atomic force microscopy. This approach strongly improves the adhesion of the conducting polymer as a result of its combination with the grafted polyacrylonitrile. This combination of insulating and conducting polymers is a way to tune the electroactivity of the conjugated chains.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Jérôme, Christine ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Geskin, V.; University of Mons-Hainaut (UMH)

Lazzaroni, Roberto; University of Mons-Hainaut (UMH)

Brédas, Jean-Luc; The University of Arizona, Tucson, USA

Thibaut, Anne; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Calberg, Cédric ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Bodart, Isabelle; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Mertens, Marc; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Martinot, Lucien ; Université de Liège - ULiège > Department of Chemistry > Coordination Chemistry and Radiochemistry

Rodrigue, Dominique; Facultés Universitaires Notre-Dame de la Paix, Namur (FUNDP) > Laboratoire Interdépartemental de Spectroscopie Electronique

Riga, J.; Facultés Universitaires Notre-Dame de la Paix, Namur (FUNDP) > Laboratoire Interdépartemental de Spectroscopie Electronique

Jérôme, Robert ; Université de Liège - ULiège > Centre d'études et de rech. sur les macromolécules (CERM)

Language :

English

Title :

Full-electrochemical preparation of conducting/insulating binary polymer films

Publication date :

May 2001

Journal title :

Chemistry of Materials

ISSN :

0897-4756

eISSN :

1520-5002

Publisher :

American Chemical Society

Volume :

Issue :

Pages :

1656-1664

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/cm001124d

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]

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