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See detailPreoptic glutamate and estradiol release during male sexual behavior
de Bournonville, Catherine ULg; de Bournonville, Marie-Pierre ULg; Aourz, Najat et al

Poster (2016, November)

Beside its long-term control by steroids, male sexual behavior is also modulated by neuroestrogens in a dynamic way (within minutes) in a number of species ranging from fishes to mammals. Studies in male ... [more ▼]

Beside its long-term control by steroids, male sexual behavior is also modulated by neuroestrogens in a dynamic way (within minutes) in a number of species ranging from fishes to mammals. Studies in male Japanese quail have also identified following exposure to a receptive female a rapid decrease in the activity of brain aromatase (AA) the enzyme responsible for the conversion of androgens into estrogens. These effects occur mainly within the medial preoptic nucleus (POM), a sexually dimorphic structure of the preoptic area that plays a key role in the activation of male sexual behavior and contains the highest AA in the brain. In vitro studies demonstrated that AA can be rapidly inhibited by calcium-dependent phosphorylations of the enzyme triggered by the activation of AMPA and kainate receptors. We confirmed here this rapid effect of glutamate on AA by injecting kainate in the POM of anesthetized males and measuring AA in the tissue after brain collection. AA in POM was inhibited in the kainate-injected hemisphere compared to the control hemisphere injected with vehicle. In a second experiment, we showed by in vivo microdialysis that glutamate is released in POM during copulation. These results thus suggest that glutamate controls dynamic changes of AA that occur in the brain during sexual interactions. To confirm that the decrease in AA leads to an actual reduction of local estradiol concentration, we quantified via microdialysis and radioimmunoassay changes in estradiol concentration in the male POM during sexual interactions with a female. Surprisingly, a dramatic elevation of estradiol was observed during copulation. Estradiol has been shown to enhance acutely male sexual motivation, therefore the function of its increase in the POM could be to maintain motivation during the entire sexual encounter. The decrease of AA observed ex vivo after copulation would then reflect a compensatory mechanism to restore baseline pre-copulatory conditions. Importantly, these results highlight that although long-term changes in AA are often used as a proxy for local estradiol concentrations, these two measures can show major short-term discrepancies possibly reflecting variations in estrogen turnover. [less ▲]

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See detailSpeech style manipulations in dysarthria in French-speaking children: Acoustic findings.
Ancelle, Josephine; Moya Gale, G.; Hetrick, B et al

Poster (2016, November)

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See detailThe influence of background noise on vocal loading parameters in music theory teachers
Schiller, Isabel ULg; Morsomme, Dominique ULg; Sfez, Lou et al

Poster (2016, August 23)

Background: Music theory teachers, who teach rhythm, singing and other music-related skills and topics, depend greatly on a well-functioning voice. Unlike other schoolteachers, who primarily use their ... [more ▼]

Background: Music theory teachers, who teach rhythm, singing and other music-related skills and topics, depend greatly on a well-functioning voice. Unlike other schoolteachers, who primarily use their voice as a pedagogic tool, music theory teachers also use it as an instrument. Furthermore, they often engage in vocally demanding free-time activities requiring a singing voice. To date, few studies have specifically looked at the voice use of music theory teachers. This study aims (1) to measure the background noise level and the amount of vocal loading affecting this specific population, and (2) to describe the influence of background noise on vocal loading parameters. Methods: Thirteen French-speaking music theory teachers (9 females and 4 males) working in a music school were monitored for one workweek, using the VoxLog voice dosimeter (Sonvox). To investigate the professional and extra-professional environments, all subjects wore the dosimeter from early morning until the end of the day. The parameters analysed were background noise level, duration of phonation, sound pressure level (SPL) and fundamental frequency (F0) of voice. Results: Overall, the mean background noise level was 75.2 dB (SD=5.4). We measured higher background noise level at work (mean=78.2 dB, SD=5.8) than in the extra-professional environment (mean=72.2 dB, SD=5.2). As expected, a rise in background noise was accompanied by a significant rise in voice SPL in both males and females (r=.61, p<.001). A significant correlation between background noise and F0 was found in females (r=.41, p=.002), but not in males (r=.39, p=.055). Furthermore, our data exhibit a significant correlation between background noise and duration of phonation (r=.05, p<.001). Conclusion: Our data suggest, that in class, music theory teachers must cope with background noise levels that dramatically exceed the limit of 35 dB recommended by the WHO (Inserm, 2006). High background noise levels lead to an increase in voice SPL, a phenomenon known as the Lombard effect (Inserm, 2006). In female subjects, we also observed a rise in F0 further to high background noise. Like Ternström, Södersten, and Bohman’s (2002) study, our data indicate that high background noise levels increase the duration of phonation. In a noisy environment, subjects seem to prolong the voiced segments of speech to make themselves understood. In other words, high background noise levels result in higher vocal loading. In the long run, this may increase the risk of voice disorders such as hyperfunctional dysphonia or vocal fold pathologies consecutive to repeated microtrauma in music theory teachers. [less ▲]

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See detailA Comparison between four Techniques to Measure Cardiac Output
Pironet, Antoine ULg; Dauby, Pierre ULg; Chase, J. Geoffrey et al

Poster (2016, August 17)

Detailed reference viewed: 13 (2 ULg)
See detailCASTLE4D : The castle of Franchimont
Luczfalvy Jancsó, Andrea ULg; Hoffsummer, Patrick ULg; Billen, Roland ULg et al

Poster (2016, August 16)

Detailed reference viewed: 13 (3 ULg)
See detailTechniques et Méthodes nucléaires : Application de la Spectrométrie Gamma au Cameroun
Moyo N., Maurice; Kayo, Steve; Ngelem M., Eric J. et al

Poster (2016, August 04)

L’imaginaire populaire est de plus en plus pessimiste au sujet du mot nucléaire, utilisées selon eux, uniquement pour détruire, en cas de guerre. Une idée reçue, mais presque imposée par l'attitude des ... [more ▼]

L’imaginaire populaire est de plus en plus pessimiste au sujet du mot nucléaire, utilisées selon eux, uniquement pour détruire, en cas de guerre. Une idée reçue, mais presque imposée par l'attitude des pays développés qui donnent l'impression de recourir au nucléaire, le plus souvent, à des fins militaires. Pourtant, les applications du nucléaire sont utiles dans des domaines aussi variés que l'agriculture, la médecine, la détection des fuites dans les barrages, la surveillance de la qualité de l'air, des eaux, des sols, des matériaux de construction, des denrées alimentaires etc. Au Cameroun, l'utilisation des rayonnements ionisants (énergie nucléaire) est en pleine croissance. Ce, spécifiquement dans les domaines médical et industriel. La radioprotection est de plus en plus l’objet des recherches et des mesures au Cameroun. Des techniques d’analyse nucléaires sont également utilisées pour déterminer les risques radiologiques lies aux rayonnements naturels provenant de l’environnement. Dans ce cadre, l’unité de recherche « Physique Fondamentale » de l’université de Douala en collaboration avec l’ANRP (Agence Nationale de RadioProtection) utilise la spectrométrie gamma pour quantifier et qualifier l’exposition des camerounais aux rayonnements. Deux mémoires de master ont à cette occasion révéler le niveau d’exposition due aux rayonnements provenant du sol de l’Université de Douala d’une part et d’autre part l’exposition due aux matériaux de construction dans la ville de Douala. Les études sur les matériaux de construction (ciment utilisé dans la ville de Douala) ont permis d’observer que l’activité spécifique dans les échantillons de ciment varie d’un radionucléide à l’autre. L’estimation des paramètres radiologiques comme (l’activité du radium équivalent Raeq, l’indice du risque externe (Hex) et interne (Hin), le taux de dose absorbée dans l’air et la dose effective annuelle (AEDE) ont montré que l’utilisation comme matériaux de construction du ciment analysé était sans risque particulier. [less ▲]

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See detailProofing & Reduction Strategies Used by Emergency Residents to Manage Fatigue-related Risk
Berastegui, Pierre ULg; Ghuysen, Alexandre ULg; Nyssen, Anne-Sophie ULg

Poster (2016, July 29)

Fatigue and sleep loss are typically associated with psychomotor and cognitive impairment resulting in poorer task performance. Most of these studies are conducted in controlled settings and involve the ... [more ▼]

Fatigue and sleep loss are typically associated with psychomotor and cognitive impairment resulting in poorer task performance. Most of these studies are conducted in controlled settings and involve the completion of experimental tasks. Only a few field studies involving exhausted residents have been conducted over the past decade, and they yielded to contradictory results (Ellman et al., 2004). One of the key factors that could be involved in the non-linear relationship between fatigue and performance in specific work context reside in the mobilization of Fatigue Proofing Strategies. FPS are adaptive and protective risk-reduction behaviors that improve the resilience of a system of work (Dawson et al., 2012). In this study, we aimed to identify and classify proofing strategies mobilized by EMS residents using an inductive content analysis approach. EMS residents reported a range of strategies for reducing subjective level of sleepiness (reduction strategies, n=15) or managing its consequences (proofing strategies, n=17). Content analysis yielded to three sub-categories of proofing strategies: Behavioral Compensation (n=8), Error’s Opportunity Reduction (n=5) and Error’s Consequences Mitigation (n=4). Our results show that EMS residents use both types of strategies although none of the proofing strategies were part of their training program. Despite the current informal use, there is significant potential for implementation of more formal processes. [less ▲]

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See detailBiofilm fermentation for the production of insect pathogenic fungi
Bawin, Thomas ULg; Francis, Frédéric ULg; Delvigne, Frank ULg

Poster (2016, July 27)

Currently, integrated pest management that aims to reduce the use of synthetic insecticides by considering all appropriate alternative methods, is promoted. In that context, insect pathogenic fungi could ... [more ▼]

Currently, integrated pest management that aims to reduce the use of synthetic insecticides by considering all appropriate alternative methods, is promoted. In that context, insect pathogenic fungi could be developed as biopesticides in two ways: spores but also metabolites that are recognized as virulence factors. Targeting adequate fermentation method is an important requirement to obtain fungal products (i.e. spores, enzymes and metabolites) of biotechnological interest. The 'Microbial Processes and Interactions' laboratory has developed an innovative fermentation technology (referred to as ‘biofilm fermentation’) involving the growth of fungal biomass on inert supports that are immersed in a liquid nutrient medium. Confining fungal biomass on immersed inert structures provides a hybrid production system aiming to keep a solid-state physiology for sporulation and secretion of metabolites while controlling fermentation parameters. This research project proposes to transfer this technology to culture insect pathogenic fungi, such as Metarhizium anisopliae, for the production of spores and insecticidal metabolites. Development stages include the qualitative and quantitative characterization of its impact on insecticidal products as well as scale-up to industrial level. [less ▲]

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See detailAharonov-Bohm oscillations of bosonic matter-wave beams in the presence of disorder and interaction
Chrétien, Renaud ULg; Dujardin, Julien; Petitjean, Cyril ULg et al

Poster (2016, July 27)

We study the one-dimensional (1D) transport properties of an ultracold gas of Bose-Einstein condensed atoms through Aharonov-Bohm (AB) rings. Our system consists of a Bose-Einstein condensate (BEC) that ... [more ▼]

We study the one-dimensional (1D) transport properties of an ultracold gas of Bose-Einstein condensed atoms through Aharonov-Bohm (AB) rings. Our system consists of a Bose-Einstein condensate (BEC) that is outcoupled from a magnetic trap into a 1D waveguide which is made of two semi-infinite leads that join a ring geometry exposed to a synthetic magnetic flux φ. We specifically investigate the effects both of a disorder potential and of a small atom-atom contact interaction strength on the AB oscillations. The main numerical tools that we use for this purpose are a mean-field Gross-Pitaevskii (GP) description and the truncated Wigner (tW) method. We find that a correlated disorder suppress the AB oscillations leaving thereby place to Aronov-Al’tshuler-Spivak (AAS) oscillations. The competition between disorder and interaction leads to a peak inversion at Φ = π, that is a signature of a coherent backscattering (CBS) peak inversion. This is confirmed by truncated Wigner simulations. [less ▲]

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See detailQuantitative characterization and calibration of salt water intrusion models with electrical resistivity tomography
Beaujean, Jean; Hermans, Thomas ULg; Vandenbohede, Alexander et al

Poster (2016, July 26)

Groundwater quality and coastal ecosystems in coastal areas are among the most vulnerable as they are threatened by excessive groundwater withdrawals, sea level rise and storm events potentially leading ... [more ▼]

Groundwater quality and coastal ecosystems in coastal areas are among the most vulnerable as they are threatened by excessive groundwater withdrawals, sea level rise and storm events potentially leading to salt water intrusions or infiltration into fresh water aquifers. The environmental protection and sustainable management of these groundwater resources often involves the development and calibration of a groundwater model subsequently used to forecast the total dissolved solid content (TDS). However, groundwater models are often built based on a limited number of sparse data due to borehole availability. Geophysical methods can provide spatially and temporally distributed data for hydrogeological modeling at relatively limited costs. In particular, electrical resistivity tomography (ERT) is very sensitive to the conductivity of pore water which is directly linked to the TDS content. The method is therefore well-suited for the monitoring of salt water intrusions. However, the inversion of ERT data involves a regularization process so that the resulting tomogram is only an estimate of the true resistivity distribution, suffering from smoothing and varying resolution. In many cases, the interpretation of ERT remains qualitative and skewed. In this contribution, we propose two different methods to improve the information content that can be extracted from ERT data. First, we show with a field example from Belgium how alternative regularization methods can be developed to integrate independent information into the inversion process of ERT. This enabled us to obtain a resistivity distribution much closer to the one observed in validation boreholes. Then, a site-specific petrophysical relationship is used to derive the TDS content of the aquifer from ERT tomograms. This can be directly used as input in the calibration process of a hydrogeological model. We also show how it is possible to counterbalance the effect of resolution loss with depth for surface ERT by filtering the results relative to their sensitivity. We show that this filtering is mandatory to use the ERT-derived information for calibrating a hydrogeological model. In a second example, we show how a fully coupled inversion approach can be used to directly invert geophysical data together with hydrogeological data for the calibration of hydrogeological models. At each iteration of the calibration, the simulated TDS content is transformed in a resistivity distribution using a parameterized petrophysical relationship and forward geophysical modeling yields the geophysical response. We show that this approach enables to better estimate the hydrogeological parameters of the simulated coastal aquifer than with an uncoupled approach if the conceptual model is sufficiently representative. With those two examples, we demonstrate the usefulness of ERT in the monitoring of salt water intrusions, both qualitatively to identify most vulnerable zones and quantitatively to estimate ERT-derived TDS contents or geophysical data and calibrate hydrogeological models. An innovative approach may consist in a conjunctive use of filtered geophysically-derived and geophysical data within the coupled hydrogeophysical inversion framework. Such an uncoupled-coupled approach based on a resolution threshold approach may offer a promising developing trend in hydrogeophysical inversion. [less ▲]

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See detailImpacts of entomopathogenic fungi on biology and behaviour of the invasive Brown Marmorated Stink Bug (Hemiptera, Pentatomidae)
Fingu Mabola, Junior Corneille ULg; Serteyn, Laurent ULg; Bawin, Thomas ULg et al

Poster (2016, July 25)

Halyomorpha halys St˚al (Hemiptera, Pentatomidae) is an invasive stink bug coming from Eastern Asia. Besides causing important yields losses in orchards, crop and vegetable fields, it overwinters inside ... [more ▼]

Halyomorpha halys St˚al (Hemiptera, Pentatomidae) is an invasive stink bug coming from Eastern Asia. Besides causing important yields losses in orchards, crop and vegetable fields, it overwinters inside houses as agglomerates of dozens. In Europe, this Brown Marmorated Stink Bug (BMSB) was accidentally introduced in Switzerland in 2007 and has been later observed in surrounding countries (France, Italy, Germany). Based on the current US situation, we can reasonably fear that BMSB will have colonized most of Europe countries in less than a decade. If we already discern a few fungus strains that are efficient against BMSB, very little is known about their actual impact on the insect itself. So we investigated the in- fluence of a fungal infection on insect development parameters and behaviour. Olfactometry was settled to investigate the dispersion and aggregation trends, while electropenetography was used to assess the feeding behaviour. Our results will be discussed to present changes according to healthy/fungus-infected status, in relation to potential biological control for that pest. [less ▲]

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See detailThe verbal overshadowing effect in children and adults is unrelated to the specific content of descriptions
Vanootighem, Valentine ULg; Brédart, Serge ULg; Dehon, Hedwige ULg

Poster (2016, July 21)

Verbal descriptions of unfamiliar faces have been found to impair later identification of these faces in children and adults, a phenomenon known as the “verbal overshadowing effect” (VOE, Schooler and ... [more ▼]

Verbal descriptions of unfamiliar faces have been found to impair later identification of these faces in children and adults, a phenomenon known as the “verbal overshadowing effect” (VOE, Schooler and Engstler-Schooler, 1990). The present study thoroughly examined the person descriptive abilities of 7–8, 10–11, and 13–14-year-old children and adults and their influence on later identification performance. Our aim was to specifically assess the prediction of the “content” account suggesting that a verbal overshadowing arises because participants generate an inadequate verbal description and later rely upon it during retrieval. Results showed a verbal overshadowing effect in all age groups but neither accuracy, length nor content of descriptions were found to be associated with identification accuracy. [less ▲]

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See detailRecollection versus familiarity in normal aging and in mild cognitive impairment: Impact of test format.
Simon, Jessica ULg; Gilsoul, Jessica ULg; SALMON, Eric ULg et al

Poster (2016, July 18)

The aim of this study was to investigate the impact of test format on recollection and familiarity in normal aging and in MCI. Seventy young participants, 65 younger-old, 53 older-old, and 13 MCIs were ... [more ▼]

The aim of this study was to investigate the impact of test format on recollection and familiarity in normal aging and in MCI. Seventy young participants, 65 younger-old, 53 older-old, and 13 MCIs were presented with forced-choice and yes/no visual recognition memory tasks with the Remember/Know/Guess paradigm. The young people had better recognition performance than younger-old, who performed better than older-old and MCIs. Recollection and familiarity declined progressively in healthy aging. In MCI, recollection was more affected than familiarity, but patients demonstrated a more liberal use of familiarity. Finally, test format did not influence strongly the results. Young people used recollection more often in the forced-choice task compared to the yes/no task. [less ▲]

Detailed reference viewed: 28 (2 ULg)
See detailGamma-Ray Spectrometry: Experimental Measurement and Monte Carlo Simulation using GEANT4 toolkit
Guembou Shouop, Cébastien Joel ULg; Ndontchueng Moyo, Maurice; Chene, Grégoire ULg et al

Poster (2016, July 13)

Nowadays the precision in the measurement has become a challenge for physicists. That is why in recent decades, the interest is very granted to simulation. Since 1940, the method Monte Carlo is more ... [more ▼]

Nowadays the precision in the measurement has become a challenge for physicists. That is why in recent decades, the interest is very granted to simulation. Since 1940, the method Monte Carlo is more useful for validation and even for prediction of the results of the experiment. The aim of this study is to validate experimental models. Our laboratories are equipped with HPGe gamma spectrometers for measuring the natural radioactivity, it becomes interesting to compare and even to improve the performance of our system. Geant4 is used for the construction of the geometry of detection, the physics processes and the primary particles. First and prliminary result was prsented in this paper. [less ▲]

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See detailCounting time measurement and statistics in gamma spectrometry: the balance
Guembou Shouop, Cébastien Joel ULg; Ndontchueng Moyo, Maurice; Chene, Grégoire ULg et al

Poster (2016, July 11)

Nuclear counting statistics at high count rate are assessed on a γ-ray spectrometer set-up. Our typical gamma spectrometry system consists of a High Purity Germanium (HPGe) detector, liquid nitrogen ... [more ▼]

Nuclear counting statistics at high count rate are assessed on a γ-ray spectrometer set-up. Our typical gamma spectrometry system consists of a High Purity Germanium (HPGe) detector, liquid nitrogen cooling system, preamplifier, detector bias supply, linear amplifier, analog-to-digital converter (ADC), multichannel storage of the spectrum, and data readout devices. Although the system is powerful enough for background measurements, it is important, nowadays, to have a great statistical in short time measurement: which is a challenge for scientists. The purpose of this study was to determine the average time for gamma spectrometry measurement. To detect Uranium, Thorium and their respective daughters and Potassium series with a relative related error less than 1%, it was found that it is necessary to count during a minimum of 24 Hours (86,400 s). This result is in accordance to the literature with planar geometry detector. These results conduct us to make the following three guidelines for selecting the detector best suited for an application: 1. The more detector material available (germanium semi-conductor), the higher the full-energy peak efficiency. 2. The smaller the distance between the detector and the source material, the higher the full- energy peak efficiency. 3. While better resolution gives a better MDA, the resolution contributes only as the square root to the MDA value, whereas the MDA is proportional to the full-energy peak efficiency. This idea came to us by comparing the spectra of measuring radioactivity lasts for 12 hours in the day that does not fully covered the night spectra for the same sample. The conclusion after several investigations became clearer: to remove all effects of radiation from outside (earth, sun and universe) our system, it is necessary to measure the background for 24, 48 or 72 hours. In the same way, the samples have to be measures for 24, 48 or 72 hours to be safe to be purified the measurement (equality of day and night measurement). It is also possible to not use the background of the winter in summer. Depend to the energy of radionuclide we seek, it is clear that the most important steps of a gamma spectrometry measurement are the preparation of the sample and the calibration of the detector. [less ▲]

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See detailRestricted interests in autism with versus without speech onset delay : the importance of perceptually versus thematically organized interests
Chiodo, Liliane ULg; Majerus, Steve ULg; Eusèbe, Sandrine et al

Poster (2016, July 07)

Objectives : To explore whether autistic adults with vs without speech delay also differ in the perceptual vs thematic nature of their restricted interests.

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See detailNonlinear analysis of compliant mechanisms: application to tape springs
Dewalque, Florence ULg; Bruls, Olivier ULg

Poster (2016, July 07)

Brief summary of the mechanical behaviour of tape springs. Main results obtained by the means of finite element models. Description of the experimental set-up and results. See the extended abstract for ... [more ▼]

Brief summary of the mechanical behaviour of tape springs. Main results obtained by the means of finite element models. Description of the experimental set-up and results. See the extended abstract for more details. [less ▲]

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See detailDevelopment and optimization of a TD-GC/MS methodology for detection and quantifi cation of furan released in air using of an experimental design.
Alsafra, Zouheir ULg; Scholl, Georges ULg; Romain et al

Poster (2016, July 07)

In the aim of understanding the way in which human is exposed to furan present in the air of an occupational area, an analytical method of Thermal desorption-gas chromatography/Mass spectrometry (TD-GC/MS ... [more ▼]

In the aim of understanding the way in which human is exposed to furan present in the air of an occupational area, an analytical method of Thermal desorption-gas chromatography/Mass spectrometry (TD-GC/MS) has been developed and optimized using a Plackett–Burman experimental design. This method was then used to study the phenomena of diffusion of furan released in air from a contamination source. This source of furan is simply a coffee machine located in a closed controlled room. Results show that furan concentration increases quickly over time after turning on the coffee machine until reaching a maxima. Then it starts to decrease slowly. On the other hand, concentration of furan seems to be identical everywhere in the conditioned room in each moment. [less ▲]

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See detailNovel butanol pretreatment significantly improves delignification and saccharification of different lignocellulosic biomasses
Schmetz, Quentin ULg; Teramura, Hiroshi; Jacquet, Nicolas ULg et al

Poster (2016, July 07)

Organosolv pretreatment using diluted acid and butanol allows the separation of cellulose, hemicelluloses and lignin into three distinct phases. The butanol process has been investigated on six different ... [more ▼]

Organosolv pretreatment using diluted acid and butanol allows the separation of cellulose, hemicelluloses and lignin into three distinct phases. The butanol process has been investigated on six different biomasses: tall fescue, sugarbeet pulp, sugarcane bagasse, beech wood, eucalyptus and Japanese cedar. Dilute acid pretreatment has been performed under similar conditions for comparison. [less ▲]

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See detailIntegrated microfluidic device for in line SERS detection for glyphosate and related metabolites
Emonds-Alt, Gauthier ULg; Malherbe, Cédric ULg; Monbaliu, Jean-Christophe ULg et al

Poster (2016, July 07)

The goal of this work is to develop a quantitative analytical method for the glyphosate and its major metabolite the aminomethylphosphonic acid (AMPA) by coupling microfluidics with surface enhanced Raman ... [more ▼]

The goal of this work is to develop a quantitative analytical method for the glyphosate and its major metabolite the aminomethylphosphonic acid (AMPA) by coupling microfluidics with surface enhanced Raman spectroscopy (SERS). This work is divided into 4 axes : (a) bimetallic nanoparticles synthesis in a microreactor, (b) nanoparticles functionnalisation, (c) SERS quantification of glyphosate/AMPA and (d) miniature prototype development composed of axes a to c. The first section aims at the synthesis of bimetallic nanoparticles (Au-Ag, Au-Cu and Ag-Cu) in a microfluidic device. This microfluidic device integrates a first section for the synthesis of monometallic nanoparticles (core) and a second section for the reductive deposition of a second metal (shell). The second axe of this work deals with the functionnalisation of nanoparticles to improve the selectivity of this method for the selected analytes. Two types of functionnalisation are studied : PEGylation (a) with multi-arm PEG ending with -SH and/or (b) with linear heterobifunctionnal PEG. The third axe consists in measuring quantitatively glyphosate and AMPA in different matrices, such as water, urine and fruit juice. Finally, the forth axe deals with the development of a portable detection system to perform on-site analysis. This prototype integrates the microfluidic device for nanoparticles synthesis, their functionnalisation, an injection port followed by a mixing section for the sample and an integrated Raman spectrometer for in-line analysis. [less ▲]

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See detailOptimisation de la production d’acide furan-2,5-dicarboxylique à partir de déchets verts pour la conception de plastiques bio-basés
Istasse, Thibaut ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Poster (2016, July 06)

Afin de trouver des alternatives renouvelables aux produits issus de l’industrie pétrochimique, de nombreuses voies de recherches ont été explorées. Une voie prometteuse est la technologie des dérivés ... [more ▼]

Afin de trouver des alternatives renouvelables aux produits issus de l’industrie pétrochimique, de nombreuses voies de recherches ont été explorées. Une voie prometteuse est la technologie des dérivés furaniques. Parmi ces composés, le 5-hydroxyméthylfurfural (5-HMF) fait partie des molécules plateformes les plus importantes1. Il s’agit d’un produit de dégradation obtenu par déshydratation des hexoses2,3. Le 5-HMF peut servir de base à la conception de nombreuses molécules valorisables comme l’acide furan-2,5-dicarboxylique dont la structure proche de l’acide téréphtalique permet des applications dans la conception de polymères bio-basés3. L’acide furan-2,5-dicarboxylique respecte la législation REACH selon l’European Chemicals Agency4. Un rapport de l’EFSA de 2014 a démontré que cette substance ne posait pas de problème de toxicité lors de son utilisation comme monomère de base dans les plastiques d’emballage pour aliments5. Selon la société Avantium, le FDCA peut être utilisé pour produire un plastique entièrement bio-basé, le polyéthylène furanoate (PEF), qui affiche des performances supérieures à celle du poléthylène téréphtalate (PET) en termes de stabilité thermique, de propriétés mécaniques et de perméabilité aux gaz6. Si le FDCA peut être convertit en de nombreux produits à haute valeur ajoutée, il existe toutefois un frein majeur à son exploitation industrielle : son précurseur, le 5-HMF, n’est pas encore produit en grande quantité1. Ce problème est dû principalement à la déshydratation non sélective des sucres de la biomasse qui aboutit à de nombreux autres produits que le 5-HMF. La première difficulté à surmonter est donc la mise au point d’un procédé permettant de déshydrater de manière efficace et sélective les sucres de la biomasse. Le 5-HMF est également peu stable en milieu acide où il se décompose en acide formique et en acide lévulinique2. L'enjeu du projet de recherche présenté est donc l’optimisation de la production de 5-HMF à partir d’un ou plusieurs types de biomasses dans un premier temps, puis l’optimisation de la conversion du 5-HMF produit en FDCA. Les paramètres à prendre en compte sont notamment les sources de biomasse, l’efficacité des prétraitements concernant l’extraction des sucres, la sélectivité et l’efficacité de la conversion de ces sucres en 5-HMF (système mono- ou biphasique), l’étude de divers catalyseurs, le coût des traitements, etc… [less ▲]

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See detailEtude de la composition chimique de Pseudotsuga menziesii (Mirb.) Franco et évaluation de l’impact de divers prétraitements lignocellulosiques sur l’extraction de la lignine
Berchem, Thomas ULg; Schmetz, Quentin ULg; Jacquet, Nicolas ULg et al

Poster (2016, July 06)

La raréfaction des ressources fossiles est une certitude à l’heure actuelle. Il est donc primordial de trouver des voies de production plus durables pour des produits de consommation courante. Le ... [more ▼]

La raréfaction des ressources fossiles est une certitude à l’heure actuelle. Il est donc primordial de trouver des voies de production plus durables pour des produits de consommation courante. Le bioraffinage fait partie des solutions envisagées pour substituer les matériaux originaires de la filière pétrochimique. Dans cette optique, ce travail se focalise sur l’extraction et la caractérisation de la lignine à partir d’une biomasse présente en abondance en région Wallonne, Pseudotsuga menziesii (Mirb.) Franco (Douglas). Ce travail vise à montrer l’impact de divers prétraitements lignocellulosiques, tant en terme de rendements et de pureté d’extraction qu’au niveau de la modification de la structure et des propriétés des lignines. Ces différents paramètres sont évalués par des techniques gravimétriques (Klason), chromatographiques (chromatographie d’exclusion stérique) et spectroscopiques (RMN 2D HSQC). Pseudotsuga menziesii (Mirb.) Franco a été préalablement caractérisé par son taux de matière lignocellulosique (cellulose, hémicelluloses, lignine), ainsi que sa teneurs en cendres, en protéines et en extractibles (à l’eau et à l’éthanol). Les lignines natives ont été caractérisées par RMN 2D HSQC. [less ▲]

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See detailIdentifying wheat varieties with low acrylamide potential
Lecart, Brieuc ULg; Jacquet, Nicolas ULg; Anseeuw, Laurent et al

Poster (2016, July 05)

Maillard reactions are responsible for the formation of many compounds in food that have been baked at temperatures above 120°C1. Some of these compounds are sought for their contribution to the ... [more ▼]

Maillard reactions are responsible for the formation of many compounds in food that have been baked at temperatures above 120°C1. Some of these compounds are sought for their contribution to the organoleptic qualities of food but others, such as acrylamide, have been identified since 1986 as reprotoxic, genotoxic and carcinogenic in animals2. Synthesized from a chain reaction between free sugars and free asparagine, acrylamide has been found in many food such as products prepared from wheat flour1,3,4. The correlation between the amount of free sugars and free asparagine in raw food with the acrylamide content in the baked food has been well documented5. For this reason we compared the levels of 15 wheat varieties and identified wheat varieties with significantly lower level (=0.05) in acrylamide precursors. Those varieties could therefore be used preferentially in products intended for food. [less ▲]

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See detailHigh-temperature and quantitative XRD study of typical Westerwald clays (Germany)
Fontaine, François ULg; Fagel, Nathalie ULg

Poster (2016, July 05)

The Westerwald is one of the largest and oldest clay mining area of Germany. Those deposits were formed during the Eocene and Oligocene as a result of the weathering, erosion and redeposition of Devonian ... [more ▼]

The Westerwald is one of the largest and oldest clay mining area of Germany. Those deposits were formed during the Eocene and Oligocene as a result of the weathering, erosion and redeposition of Devonian rocks. During the Miocene, intense volcanic activities led to a large basalt cover, protecting the clays from the erosion. The fine fraction is mainly composed of kaolinite and illite, with the possible presence of interstratified I S. Other minerals such as quartz, feldspars, hematite, goethite or anatase are present in variable concentrations. Four typical Westerwald clays were chosen for this study: kaolinite-rich clay, kaolinite-illite clay, a red and a yellow firing clays. The first goal is to perform quantitative XRD using two different methods and to compare them: reference intensity ratio (RIR) and Rietveld (using Topas and BGMN). The second goal is the study of those samples using high-temperature XRD (HTXRD). The samples were heated up to 1250°C and a XRD pattern was obtained in situ every 100°C. The results show the temperatures of vitrification and formation of mullite and cristobalite varying from one sample to another, which is mainly linked to their flux concentration. [less ▲]

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See detailPIXE-PIGE analysis of Early Medieval Glass Artefacts at IPNAS cyclotron external beam line
Chene, Grégoire ULg; Van Wersch, Line ULg; Biron, Isabelle et al

Poster (2016, July 05)

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See detailL’intégration d’indicateurs biologiques dans un réseau de surveillance des sols afin d’améliorer le diagnostic de la qualité du sol – une étude de cas dans le sud de la Belgique (Wallonie)
Krüger, Inken ULg; Chartin, Caroline; van Wesemael, Bas et al

Poster (2016, July 05)

Les organismes du sol et leurs activités sont essentiels pour le fonctionnement de l’écosystème du sol et ils peuvent donc servir comme indicateurs de la qualité du sol. Des efforts ont récemment été ... [more ▼]

Les organismes du sol et leurs activités sont essentiels pour le fonctionnement de l’écosystème du sol et ils peuvent donc servir comme indicateurs de la qualité du sol. Des efforts ont récemment été menés pour intégrer les indicateurs biologiques de la qualité du sol dans les réseaux de surveillance régionaux/nationaux. Le but de cette étude était de déterminer des gammes de valeurs pour six indicateurs biologiques et deux quotients éco-physiologiques pour les sols agricoles. La respiration potentielle, la biomasse microbienne (carbone et azote), la minéralisation nette de l’azote, la diversité métabolique des bactéries du sol, l’abondance des vers de terre, le quotient microbien et le quotient métabolique ont été mesurés dans 60 sites dans des régions agricoles contrastées (différents types de sol et climat) et différentes utilisations de sol (prairies et cultures) sélectionnés d’un réseau de surveillance du carbone organique du sol (CARBOSOL). Les liens entre indicateurs biologiques et paramètres chimiques (le pH du sol, carbone organique total, soluble, labile et stable) sont analysés. Quatre des six indicateurs biologiques sélectionnés (respiration potentielle, biomasse microbienne (carbone et azote) et diversité métabolique des bactéries du sol) sont significativement plus élevés sous prairies que sous cultures. Les gammes de valeurs sont plus larges sous prairies que sous cultures. Les indicateurs biologiques sélectionnés ne sont pas significativement influencés par la région agricole. Les meilleures corrélations avec les paramètres chimiques ont été trouvées pour la respiration potentielle et la biomasse microbienne (carbone et azote). L’étude définit des gammes de valeurs pour les sols agricoles à l’échelle régionale (Wallonie) séparées par utilisation de sol (prairies et cultures) et présente une base solide pour l’établissement d’un réseau de surveillance de la qualité biologique du sol. [less ▲]

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See detailApplication of NIR hyperspectral imaging combined to chemometrics to assess the impact of tillage on the root system development of a winter wheat crop
Fraipont, Guillaume ULg; Eylenbosch, Damien ULg; Baeten, Vincent et al

Poster (2016, July)

This poster presents de results of a study of the influence of tillage on the root development of a winter wheat crop. The originality of this research lies in the application of an innovative root ... [more ▼]

This poster presents de results of a study of the influence of tillage on the root development of a winter wheat crop. The originality of this research lies in the application of an innovative root quantification method based on the near infrared hyperspectral imaging. [less ▲]

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See detailGeochemistry and mineralogy approaches to characterize brick and its lake sediments sources: Antioch Roman City (Southern Turkey)
El Ouahabi, Meriam ULg; Hubert, Aurelia ULg; Benjelloun, Yacine et al

Poster (2016, July)

The Roman aqueduct of Antioch-on-the-Orontes (Southern Turkey) is situated close to the Antioch city. This last is located near the Amik Lake (Lake of Antioch) and close to the junction between the active ... [more ▼]

The Roman aqueduct of Antioch-on-the-Orontes (Southern Turkey) is situated close to the Antioch city. This last is located near the Amik Lake (Lake of Antioch) and close to the junction between the active Dead Sea fault and the East Anatolian fault. During the Roman period, the Amik Plain was more densely occupied than at any time in its history [1]. The study focuses on the bricks and the lake sediments characterization in order to determine the source area as well as the technical production used at this period. For this purpose, several bricks were sampled on different parts of the city's aqueducts. Furthermore, a core of about 6 m of sediments was also collected from the dried Amik Lake. The bricks were characterized through a mineralogical (XRD) and chemical (PIXE-PIGE) approaches. Unfired clay fraction remained as inclusion in the brick was separated and then analysed using XRD. Geochemical composition and clay mineralogy were performed on the raw sediments from the Amik Lake in order to compare the source area. Technological test will be performed on the raw clay sediments from the Amik Lake in the purpose to understand the production techniques used at this time. The age of the brick production was previously dated to the Roman Period [2]. The synthesis of all the data attested the Amik Lake sediment as the raw material for the bricks of the aqueduct. Clay mineral composition from the Roman period deposited in the lake is smectite, illite, kaolinite and small amount of mixed-layer clays. The similar clays composition is found in the remained clays on the brick used for the aqueduct construction. Fast and heterogeneous firing practice characterized the manufacturing of these materials due to the rapid need for the materials during the post-seismic repairs after earthquakes that are mentioned in historical written works. [1] J. Casana, Geomorphology, 101, 429-442 (2008) [2] Y. Benjelloun, J. de Sigoyer, J. Carlut, A. Hubert-Ferrari, H. Dessales, H. Pamir, V. Karabacak, Comptes Rendus Geoscience, 347, 170-180 (2015) [less ▲]

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See detailMagnetocapillary self-assemblies: Swimming and micromanipulation
Grosjean, Galien ULg; Hubert, Maxime ULg; Lagubeau, Guillaume et al

Poster (2016, July)

Floating magnetic particles can self-assemble into structures, by a combination of a magnetic dipole-dipole interaction and an attraction due to the interfacial deformation. These structures are ... [more ▼]

Floating magnetic particles can self-assemble into structures, by a combination of a magnetic dipole-dipole interaction and an attraction due to the interfacial deformation. These structures are periodically deformed in a non reciprocal way using magnetic fields, which leads to controllable low Reynolds number locomotion. Such microswimmers provide a basis for micromanipulation applications such as transport of micro-objects, local mixing of fluids or surface cleaning. [less ▲]

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See detailPassive flutter suppression using a nonlinear tuned vibration absorber
Verstraelen, Edouard ULg; Gourc, Etienne ULg; Kerschen, Gaëtan ULg et al

Poster (2016, July)

A recent study showed that the addition of a linear tuned vibration absorber could increase the flutter speed of a rigid wing with pitch and flap degrees of freedom by about 35%. However, the absorber was ... [more ▼]

A recent study showed that the addition of a linear tuned vibration absorber could increase the flutter speed of a rigid wing with pitch and flap degrees of freedom by about 35%. However, the absorber was turning the initial super-critical bifurcation into a sub-critical one. This work shows numerically that adding a nonlinear restoring force to the absorber can restore the su- percritical behaviour of the bifurcation and further reduce the post-instability limit cycle amplitude. [less ▲]

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See detailPaleoenvironmental implications in the dried lake sediments (Amik Lake, Southern Turkey)
El Ouahabi, Meriam ULg; Hubert, Aurelia ULg; Vander Auwera, Jacqueline ULg et al

Poster (2016, July)

The Amik Basin in the Eastern Mediterranean region has been continuously inhabited since 6000 – 7000 BC. The study focuses on the sedimentary record of the Amik Lake located in the central part of the ... [more ▼]

The Amik Basin in the Eastern Mediterranean region has been continuously inhabited since 6000 – 7000 BC. The study focuses on the sedimentary record of the Amik Lake located in the central part of the basin. Our objective is to constrain major paleo-environmental changes in the area over the last 4000 years and to unravel possible human impacts on the sedimentation. A diverse array of complementary methods was applied on the 6 m long record. Mineralogical (XRD), and geochemical (XRF) analyses were performed. The age of the record is constrained combining radionuclide and radiocarbon dating. A high sedimentation rate of 0.12 cm/yr was inferred at the studied site. The 4000 years (since ~1800 BC) long record shows that significant fluctuations of the lake level and the riverine system inflow into the Amik Lake occurred. The Late Bronze lowstand led to punctual dryings of the lake at the end of the Bronze/Iron Age transition. At that time, the rivers yielded a large terrigenous input linked to strong soil erosion related mainly to deforestation and exploitation of mineral resources. During the Roman and later periods, upland soils were partly depleted and the riverine system completely transformed by channelization (anthropic) that led to a marshification of the Amik Basin [1]. Chemical and mineralogical composition of sediments is quite diversified reflecting the significant geological variation of drainage basins. Periods with strong aggradation linked to major increase in erosion were identified and characterized by high amount of Cr, Ni and Zr. Levels relatively rich in fluorite, richterite, enstatite, hornblende and chrysotile are a result of the erosion of the ophiolitic rocks from the surrounding Amanos Mountains. These levels are interpreted as periods of relatively high physical erosion, while more humid periods led to more intensive weathering. Consequently, the dominance of kaolinite, muscovite/illite and talc indicates a climate with contrasting seasons. During the most recent period a marked increase in terrigenous minerals associated with a rise in dolomite indicates ungoing erosion as well as the drying-out of the lake. [1] T.J. Wilkinson, L. Rayne, Water History, 2, 115-144 (2010). [less ▲]

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See detailInterspecific variation of warning calls in piranhas: comparative analysis
Mélotte, Geoffrey ULg; Michel, Christian ULg; Vigouroux, Régis et al

Poster (2016, July)

Fish sounds are often considered as species-specific with unique temporal and spectral features. Differences between acoustic signals of closely related species could be considered as pre-zygotic barrier ... [more ▼]

Fish sounds are often considered as species-specific with unique temporal and spectral features. Differences between acoustic signals of closely related species could be considered as pre-zygotic barrier and could be related to the evolutionary history of the species. In the present study, sounds were recorded and compared in eight piranha species (Serrasalmus elongatus, Serrasalmus marginatus, Serrasalmus compressus, Serrasalmus manueli, Serrasalmus spilopleura, Serrasalmus rhombeus, Serrasalmus eigenmanni and Pygocentrus nattereri) in order to evaluate the potential role of acoustic communication as a driving force in the clade diversification. The same kind of sound-producing mechanism was found in all the species: sonic muscles originate on vertebrae and attach to a tendon surrounding ventrally the bladder. Contractions of the sound-producing muscles force swimbladder vibration. Having the same kind of sound-producing mechanism, the calling features of the eight piranha species show logically many common characteristics. In all the species, the calls are harmonic sounds composed of several pulses without inter-pulse interval. It was possible to discern species-specific sounds, but the differences among species could be, in part, explained by the size. Only the sounds of S. elongatus and S. manueli are really distinguishable from the other species. Serrasalmus elongatus differed by having a higher number of pulses and high-pitched fundamental frequency, whereas S. manueli differed by having long pulse periods and a low fundamental frequency. In the framework of this study, acoustic communication cannot be considered as the main driving force in the diversification process of piranhas. Behavioral studies are however needed to clearly understand the eventual role of the calls during the spawning events. [less ▲]

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See detailGirls and Math Careers Expectations: Influence of Teacher Support and Motivational Variables
Jaegers, Doriane ULg; Lafontaine, Dominique ULg

Poster (2016, July)

Drawing on the expectancy-value theory, the three basic dimensions of instructional quality and the self-determination theory, this study examines the relation between teacher support, motivational ... [more ▼]

Drawing on the expectancy-value theory, the three basic dimensions of instructional quality and the self-determination theory, this study examines the relation between teacher support, motivational variables, course enrollment and career expectations in the domain of math. Gender differences are also investigated. Teacher support is seen as the fulfilment of the need of relatedness which is defined by the affective and academic quality of the teacher-student relationship. [less ▲]

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See detailCoherent backscattering in the Fock space of Bose- and Fermi-Hubbard systems
Engl, Thomas; Dujardin, Julien; Tisserond, Emilie et al

Poster (2016, July)

Coherent backscattering generally refers to a significant and robust enhancement of the average backscattering probability of a wave within a disordered medium, which from a semiclassical point of view ... [more ▼]

Coherent backscattering generally refers to a significant and robust enhancement of the average backscattering probability of a wave within a disordered medium, which from a semiclassical point of view arises due to the constructive interference between backscattered trajectories and their time-reversed counterparts. We recently investigated the manifestation of this wave interference phenomenon in the Fock space of a disordered Bose-Hubbard system of finite extent [1], which can potentially be realized using ultracold bosonic atoms within optical lattices. Preparing the atoms in a well-defined Fock state of the lattice and letting the system evolve for a finite time will, for suitable parameters of the system and upon some disorder average over random on-site energies of the lattice, generally give rise to an equidistribution of the occupation probability within the energy shell of the Fock space that corresponds to the initial energy of the system, in accordance with the quantum microcanonical ensemble. We find, however, that the initial state is twice as often encountered as other Fock states with comparable total energy, which is a consequence of coherent backscattering [1]. Most recently, we showed that this phenomenon also arises in spin 1/2 Fermi-Hubbard rings that involve Rashba hopping terms (which combine inter-site hoppings with spin flips and arise from spin-orbit coupling), for which a newly developed semiclassical theory [2] correctly predicts a coherent enhancement of the occupation probabilities of the initial state and its spin-flipped counterpart. Moreover, performing a global spin flip within this Fermi-Hubbard system will give rise to significant spin echo peaks on those two Fock states, which is again a consequence of quantum many-body interference [3]. The semiclassical predictions of these enhancements and peaks are found to be in very good agreement with numerical findings obtained from the exact quantum time evolution within this Fermi-Hubbard system. [1] T. Engl, J. Dujardin, A. Argüelles, P. Schlagheck, K. Richter, and J. D. Urbina, Phys. Rev. Lett. 112, 140403 (2014). [2] T. Engl, P. Plößl, J. D. Urbina, and K. Richter, Theoretical Chemistry Accounts 133, 1563 (2014). [3] T. Engl, J. D. Urbina, and K. Richter, arXiv:1409.5684. [less ▲]

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See detailSolo vs. duet in different virtual rooms: On the consistency of singing quality across conditions
Fischinger, Timo; Kreutz, Gunter; Larrouy, Pauline ULg

Poster (2016, July)

Previous research on vocal pitch accuracy revealed insights into the fundamentals of singing. However, most of the research on singing focused on the analysis of single voices, whereas few aYempts have ... [more ▼]

Previous research on vocal pitch accuracy revealed insights into the fundamentals of singing. However, most of the research on singing focused on the analysis of single voices, whereas few aYempts have been made to tackle the challenge of analyzing mulTtrack recordings of singing ensembles. In addiTon, singers have to adjust their way of singing with respect to a given venue’s acousTcal environment (e.g., small room vs. a comparaTvely large space like a church). If it is common that musical performances are greatly influenced by room acousTcs, studies on the effects of room acousTcal features during ensemble singing are rare. In order to invesTgate singing performances across various condiTons, we manipulated the singing condiTon (unison, canon, solo) as well as the acousTcal feedback by applying diverging virtual rooms. Three duets with female singers (N = 6) were asked to sing three different melodies using headset microphones to record each singer separately. Recordings took place in the communicaTon acousTc simulator (CAS) at the House of Hearing (Oldenburg, Germany) to be able to provide different simulated acousTcal spaces (i.e., cathedral, classroom, and dry condiTon) to the singers. ObjecTve measures were performed on each recording and confirmed that the singers sang the melodies with high precision (small pitch interval deviaTons) hardly affected by singing condiTons or by the type of acousTcal feedback. However, the singers tended to driH (larger deviaTons of the tonal center) when singing in canon compared to solo and unison singing. Overall, the analysis of the pitch accuracy showed a general effect of condiTon (i.e., unison, canon, solo), but no general effect of acousTcal feedback and no interacTon between the two variables under study. [less ▲]

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See detailUnveiling new stellar companions from the EXOZODI survey : follow up
Marion, Lindsay ULg; Absil, Olivier ULg; Ertel, Steve et al

Poster (2016, June 30)

In 2012, we have conducted a survey of nearby main sequence stars with VLTI/PIONIER to search for the presence of circumstellar dust. We focused on the use of the closure phases and the square ... [more ▼]

In 2012, we have conducted a survey of nearby main sequence stars with VLTI/PIONIER to search for the presence of circumstellar dust. We focused on the use of the closure phases and the square visibilities in a combined way to search for faint companions around the whole sample. In this process, we found four new stellar companions, for which we conducted follow-up observations in 2014. This follow up allows us to confirm the four detections, and to detect another new companion. Only the case of HD202730 remains ambiguous. [less ▲]

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See detailSmart co-phasing system for segmented mirror telescopes
Simar, Juan Felipe ULg; Stockman, Yvan ULg; Surdej, Jean ULg

Poster (2016, June 30)

One of the main challenges in space observations is to observe always fainter and more compact objects. This can be achieved by increasing the telescope diameters. So, increasing the primary mirror ... [more ▼]

One of the main challenges in space observations is to observe always fainter and more compact objects. This can be achieved by increasing the telescope diameters. So, increasing the primary mirror diameters of the telescopes is the challenge solution but it is technically impossible to manufacture monolithic mirrors larger than 10m in diameter. The use of segmented mirrors thus becomes mandatory. This paper describes the results of a light co-phasing setup mounted in laboratory. This setup is able to correct a piston from 200μm to 15 nm based on coarse (200μm to 300nm) and fine (300nm to 15nm) measurement methods. Both measurements are then chained in a feedback system in order to completely co-phase and keep the segments aligned. [less ▲]

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See detailMerging carbon dioxide utilisation, bioresources and CO2-based process for sustainable low carbon footprints polyurethanes
Alves, Margot ULg; Grignard, Bruno ULg; Gennen, Sandro ULg et al

Poster (2016, June 29)

Making plastics more sustainable by valorizing waste CO2 as a cheap, inexhaustible and renewable feedstock is an early stage technology with strong innovation potential that imposes itself as a strategic ... [more ▼]

Making plastics more sustainable by valorizing waste CO2 as a cheap, inexhaustible and renewable feedstock is an early stage technology with strong innovation potential that imposes itself as a strategic driver for developing future low carbon footprints materials and technologies. With a global production estimated to 18 million tons for 2016, polyurethane (PU) is one of the most important polymers in our everyday life with applications in automotive, in building and construction, in coating, in the medical field, as flexible and rigid foams for thermal and/or acoustic insulation. Industrially, PU is produced by step-growth polymerization between di- or polyisocyanates and di- or polyols. However, isocyanates are extremely toxic compounds and made from even more toxic and explosive phosgene. Prolonged exposure to isocyanates vapour results in serious health damages such as skin irritation, asthma or DNA mutation whereas phosgene causes death. Because of the toxicity issues of these compounds associated to drastic changes in the REACH regulations limiting/banning the use of isocyanates, there is a need today to develop new greener and safer alternatives to produce PU. Valorising CO2 as C1 feedstock for producing precursors entering in the synthesis of polyurethanes by a non-isocyanate route (NIPU) is a promising route to solve this challenge the polyurethane sector is facing. Through its global objective focussing on the synthesis of isocyanate-free low carbon footprint foamed materials for thermal insulation this research highlights benefits of merging bio-resources with carbon dioxide transformation and “physical” utilization. The success of the project relies on 3 key steps involving: i) The synthesis of bio- and CO2-sourced cyclic carbonates using new highly efficient organocatalysts: Due to the low reactivity of CO2 versus epoxides, addition of catalysts in the reaction medium is necessary. If lot of catalysts have been developed, their use generally suffers from some drawbacks. Indeed, most of the metal-based catalysts are highly sensitive to hydrolysis and oxidation or/and poorly selective and additionally, some of them are toxic whereas less/non-toxic and eco-friendly organocatalysts such as ionic liquids and halide salts are generally only efficient at very high temperature and pressure, so favouring the decomposition of catalyst. To overcome these limitations, we developed a new highly-efficient bicomponent homogeneous organocatalyst that showed unexpected catalytic activity for the fast (within a few minutes) and selective addition of CO2 onto model epoxides and epoxidized vegetable oils under solvent-free and mild experimental conditions. The use of this powerful dual organocatalyst was further extended to the first organocatalytic coupling of CO2 with less reactive oxetanes to produce hydroxyl telechelic oligocarbonate entering the synthesis of CO2-sourced conventional PUs. ii) The synthesis of sustainable non-isocyanate polyurethanes: Sustainable NIPUs were produced by step-growth polymerization between the so-produced bio- and CO2-sourced cyclic carbonates and biosourced amino-telechelic comonomers derived from linseed fatty acids according to a process compatible with existing industrial infrastructures (extrusion). iii) The foaming of NIPUs: Sustainable foams with thermal insulation were produced by the supercritical CO2 assisted foaming technology. Due to its solubility in polymers, CO2 can replace conventional flammable VOCs and ozone depletion chemical or physical blowing agents such as diazo compounds, hydrocarbons (pentane, isopentane…) or inert gases (nitrogen…) to produce (ultra)lightweight microcellular foams. By finely choosing the CO2 impregnation and the foaming conditions, foams with a thermal conductivity as low as 0.052 Wm-1K-1 were produced. Our study shows that CO2 is not only sequestered in the material for long-term application, but is also valorized as a blowing agent in the production of sustainable thermally insulating NIPU foams. Such low carbon footprints materials will contribute to energy conservation and savings by reducing CO2 emissions [less ▲]

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See detailHolocene paleoclimate reconstructions from belgian continental archives
Allan, Mohammed ULg; VERHEYDEN, sophie; CRUCIFIX, Michel et al

Poster (2016, June 28)

Speleothems and peatbogs presented in Belgium are interesting archives for atmospheric pollution record and climate variability. Both archives are reliable continental environmental archives of high ... [more ▼]

Speleothems and peatbogs presented in Belgium are interesting archives for atmospheric pollution record and climate variability. Both archives are reliable continental environmental archives of high interest due to their dating possibilities and their possibility to preserve multi-proxy records of environmental and climatic dynamics. Combining studies on speleothems and peatbogs from the same area will provide an age-constrained reconstruction of climatic variability at annual resolution for key intervals of the Holocene. The reconstructed precipitation and temperature curves in NW European settings, as proposed in HOPES, are essential to better constrain the Northern Hemisphere climatic record and to test climate models. Our strategy is derived from a comparative study of two continental archives speleothems and peatbogs. Time series of elemental and stable isotope geochemistry will be established for the 2 archives. For peatbog, the reconstructions of temperature (derived from stable C and O isotope), precipitation (derived from humification) and dust flux (from elementary geochemical signature) would track climate changes with subdecadal resolution. As an innovative part, Laser Ablation analyse of elemental geochemistry on impregnated peat section will allow to reach an annual resolution in the dust flux. For speleothems, records of temperature (derived from oxygen and carbon isotopic composition of calcite) and effective rainfall (derived from geochemical ratios) would reach a seasonal resolution. [less ▲]

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See detailMapping and investigating phase anomalies in GPS data onboard Low Earth Orbiters
Wautelet, Gilles ULg; Bruinsma, Sean; Loyer, Sylvain et al

Poster (2016, June 28)

To face important societal challenges like sea level variations, climate change and natural hazards management (tsunami detection, earthquakes, crustal deformations…), modern science rely more and more on ... [more ▼]

To face important societal challenges like sea level variations, climate change and natural hazards management (tsunami detection, earthquakes, crustal deformations…), modern science rely more and more on precise geodesy. Precise Orbit Determination (POD) is of major concern in the frame of altimetry or gravity recovery missions like GOCE or GRACE. Using the GPS receiver onboard, orbits at cm-level accuracy are generally achieved in both kinematic and reduced-dynamic approaches using dual frequency code and phase measurements. GPS data processing generally uses the Ionospheric-Free (IF) combination to get rid of the ionospheric delay, which is varying with the season, latitude, local time and solar activity. However, large discrepancies in the orbit determination are still observed over polar and equatorial regions, which turn into artefacts and errors in the derived scientific products (gravity field, sea surface height…). More precisely, large RMS values are strongly correlated to phase anomalies occurring on GPS receivers: cycle slips, data unavailability or enhanced measurement noise, especially on L2 signal. Phase anomalies are generally observed when the satellite orbit crosses regions where ionospheric scintillations occur, which are defined as rapid fluctuations in phase and amplitude of the GNSS signals. The occurrence of scintillations exhibits large day-to-day variations and depends mainly on geomagnetic latitude, season and local time. At low latitudes, maximum occurrence of scintillations is observed 15-20° on either side of the geomagnetic equator. Scintillations also occur at auroral and polar latitudes, where their intensity increases with increasing geomagnetic activity. This paper aims at detecting, mapping and understanding the phase anomalies experienced by LEO satellites and analyzing their correlation with geomagnetic activity, latitude, season and local time. Several LEO satellites at different altitudes are analyzed (e.g. SWARM, GRACE or JASON), which allows a multi-layer analysis of the underlying ionospheric phenomenon, including scintillation. The latter are generally measured with several indices, like the amplitude index S4 or the phase index SigmaPhi (σφ), which are usually derived from 100Hz measurements performed by dedicated scintillation monitors. In this study, we compute a similar index (called pseudo-σφ) using GPS phase data at 1Hz coming from POD GNSS antenna. A detailed study of the occurrence rate and the severity of pseudo-σφ, together with cycle slips and other spurious phase data, will be performed for different LEO satellites. [less ▲]

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See detailConception of a near-IR spectrometer for ground-based observations of massive stars
Kintziger, Christian ULg; Desselle, Richard ULg; Loicq, Jerôme ULg et al

Poster (2016, June 27)

In our contribution, we outline the different steps in the design of a fiber-fed spectrographic instrument that intends to observe massive stars. Starting from the derivation of theoretical relationships ... [more ▼]

In our contribution, we outline the different steps in the design of a fiber-fed spectrographic instrument that intends to observe massive stars. Starting from the derivation of theoretical relationships from the scientific requirements and telescope characteristics, the entire optical design of the spectrograph is presented. Specific optical elements, such as a toroidal lens, are introduced to improve the instrument’s performances. Then, the verification of predicted optical performances is investigated through optical analyses such as resolution checking. Eventually, the star positioning system onto the central fiber core is explained. [less ▲]

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See detailAssaying asparagine content in a complex matrix using a spectrophotometric method
Lecart, Brieuc ULg; Jacquet, Nicolas ULg; Anseeuw, Laurent et al

Poster (2016, June 23)

In this study we show, on 15 wheat varieties, the ability to assay the asparagine content in a complex matrix such as wheat flour by a simple spectrophotometric assay. This method is easier, faster and ... [more ▼]

In this study we show, on 15 wheat varieties, the ability to assay the asparagine content in a complex matrix such as wheat flour by a simple spectrophotometric assay. This method is easier, faster and cheaper than conventional chromatography analysis and allow to discriminate quickly which materials has high or low level of this amino acid. Asparagine is an amino acid present in free form in the food biomass and has the property of reacting with the free sugars during the Maillard reactions that occur during baking at temperatures above 120°C. The Acrylamide resulting from this reaction chain has been identified as reprotoxic, genotoxic and carcinogenic in animals since 1986. The present method allowed us to identify wheat varieties with significantly lower or higher asparagine contents (α=0.05). Therefore, this method can be used to identify wheat varieties or other plants with low asparagine content to use preferentially in products designed for food. [less ▲]

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See detailImpact of cooking and species on intestinal fermentation patterns of vegetables in a humanized in vitro model of the gastro-intestinal tract
Kalala Bolokango, Gaetan ULg; Kambashi Mutiaka, Bienvenu ULg; Njeumen Lemotio, Georges Patrick ULg et al

Poster (2016, June 21)

Obesity and associated pathologies have dramatic consequences on patients’lives as well as high societal costs. Because of the role of intestinal dysbiosis and microbiota make-up on the pathogenesis of ... [more ▼]

Obesity and associated pathologies have dramatic consequences on patients’lives as well as high societal costs. Because of the role of intestinal dysbiosis and microbiota make-up on the pathogenesis of obesity, several strategies such as eating prebiotics and dietary fibre supplements are being investigated to reshape the intestinal microbial communities of obese patients. Beyond supplement, dietary fibre is supplied through plant ingredients in the meals. In the framework of the multidisciplinary research project Food4Gut, the use of vegetables rich in specific targeted dietary fiber, namely fructans, is being scrutinized for its ability to induce positive changes in the intestinal ecophysiology. Because expected effect might differ according the content in dietary fibre and fructans, the soluble:insoluble ratio, as well as the cooking of the vegetables, the fermentation patterns of several vegetables are being investigated in an dual in vitro model combining enzymatic hydrolysis to an in vitro fermentation step using faecal inoculums from humans, to evaluate the performance of gut microbiota, modulation of metabolic functions. Six vegetables were sampled in triplicates (N=3) and steamed for 20 to 30 min.: Jerusalem artichoke, salsify, asparagus, pumpkin, fennel and swede. They were chosen because they display a variety of contents in fructans, soluble (SDF) and insoluble dietaryfibre (IDF). Steamed vegetable samplesand burgers from local fast food restaurants (negative control) were hydrolyzed in vitro why porcine pepsin and pancreatin to mimic digestion in the upper gut and indigested fiber residues were recover using a 6kDa dialysis membrane.Subsequently, in vitro fermentation is being run with independent fecal inoculums from obese and lean patients (N=4). Fermentation kinetics over 24h as well as short-chain fatty acid production and profiles will be compared according to the individual donor and the vegetable species and multivariate analysis will be used to explore the relationships between donor, vegetable species and composition and fermentation patterns. [less ▲]

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See detailNatural radioactivity and elemental composition of sands in the Douala region, Littoral of Cameroon Using Portable XRF and HPGe detector
Guembou Shouop, Cébastien Joel ULg; Ndontchueng Moyo, Maurice; Chene, Grégoire ULg et al

Poster (2016, June 21)

Twenty four sand samples from seven sand quarries alone the Gulf of Guinea, Douala Littoral region of Cameroon, were analyzed using high purity germanium detector and a portable X-ray fluorescence (PXRF ... [more ▼]

Twenty four sand samples from seven sand quarries alone the Gulf of Guinea, Douala Littoral region of Cameroon, were analyzed using high purity germanium detector and a portable X-ray fluorescence (PXRF) spectrometer. A comprehensive study was conducted to determine the natural radioactivity concentrations and the geological provenience of sand samples from seven different quarries sites of the Douala, a popular city, and its surroundings. The radioactivity investigation was performed by using high resolution gamma-ray spectrometry. From the measured gamma-spectra, the average activity concentrations were determined for 226Ra, 232Th, 40K and 235U for a depth of 5–25 cm. Results of this study were compared to values from other locations around the world. X-ray fluorescence spectrometry (XRF) measurements were performed for the quantitative elemental analysis of the sands, revealing the major, minor and trace elements present in the investigated samples. Reference marine and geological sample are used to check precision and accuracy of the equipment for major and minor components. From XRF experimental results it was possible to estimate the geological provenience of the analyzed sands. These data record the radioactivity background levels in sands and could be used as reference information in Cameroon. The comparison of major (Si, Al), minor (K, Ca,Fe), and trace (Ti, Mn, Zr, Rb, Sr) element ratios was made. The results indicate that the levels of Si and Al can be very helpful in subgroup definition and provide useful clues to the raw materials used for glassmaking in Cameroon. [less ▲]

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See detailVisual artificial grammar learning in children with SLI : Is variability the key ?
Desmottes, Lise ULg; Maillart, Christelle ULg; Demelenne, Pauline et al

Poster (2016, June 18)

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See detailCapturing fine-level structure using unsupervised clustering method with multiple data types
Chaichoompu, Kridsadakorn ULg; Tongsima, Sissades; Shaw, Philip James et al

Poster (2016, June 17)

Several methods exist to detect shared genetic ancestry or to identify population substructure using SNP-based or haplotype-based information (Price et al. 2006, Lawson et al. 2012). Here, we propose an ... [more ▼]

Several methods exist to detect shared genetic ancestry or to identify population substructure using SNP-based or haplotype-based information (Price et al. 2006, Lawson et al. 2012). Here, we propose an unsupervised clustering method built on the ipPCA algorithm (Intarapanich et al. 2009). Our method supports both ordinal and categorical data, and it can be applied to panels of single locus and/or multiple loci data, or gene-based integrative summaries (Fouladi et al. 2015). Our method involves an iterative process using binary and ternary splits based on multivariate Gaussian mixture modeling of PCs and Clustering EM estimation as in (Lebret et al. 2015). To evaluate its performance, we examined different simulated scenarios of 2-4 populations, 500-8,000 individuals, 5,000-20,000 independent SNPs in HWE, and FST=[0.0007,0.006] (Balding and Nichols 1995), with 100 replicates for each scenario. SNPs were treated as categorical or continuous including ancestry-corrected SNPs. Haplotype-based runs used HapMap 3 data: CHB, CHD, and JPT. In simulated scenarios of extremely subtle structure (FST=[0.0009,0.006]), a population classification accuracy of 92% or greater was obtained, which was superior to ipPCA. Also in case of the HapMap populations, promising results to detect fine structure were obtained. We are convinced that our method has a potential to detect fine-level structure and it will be important in molecular reclassification studies of patients once underlying population structure has been removed. [less ▲]

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See detailEstetrol Attenuates Neonatal Hypoxic-Ischemic Encephalopathy: Preclinical Studies
Tskitishvili, Ekaterine ULg; Nisolle, Michelle ULg; Noël, Agnès ULg et al

Poster (2016, June 17)

Brain hypoxia and ischemia due to systemic hypoxemia and reduced cerebral blood flow (CBF) are the primary causes of neonatal hypoxic-ischemic encephalopathy (HIE) accompanied by gray and white matter ... [more ▼]

Brain hypoxia and ischemia due to systemic hypoxemia and reduced cerebral blood flow (CBF) are the primary causes of neonatal hypoxic-ischemic encephalopathy (HIE) accompanied by gray and white matter injuries occurring in neonates. Perinatal HIE still remains a challenge in perinatal medicine. About 20% of affected newborns die in the postnatal period, and an additional 25% will sustain childhood disabilities. So far no medical treatment provides important neuroprotection against HIE. Studies of new neuroprotective agents in animal models of HIE may have importance for the development of new compounds and treatment strategies for this pathological condition. Estetrol (E4) is a recently described estrogen with four hydroxyl-groups that is synthesized exclusively during pregnancy by the human fetal liver. It has important antioxidative activity. To study the neuroprotective and therapeutic effects of E4 in vivo neonatal HIE model of 7-day-old newborn rat pups was used. Rat pups body temperatures were examined along with their body and brain weights. Brains were studied at the level of the hippocampus and cortex. Intact cell counting and expressions of markers for neuronal cell viability (microtubule-associated protein-2 (MAP-2)), neurogenesis (doublecortin (DCX)) and angiogenesis (vascular-endothelial growth factor (VEGF)) were evaluated by histo- and immunohistochemistry. The serum levels of brain damage markers (S100B and glial fibrillary acidic protein (GFAP)) were measured by ELISA. Our results demonstrate for the first time that E4 has a significant neuroprotective and therapeutic effects. It decreases the early gray matter loss and promotes neuro- and angiogenesis in vivo. Estetrol treatment has no effects on body weight, brain weight or body temperature. Taken together, E4 might become an important safe and physiological substance to treat neonatal HIE. [less ▲]

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See detailLignin as a bio-based flame retardant additive: Pretreatments overview
Istasse, Thibaut ULg; Jacquet, Nicolas ULg; Richel, Aurore ULg

Poster (2016, June 12)

Lignin is a cross-linked phenol polymers from plant cells wall and is the third most abundant organic material after cellulose and hemicelluloses. This substance was studied as a flame retardant for ... [more ▼]

Lignin is a cross-linked phenol polymers from plant cells wall and is the third most abundant organic material after cellulose and hemicelluloses. This substance was studied as a flame retardant for various polymers and represents an interesting opportunity to create more eco-friendly and safer plastics and resins. This poster explains one potential technology to extract lignin: the organosolv treatment. [less ▲]

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See detailWater familiarization testing battery adapted for young children
Vandermeulen, Mary ULg; Schietecatte, Delphine; Delvaux, Anne ULg et al

Poster (2016, June 11)

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See detailThe Computer in German Literature at the Turn of the Millennium
Dupont, Bruno ULg

Poster (2016, June 09)

This poster shows how the representation of the computer in German literature since 1990 changes the very form and content of literary works. The social importance of the computer challenges the texts on ... [more ▼]

This poster shows how the representation of the computer in German literature since 1990 changes the very form and content of literary works. The social importance of the computer challenges the texts on three levels: their topical organisation, the language used for the transcription of the new reality, and the ideological positioning on new media. [less ▲]

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See detailMALDI-imaging guided microproteomics workflow for biomarker discovery of intra-tumor heterogeneity
Alberts, Deborah ULg; Longuespée, Rémi ULg; Smargiasso, Nicolas ULg et al

Poster (2016, June 09)

Introduction A single tumoral tissue can bear phenotypically different cell populations. This phenomenon called intra-tumor heterogeneity can lead to differential behaviors regarding metastasis seeding ... [more ▼]

Introduction A single tumoral tissue can bear phenotypically different cell populations. This phenomenon called intra-tumor heterogeneity can lead to differential behaviors regarding metastasis seeding and therapy resistance [Zardavas et al., Nature Rev. Clin. Onc. 2015]. MALDI imaging has proven its efficiency for revealing hidden molecular features offering an insight into distinct cellular regions based on their molecular content. Further, proteomics applied to these regions could allow depicting the molecular context associated to particular cells groups and enable the collection of qualitative, quantitative and spatial information for each protein. Methods Breast cancer Formalin Fixed and Paraffin Embedded tissues, from patients whose outcome had been recorded over a period of 10 years, were provided by the department of Pathology of University of Liège. After Citric Acid Antigen Retrieval and trypsin digestion, images were obtained by MALDI-TOF/TOF-MS (Bruker, Germany). From the obtained datasets, segmentation and analytical data analysis were applied using SCiLS (Bruker, Germany) and the cloud software Multimaging (ImaBiotech, France). Small tissue areas were obtained by laser microdissection (LEICA LMD 700, Germany), upon which a combination of chemical processes was applied to ensure optimal protein antigen retrieval, extraction and digestion. Finally, the tissue pieces obtained were analyzed by LC-MS/MS using UPLC Waters Nanoacquity and Thermo Q-Exactive instruments. Preliminary data Based on mathematical calculations for the MALDI imaging datasets of the breast cancer FFPE tissues, Regions Of Interest (ROIs) were detected in a single tumor, revealing intra-tumoral heterogeneity, which can be correlated to the level of aggressiveness of the affliction and to the final prognosis of the patient. We aimed to compare the proteomic profiles of each of the small ROIs. Until today, proteomics applied to tissues composed by a restricted number of cells is quite tedious due to possible tissue losses during their handling. Recently, Longuespée [Longuespée et al., Methods 2015] published a method in order to retrieve the identification of 1400 proteins from microdissected tissue pieces containing only 2700 cells. This whole procedure allowed us to identify a panel of protein that characterizes tissue heterogeneity within a single tumor. This proves the applicability of the combination of MALDI imaging for the discovery of intra-tumoral heterogeneity without a priori, on a mathematical basis, and classical proteomics applied on laser-microdissected tissue samples of very restricted areas. This method will now be applied to several MALDI datasets in order to retrieve commune ROIs and to associate their presence with the information of each patient, such as their prognosis. Those ROIs will then be microdissected and subjected to microproteomic methods that will allow us to retrieve the extensive molecular context associated to bad patient prognosis and/or therapy resistance. The possibility to identify protein/peptide markers will have the power to predict the outcome of the breast cancer patient at the beginning of their treatment, and thus, improve the clinical care for the benefit of the patients. Novel aspect The workflow combines the unique advantages of MALDI imaging for de novo molecular features characterization and LMD-based microproteomics. [less ▲]

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See detailFunctional analysis of PEBP genes in root chicory (Cichorium intybus)
Saintmard, Nicolas ULg; Tocquin, Pierre ULg; Périlleux, Claire ULg

Poster (2016, June 09)

Manipulating plant architecture is key to increase crop yield. In this perspective, basic knowledge on the molecular mechanisms regulating plant growth and development will be fundamental for the future ... [more ▼]

Manipulating plant architecture is key to increase crop yield. In this perspective, basic knowledge on the molecular mechanisms regulating plant growth and development will be fundamental for the future of agriculture. Recent progress indicates that a family of plant genes, homologous to POSPHADITYLETHANOLAMINE-BINDING PROTEINS (PEBP) in other eukaryotes, plays critical roles in controlling shoot development traits such as branching, flowering, bud dormancy or tuberization. Very little is known however on the functions of these genes in root development. The current research will attempt to answer this question in the case of Cichorium intybus, a biannual plant cultivated for the extraction of inulin (a polymer of fructose) from its root. Functional analyses will include expression kinetics, complementation tests in Arabidopsis mutants and creation of PEBP- overexpressing or silencing chicory plants. The preliminary steps of the project are the identification of PEBP genes in chicory by in silico analyses, the determination of the time of the storage root initiation and the establishment of a regeneration protocol for the genetic transformation. [less ▲]

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See detailCharacterization of FRD3, a iron and zinc homeostasis actor in Arabidopsis relatives
Scheepers, Maxime ULg; Charlier, Jean-Benoit; Spielmann, Julien ULg et al

Poster (2016, June 09)

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See detailTowards a Digital Philology. Creation, Spread and Apprehension of Knowledge through Digital Scholarly Platforms in Humanities
Mayeur, Ingrid ULg

Poster (2016, June 09)

This contribution aims to present and discuss my thesis project. I plan to study the concrete conditions of production, diffusion and reception of knowledges on digital scholarly platforms in Humanities ... [more ▼]

This contribution aims to present and discuss my thesis project. I plan to study the concrete conditions of production, diffusion and reception of knowledges on digital scholarly platforms in Humanities. This work will especially focus on the four plateforms of the portal OpenEdition: OpenEdition Books, Calenda, Hypothèses and Revues.org. The main problematic is: what are the uses of those platforms, and in what concrete way are they influencing the modes of scientific communication? To start with, I need to highlight the frameworks that structure the digital scholarly texts, that Jeanneret named ‘architexts’ (Davallon & al. 2003, Jeanneret 2014). Such frameworks contribute to configure the digital texts (e. g. with hypertext, flows aggregation), and their uses. Three aspects will then be taken into consideration in my analysis: (I) the articulation of temporal stratums within the plateform: how do archival materials deal with actualities (scientific monitoring, work in progress as grey literature)? What means of contextualization (Treleani 2013) or editorialization (Vitali Rosati 2016) could be given when an old document is used again (e.g. in “epi-revues” that collect scientific papers) ? (II) What are the genres and formats conveyed on the plateform, proper to the Web as blog post, commentary, etc., or still used in other medias as scientific article, advert, etc. (Maingueneau 2013)? (III) Who are the users of those plateforms (researchers, groups, professionals, etc.)? How do they deal with their digital identities? How can they appropriate and diffusing knowledges, by citing, reusing and discussing? How are emerging new ways for research in Humanities, through collective negociation or evaluation, interdisciplinarity – such actions that could be promoted by the technical device of the plateform? This last point will be treated by a philological approach concerning paratexts and quotations (Genette 1982, Compagnon 1979). Other indicators (users’ itineraries, interactions between members, etc.) could also be used, and treated with network’s visualization tool. In summary, this research project aims to explore the means of a digital philology (Crane, Bamann and Jonesin Schreibman 2008; Rastier 2011), not only based on making traditional philology with digital tools (i.e. semantic enrichment of antics or medieval texts), but also on a critical approach of the digital textuality and on an active as well as reflexive contribution from the users in building knowledges. References Davallon, Jean, Marie Després-Lonnet, Yves Jeanneret, Joëlle Le Marec, and Emmanuël Souchier. 2003. Lire, écrire, récrire : Objets, signes et pratiques des médias informatisés. Études et recherche. Paris: Éditions de la Bibliothèque publique d’information. Compagnon, Antoine. 1979. La Seconde main ou le Travail de la citation. Paris: Seuil. Genette, Gérard. 1982. Palimpsestes: La littérature au second degré. Paris: Seuil. Maingueneau, Dominique. 2013. « Genres de discours et web : existe-t-il des genres web ? » In Manuel d’analyse du web en Sciences Humaines et Sociales, 74 93. Paris: Armand Colin. Mounier, Pierre, and Marin Dacos. 2010. L’édition électronique. Paris: La Découverte. Rastier, François. 2011. La mesure et le grain. Sémantique de corpus. Paris: Honoré Champion. Treleani, Matteo. 2014. Mémoires audiovisuelles: les archives en ligne ont-elles un sens? Montréal: PUM. Vitali-Rosati, Marcello. 2016. « What is editorialization? » Sens public, janvier. http://www.sens-public.org/article1059.html, consulté le 10 février 2016. Crane Gregory, David Bamman, and Alison Jonesin Schreibman, “ePhilology: When the Books Talk to Their Readers” in Susan, et Ray Siemens, éd. 2008. Companion to Digital Literary Studies. Oxford: Blackwell Publishing Professional. URL : http://www.digitalhumanities.org/companion/view?docId=blackwell/9781405148641/9781405148641.xml&chunk.id=ss1-4-1&toc.depth=1&toc.id=ss1-4-1&brand=9781405148641_brand. Consulted on 10 fev. 2016.   [less ▲]

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See detailAg/SiO2 and Cu/SiO2 cogelled xerogel catalysts for benzene combustion and 2-butanol deshydrogenation
Mahy, Julien ULg; Claude, Vincent ULg; Tasseroul, Ludivine ULg et al

Poster (2016, June 08)

Tars are recognized as major impurities when biomass is gazified into Syngas (mixture CO + H2) or when the methane reforming was produced from sustainaible reagents [1]. Therefore, fundamental knowledge ... [more ▼]

Tars are recognized as major impurities when biomass is gazified into Syngas (mixture CO + H2) or when the methane reforming was produced from sustainaible reagents [1]. Therefore, fundamental knowledge of catalytic oxidation and deshydrogenation mechanisms can be valuable to develop effective methods to control syngas or methane pollution. A very important concern about cogelled catalysts is the accessibility of the active centers. Because the silver and copper is located inside silica particles, there is a risk that it may not be accessible. In the case of benzene oxidation, it was observed that the specific activity (mol s-1 g-1Ag) of Ag/SiO2 and Cu/SiO2 catalysts increases when the silver or copper loading decreases (Fig. 1). In fact, visual observations by TEM showed that in samples Ag0.25, Ag0.45, Ag1.05 and Cu1.00, there are not silver or copper particles located on silica particles external surface and then the metal dispersion values are greater in these samples. So, it is the proof that Ag and Cu particles located inside the silica particles are accessible for benzene in this catalytic system. In the case of 2-butanol dehydrogenation, the specific activity of Cu/SiO2 catalysts increases when the copper loading increases or when the metal dispersion values decreases (Fig. 2). However, in Cu1.00 sample, copper particles inside silica particles only are observed by TEM. It seems that these metallic particles are accessible for 2-butanol in this catalytic system. [less ▲]

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See detailMOISTURE CONTENT DETERMINATION OF FREEZE-DRIED PRODUCTS BY NEAR-INFRARED SPECTROSCOPY: A CASE STUDY FOR UNIVERSAL REGRESSION MODEL
Clavaud, Matthieu ULg; Roggo, Yves; Degardin, Klara et al

Poster (2016, June 06)

Karl Fischer titration is the reference method for moisture content determination in the pharmaceutical industry. Near-infrared spectroscopy is considered the most suitable alternative technique. Indeed ... [more ▼]

Karl Fischer titration is the reference method for moisture content determination in the pharmaceutical industry. Near-infrared spectroscopy is considered the most suitable alternative technique. Indeed, NIRS is a safe and fast method which does not require sample preparation. Nevertheless, the development and validation phases are time-consuming. In addition, the NIRS methods presented so far were mostly product specific. The main objective of this study is to highlight that an universal calibration model can be validated for several freeze-dried products in order to speed up the validation time. This objective was led in two steps. A universal model was first evaluated. A calibration set and a validation set were built up with three freeze-dried products. An antibody drug conjugate, a large molecule and a small molecule all packed in sealed vials were used to introduce more variability. Regression methods were then compared in order to optimize the prediction values. [less ▲]

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See detailOn the α-polarization of bacterial suspensions: SIP measurements on four bacterial strains
Pilawski, Tamara ULg; Tappe, Wolfgang; Zimmermann, Egon et al

Poster (2016, June 06)

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See detailModélisation d'une climatisation automobile multi-évaporateurs
Gillet, Thomas ULg; Rullière, Romuald; Haberschill, Philippe et al

Poster (2016, June 02)

La modélisation d’une climatisation automobile multi-évaporateurs, composées de deux évaporateurs et d’un refroidisseur de fluide secondaire, a été réalisée à l’aide du logiciel LMS Imagine.Lab Amesim® 1D ... [more ▼]

La modélisation d’une climatisation automobile multi-évaporateurs, composées de deux évaporateurs et d’un refroidisseur de fluide secondaire, a été réalisée à l’aide du logiciel LMS Imagine.Lab Amesim® 1D. Dans le but d’étudier le comportement de la boucle, des perturbations sous la forme d’échelon ont été simulées sur un point de fonctionnement à moyenne et haute charge. L’impact de ces perturbations sur la stabilité de la température d’air soufflé est analysé pour deux types de détendeur. Les premiers résultats montrent que les détendeurs thermostatiques peuvent engendrer des instabilités. [less ▲]

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See detailScreening of mahoran plants for cosmetic applications.
Saive, Matthew ULg; Frederich, Michel ULg; Fauconnier, Marie-Laure ULg

Poster (2016, June 01)

This study’s main aim is to identify plant species showing anti-oxidant, anti-inflammatory and skin whitening properties. A selection of 89 samples from previous infield studies on the traditional uses of ... [more ▼]

This study’s main aim is to identify plant species showing anti-oxidant, anti-inflammatory and skin whitening properties. A selection of 89 samples from previous infield studies on the traditional uses of plants in Mayotte were analyzed. The anti-oxidant activity was assessed using the α, α-diphenyl-β-picrylhydrazyl (DPPH) method developed by Blois [1]. The anti-inflammatory activity and the skin whitening activity were both assessed through the study of inhibition kinetics from specific enzymes: respectively, lipoxygenase (EC 1.13.11.12) due to its important role in the leukotriene pathway and tyrosinase (EC. 1.14.18.1) as it takes part in the melanogenesis pathway. The IC 50 value for each sample and for each activity was obtained using UV/Vis spectrophotometric technics. These IC 50 were then compared with the ones obtained from known molecules found in the literature: namely, (±)-6-Hydroxy-2,5,7,8-tetramethylchromane-2-carboxylic acid (IC50 = 4,388 µM) for the anti-oxidant activity, nordihydroguaiaretic acid (IC50 = 3,5µM) for the anti-inflammatory activity and kojic acid (IC50 = 722 µM) for the anti-tyrosinase activity. The most effective anti-oxidant activity was observed in fresh leaves from Acalypha wilkesiana Müll.Arg. (IC50 = 0,381 g/L) and Leea guineensis G. Don. (IC50 = 0,225 g/L) as well as in dried roots from Litchi chinensis Sonn. (IC50 = 0,346 g/L). All results are expressed in grams of fresh matter. According to the preliminary tests for the-anti-inflammatory and skin whitening activities, the crude extracts from Kalanchoe pinnata Lam. Pers., Litchi chinensis Sonn., Zingiber zerumbet (L.) Sm., Leea guineensis G. Don. and Paullinia pinnata L. are likely to show promising activities. [less ▲]

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See detailSpeech characteristic of French-speaking children with Dysarthria: Pilot study
MacLeod, andrea; Maillart, Christelle ULg; Ancelle, J. et al

Poster (2016, June)

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See detailEffects of protein source and cooking procedure on intestinal microbiota and on fermentation end-products in rats
POELAERT, Christine ULg; Despret, Xavier; Portetelle, Daniel ULg et al

Poster (2016, June)

Animal and plant proteins are major proteins sources in the human diet. After their enzymatic degradation in the upper gastro-intestinal tract, the undigested fraction of these proteins is available for ... [more ▼]

Animal and plant proteins are major proteins sources in the human diet. After their enzymatic degradation in the upper gastro-intestinal tract, the undigested fraction of these proteins is available for fermentation by the microbiota of the large intestine leading to the production of short-chain fatty acids (SCFA), branched-chain fatty acids (BCFA), ammonia, biogenic amines, sulphur metabolites, phenols and indoles. As some of these compounds have genotoxic and cytotoxic effects, protein fermentation is considered as detrimental to the host’s epithelial health. BCFA are usually used as a marker of intestinal protein fermentation. We studied in vivo the impact of proteins from animal and plant origin, raw or after a cooking procedure, on the composition of gut microbiota and on fermentation end-products. Weanling rats were used as models of the human gut microbiota. Eight experimental diets were formulated with beef meat (Longissimus dorsi), chicken meat (Pectoralis major), white pea beans (Phaseolus vulgaris), soybeans (Glycine max), used raw and cooked, as sole source of protein in the diet. One casein diet was used as control. All diets, formulated to contain 15% of raw protein, were given to seven rats for four weeks. After euthanasia, caecal contents were collected. Pyrosequencing analyses (Roche 454 GS Junior Genome Sequencer) were performed to study the microbial composition. SCFA and BCFA were measured using HPLC (Waters 2690). Microbial composition in the caecum is associated to the type of dietary protein and to the cooking procedure applied. The proportion of BCFA in the caecal content is mainly affected by the type of protein. So BCFA represent respectively 04-06% and 35-44% of total SCFA with diets based on plant and on animal proteins. In conclusion, both the type of protein and the cooking procedure could impact the gut microbiota in terms of composition and of fermentative capacity. [less ▲]

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See detailMethodology to fish peptide ligands of nAChRs from Cone snail venoms by MALDI-TOF mass spectrometry
Echterbille, Julien ULg; Gilles, Nicolas; Araoz, Romulo et al

Poster (2016, June)

More than 50,000 of venomous species are currently indexed in the world. Each of their venom is composed of hundreds of toxins which potentially exhibit a high selectivity for membrane receptors such as ... [more ▼]

More than 50,000 of venomous species are currently indexed in the world. Each of their venom is composed of hundreds of toxins which potentially exhibit a high selectivity for membrane receptors such as GPCRs or ion channels. Among them, nAChRs are a target for drug discovery, primarily for treating central nervous system troubles. Therefore, the discovery of pharmacological tools and innovative drugs targeting nAChRs from animal venoms appears as an evidence. This study proposes the use a mass-spectrometry based methodology1 to discover new nAChRs ligands from cone snails venoms, and particularly -conotoxins (a-CTXs), known as potential antagonists of nAChRs2. in few words, Torpedo membranes, containing a high concentration of nAChRs, are incubated with BSA tryptic digests (>100 peptides) doped by small amounts of known a-CTXs. After two hours incubation, free (i.e. containing molecules remaining in solution) and bound (i.e. peptides bound to the membranes) fractions were analyzed with a MALDI-TOF/TOF mass spectrometer. The POC (positive and negative controls) as well as a real screening of Conus ermineus venom are presented. [less ▲]

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See detailImpact d'un programme d'activation comportementale sur l'humeur, le niveau d'engagement dans des activités, les ruminations et les biais attentionnels chez des étudiantes universitaires
Krings, Audrey ULg; Wagener, Aurélie ULg; Blairy, Sylvie ULg

Poster (2016, June)

A Behavioral activation program was proposed to undergraduated students with difficulties to deal with their mood. Six sessions of a Martell's program was proposed with two evaluations, before (T0) and ... [more ▼]

A Behavioral activation program was proposed to undergraduated students with difficulties to deal with their mood. Six sessions of a Martell's program was proposed with two evaluations, before (T0) and after (T1) the sessions. Different psychological processes were evaluated (behavioral activation, avoidance, rumination and attentional biases). Compared to the control group, a significal reduction was observed for abstract rumination, avoidance and a significant enhancement of selective attention to positive faces in the dot probe task was also observed. [less ▲]

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See detailDisentangling soil from plant methanol exchanges in a maize field: a first step
Bachy, Aurélie ULg; Mozaffar, Ahsan ULg; Aubinet, Marc ULg et al

Poster (2016, June)

This poster presents the current research done in order to disentangle soil from plant methanol exchanges in a maize field. Methanol exchanges were calculated at ecosystem-scale (therefore including both ... [more ▼]

This poster presents the current research done in order to disentangle soil from plant methanol exchanges in a maize field. Methanol exchanges were calculated at ecosystem-scale (therefore including both components). It bases on the following observation: methanol exchanges on bare soil (measured when maize was at germination stage) were as important as when plants were fast growing (and thereby, when the highest methanol plant methanol emissions were expected), and this under similar weather conditions. The goal of this poster is thus to understand why emissions were similar at these two periods. First, it addresses the question of the actual contribution of maize plants in methanol exchanges, by comparing up-scaled methanol exchanges measured on maize at leaf-scale (Mozaffar A.) to those measured at ecosystem-scale. Then, it investigates methanol exchanges mechanisms in order to evaluate how did soil methanol emissions evolve along the maize growing season. At the end of this poster, the hypothesis of decreasing soil methanol emissions along the maize growing season is proposed. [less ▲]

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See detailPhotoionization as a Soft Ionization Source for Comprehensive Two-dimensional GC (GCxGC) and High-Resolution TOFMS
Ubukata, M; Cody, RB; Dane, J et al

Poster (2016, June)

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See detailDevelopment of improved preservation techniques for cyanobacterial and diatom strains in the BCCM collections
Crahay, Charlotte ULg; Chepurnova, Olga; Day, John G et al

Poster (2016, June)

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See detailAnalogical reasoning in children with Specific Language Impairment: Evidence from a scene analogy task
Krzemien, Magali ULg; Jemel, Boutheina; Maillart, Christelle ULg

Poster (2016, June)

Analogical reasoning development maintains a mutual influence with language acquisition: the use of relational labels helps to resolve analogical reasoning tasks (Christie & Gentner, 2014) while ... [more ▼]

Analogical reasoning development maintains a mutual influence with language acquisition: the use of relational labels helps to resolve analogical reasoning tasks (Christie & Gentner, 2014) while analogical reasoning enables the acquisition of new linguistic concepts or structures (Gentner & Namy, 2006). This link has driven some authors to examine the analogical reasoning ability of children with Specific Language Impairment. Those children have poorer analogical reasoning performance than their age-matched peers without language disorders (Leroy et al., 2012 ; Leroy et al., 2014). So, children with SLI seem to have an analogical reasoning weakness which could be linked to their language disorders. Thus, our goal here is to measure the ability of children with SLI to solve analogies, and to compare it to chronological age-matched but also to linguistic age-matched peers without language disorders. Our hypotheses here are the followings: children with SLI have weaker analogical reasoning competence compared to chronological age-matched peers and similar or weaker analogical reasoning competence compared to language-matched peers. To test these hypotheses, we use a scene analogy task composed of pictures of 20 relations (Richland et al., 2006) varying in relational complexity (binary or ternary relations) and in perceptual distraction. Twenty children with SLI are matched to chronological age and linguistic age peers without language disorders. Children with SLI have poorer performance then their age-matched peers but they have similar performance to their language-matched peers. This data reinforces the idea of a link between analogical reasoning and language, also in children with SLI. However, the nature of this link should still be clarified. [less ▲]

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See detailMyoclonin-1 modulates the post-translational modification of microtubules
Medard, Laurie ULg; Coumans, Bernard ULg; Lakaye, Bernard ULg et al

Poster (2016, June)

Juvenile myoclonic epilepsy is one of the most common forms of generalized genetic epilepsy. Genetic studies have shown that heterozygous mutations in Myoclonin1 are responsible for 3-9% of clinical cases ... [more ▼]

Juvenile myoclonic epilepsy is one of the most common forms of generalized genetic epilepsy. Genetic studies have shown that heterozygous mutations in Myoclonin1 are responsible for 3-9% of clinical cases worldwide. This protein contains three DM10 domains of unknown function and an EF-hand domain. We have previously demonstrated that Myoclonin1 is a microtubule-associated protein involved in cell division and radial migration during neocortex development. In cells, this protein co-localized with specific structures rich in microtubules (MTs) such as the centrosome, the poles of the mitotic spindle or the motile cilia but not with cytoplasmic MTs. This suggests post-translational modifications (PTM) of MTs may be important for the interaction between Myoclonin1 and MTs. We have co-express the different enzymes catalyzing PTM of MTs with Myoclonin1 in U2OS cell line. With one of these enzymes, we observed a strong increase in PTM in the presence of Myoclonin-1. This suggests that Myoclonin1 may interact with and modulate the activity of this enzyme. By using luciferase complementation assay and pull down experiments, we could demonstrate that it is indeed the case. Interestingly, the effect is observed even when a DM10 domain alone is co-expressed with the enzyme, suggesting for the first time a role for this domain. In conclusion our data suggest myoclonin-1 modulates specific PTM of MTs. This is of prime importance for microtubule dynamic and notably for neuroblast precursor migration during neocortex development. This could be the mechanism that explains why pathological forms of myoclonin-1 affect brain development. [less ▲]

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See detailTranscranial magnetic stimulation in sleep consciousness
Gosseries, Olivia ULg; Niemienen, Jaakko; Jason, Samaha et al

Poster (2016, June)

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See detailEducation of instructors of a physical activity program for cancer patients and survivors: planning and evaluation of a poster presentation session
Rompen, Jérôme ULg; Korycki, Marta ULg; Ortmans, Sabine et al

Poster (2016, June)

Introduction The Belgian Foundation against Cancer proposes an adapted physical activity (APA) program for cancer patients and survivors, called Raviva (http://www.cancer.be/raviva-bouger-pour-se-sentir ... [more ▼]

Introduction The Belgian Foundation against Cancer proposes an adapted physical activity (APA) program for cancer patients and survivors, called Raviva (http://www.cancer.be/raviva-bouger-pour-se-sentir-mieux).The activities are supervised by instructors with inconstant trainings and experiences. Contrary to other countries, Belgian APA instructors do not necessarily need to follow specific education programs such those proposed by the ACSM (Schmitz et al., 2010).We were involved in the implementation of a specific training day for in-service Raviva instructors. As it is the case in sport coaches’ education (Erickson et al., 2008), interacting with colleagues seemed to be an appropriate method to improve APA instructors’ skills. Therefore, interactive methods were proposed to be used in order to increase the participants’ interest. The aim of this paper was to describe and analyse a poster presentation session as well as to identify good practices. Methods As part of the training day, the poster presentation session consisted to create groups of 4 to 5 persons and to ask them to imagine and share solutions to specific problems linked with psycho-emotional aspects of the instruction process with Raviva groups. Three methods were used to collect the data: interviews of the organizers (n=4), a questionnaire for all trainees (n=35) and participant observation. Results Examples of good practices were listed and exchanged between the participants. All trainees considered that the poster presentation session was interesting and most of them (94%) reported that appropriate themes were discussed. Moreover, 88.2% of the participants mentioned that they were able to share their experiences. Three expressed negative opinions about the organization. These opinions were supported by all organizers as well as by the observation. Conclusions This educational tool seems to be interesting. However, organizers should plan enough time for such activity. Moreover, the time allocation between each part of the session should be better prepared and controlled. [less ▲]

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