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Peer Reviewed
See detailRadiative lifetimes in La III and oscillator strengths in La III and Lu III
Biémont, Emile ULg; Li, Z. S.; Palmeri, P. et al

in Journal of Physics : B Atomic Molecular & Optical Physics (1999), 32

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See detailRadiative lifetimes of 6sns S-3(1) and 6snd D-3(1) excited states of HgI
Blagoev, K.; Pentchev, V.; Biémont, Emile ULg et al

in Physical Review A (2002), 66(3),

Natural radiative lifetimes have been measured along the 6sns S-3(1) (n=7-10) and 6snd D-3(1) (n=6-11) Rydberg series of neutral mercury using time-resolved laser-induced fluorescence spectroscopy in a ... [more ▼]

Natural radiative lifetimes have been measured along the 6sns S-3(1) (n=7-10) and 6snd D-3(1) (n=6-11) Rydberg series of neutral mercury using time-resolved laser-induced fluorescence spectroscopy in a laser-produced mercury plasma. The states of Hg I investigated in the present work were populated from the ground state by a stepwise excitation process. Relativistic Hartree-Fock calculations, including intravalence interactions and core-polarization effects, have been performed and the theoretical lifetimes have been compared with the measurements. [less ▲]

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See detailRadiative lifetimes of Cd I and Cd II excited states
Xu, H.; Persson, A.; Svanberg, S. et al

Conference (2004)

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See detailRadiative lifetimes of Zn I, II excited states
Blagoev, K. B.; Malcheva, G.; Penchev, V. et al

in Physica Scripta (2004), 69(6), 433-440

Radiative lifetimes of excited states of Zn I (3d(10)4sns S-3(1), n = 6-8; 3d(10) 4snd D-3, n = 4-7) and Zn II (3d(10) 4p P-2(1/2.3/2), 4d D-2(3/2,5/2), 3d(10)5S S-2(1/2)) have been measured using a time ... [more ▼]

Radiative lifetimes of excited states of Zn I (3d(10)4sns S-3(1), n = 6-8; 3d(10) 4snd D-3, n = 4-7) and Zn II (3d(10) 4p P-2(1/2.3/2), 4d D-2(3/2,5/2), 3d(10)5S S-2(1/2)) have been measured using a time-resolved laser-induced fluorescence technique. Single- or two-step excitation of atoms and ions produced by laser ablation was employed. The experimental radiative lifetimes have been compared with theoretical results obtained within a multiconfigurational relativistic Hartree-Fock approach taking core-polarization effects into account. [less ▲]

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See detailRadiative lifetimes, branching fractions and oscillator strengths in PdI and the solar palladium abundance
Xu, H. L.; Sun, Z. W.; Dai, Z. W. et al

in Astronomy and Astrophysics (2006), 452(1), 357-362

Transition probabilities have been derived for 20 5s-5p transitions of Pd I from a combination of radiative lifetime measurements for 6 odd-parity levels with time-resolved laser-induced fluorescence ... [more ▼]

Transition probabilities have been derived for 20 5s-5p transitions of Pd I from a combination of radiative lifetime measurements for 6 odd-parity levels with time-resolved laser-induced fluorescence spectroscopy and of branching fraction determination using a hollow cathode discharge lamp. Additional oscillator strengths for 18 transitions have been determined from measured lifetimes and theoretical branching fractions obtained from configuration interaction calculations with core-polarization effects included. These new results have allowed us to refine the palladium abundance in the solar photosphere: A(Pd) = 1.66 +/- 0.04, in the usual logarithmic scale, a result in close agreement with the meteoritic value. [less ▲]

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See detailRadiative lifetimes, branching fractions and transition probabilities in Ge I. Solar implications
Biémont, Emile ULg; Lynga, C.; Li, Z. S. et al

in Monthly Notices of the Royal Astronomical Society (1999), 303

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See detailRadiative lifetimes, branching ratios and transition probabilities in Ge I.
Biémont, Emile ULg; Doidge, P. S.; Garnir, Henri-Pierre ULg et al

Conference (1998, August)

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See detailRadiative parameters for some transitions arising from the 3d(9)4d and 3d(8)4s(2) electronic configurations in CuII spectrum
Ortiz, M.; Mayo, R.; Biémont, Emile ULg et al

in Journal of Physics B-Atomic Molecular and Optical Physics (2007), 40(1), 167-176

Transition probabilities of 41 transitions originating from the 3d(9)4d and 3d(8)4s(2) electronic configurations of singly ionized copper have been determined using laser-induced breakdown spectroscopy ... [more ▼]

Transition probabilities of 41 transitions originating from the 3d(9)4d and 3d(8)4s(2) electronic configurations of singly ionized copper have been determined using laser-induced breakdown spectroscopy. The Cu II ions have been produced by laser ablation. The experimental relative transition probabilities have been converted into an absolute scale using measured branching fractions and theoretical radiative lifetimes of the corresponding upper states obtained by a relativistic Hartree-Fock method taking core-polarization and configuration interaction effects into account. Comparison of the new results with previously available data is also presented. [less ▲]

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See detailRadiative parameters for some transitions in Cu(II) and Ag(II) spectrum
Biémont, Emile ULg; Blagoev, K.; Campos, J. et al

in Journal of Electron Spectroscopy & Related Phenomena (2005), 144-147

Radiative parameters for transitions depopulating the levels belonging to the 3d84s2 configuration of Cu(II) and 4d96s and 4d95d configurations of Ag(II) have been obtained both theoretically and ... [more ▼]

Radiative parameters for transitions depopulating the levels belonging to the 3d84s2 configuration of Cu(II) and 4d96s and 4d95d configurations of Ag(II) have been obtained both theoretically and experimentally. On the experimental side, a laser-produced plasma was used as a source of Cu(II) and Ag(II) spectra. The light emitted by the plasma was focused on the input slit of a grating monochromator coupled with a time-resolved optical multichannel analyzer system. Spectral response calibration of the experimental system was made using a deuterium lamp in the wavelength range extending from 200 to 400 nm, and a standard tungsten lamp in the range from 350 to 600 nm. The transition probabilities were obtained using measured branching fractions and available radiative lifetimes of the corresponding states. On the theoretical side, a relativistic Hartree-Fock (HFR) approach, including core-polarization effects, has been used for the calculations. A reasonable agreement theory–experiment has been observed. [less ▲]

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See detailRadiative parameters for some transitions in the spectrum of Ag-II
Campos, J.; Ortiz, M.; Mayo, R. et al

in Monthly Notices of the Royal Astronomical Society (2005), 363(3), 905-910

Radiative parameters for transitions depopulating the levels belonging to the 4d(8)5s(2), 4d(9)6s and 4d(9)5d configurations of Ag II have been obtained from a combination of theoretical lifetimes and ... [more ▼]

Radiative parameters for transitions depopulating the levels belonging to the 4d(8)5s(2), 4d(9)6s and 4d(9)5d configurations of Ag II have been obtained from a combination of theoretical lifetimes and experimental branching fractions. On the experimental side, a laser-produced plasma was used as a source of Ag+ ions. The light emitted by the plasma was analysed by a grating monochromator coupled with a time-resolved optical multichannel analyser system. Spectral response calibration of the experimental system was performed using a deuterium lamp in the wavelength range from 200 to 400 nm, and a standard tungsten lamp in the range from 350 to 600 nm. The transition probabilities were obtained from measured branching ratios and theoretical radiative lifetimes of the corresponding states calculated with a relativistic Hartree-Fock approach including core-polarization effects and configuration interaction in an extensive way. Theoretical and experimental data have been compared and the new data have also been compared with the few previous results available in the literature. [less ▲]

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See detailRadiative parameters of Nb I excited states
Malcheva, G; Nilsson, H; Engström, L et al

in Monthly Notices of the Royal Astronomical Society (2011), 412

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See detailRadiative properties and core-polarization effects in W5+ ions
Enzonga Yoca, S; Palmeri, P; Quinet, Pascal ULg et al

in Journal of Physics : B Atomic Molecular & Optical Physics (2012), 45

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See detailRadiative Properties of Neutral Germanium obtained from excited-state lifetime and branching-ratio measurements and comparison with theoretial calculations
Li, Z. S.; Norin, J.; Persson, A. et al

in Physical Review. A (1999), 60

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See detailRadiative seesaw: Warm dark matter, collider and lepton flavour violating signals
Aristizabal Sierra, Diego ULg; Kubo, Jisuke; Restrepo, D. et al

in Physical Review D (2009), 79

Extending the standard model with three right-handed neutrinos (Nk) and a second Higgs doublet (η), odd under the discrete parity symmetry Z2, Majorana neutrino masses can be generated at one-loop order ... [more ▼]

Extending the standard model with three right-handed neutrinos (Nk) and a second Higgs doublet (η), odd under the discrete parity symmetry Z2, Majorana neutrino masses can be generated at one-loop order. In the resulting model, the lightest stable particle, either a boson or a fermion, might be a dark matter candidate. Here we assume a specific mass spectrum (M1≪M2<M3<mη) and derive its consequences for dark matter and collider phenomenology. We show that (i) the lightest right-handed neutrino is a warm dark matter particle that can give a ~10% contribution to the dark matter density; (ii) several decay branching ratios of the charged scalar can be predicted from measured neutrino data. Especially interesting is that large lepton flavor violating rates in muon and tau final states are expected. Finally, we derive upper bounds on the right-handed neutrino Yukawa couplings from the current experimental limit on Br(μ→eγ). [less ▲]

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See detailRadiative stabilization and photodissociation of HeH+ in its two lowest 3 sigma plus states
Vranckx, Stéphane; Loreau, Jerôme; Desouter, Michèle ULg et al

in Journal of Physics: Conference Series (2012), 288(2), 022109

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See detailRadiative transfer based scaling of LAI/FPAR retrievals from reflectance data of different resolutions.
Tian, Y; Wang, Y; Zhang, Y et al

in Remote Sensing of Environment (2002), 84(1), 143-159

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See detailRadiative transition probabilities for forbidden lines in singly ionized cobalt (Co II)
Quinet, Pascal ULg

in Astronomy and Astrophysics. Supplement Series (1998), 129

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See detailRadiative transition rates and collision strengths for Si II
Bautista, M A; Quinet, Pascal ULg; Palmeri, P et al

in Astronomy and Astrophysics (2009), 508

See detailRadical coupling of polymers formed by cobalt-mediated radical polymerization
Debuigne, Antoine ULg; Hurtgen, Marie ULg; Jérôme, Christine ULg et al

in Matyjaszewski, Krzysztof; Sumerlin, Brent; Tsarevsky, Nicolas V. (Eds.) Progress in controlled radical polymerization: mechanisms and techniques (2012)

Considerable progress has been recently made in cobalt-mediated radical polymerization (CMRP), a controlled radical polymerization system based on the temporary deactivation of the polymer chains by a ... [more ▼]

Considerable progress has been recently made in cobalt-mediated radical polymerization (CMRP), a controlled radical polymerization system based on the temporary deactivation of the polymer chains by a cobalt complex, like the improvement of the mechanistic understanding, the extension to a range of monomers and the preparation of novel architectures. However, the real breakthrough in this field concerns the development of efficient radical coupling methods for polymer precursors preformed by CMRP. This book chapter aims to describe the general principle and main characteristics of such radical coupling techniques involving dienes, nitrones, fullerenes or carbon nanotubes. Well-defined and complex architectures obtained by these techniques are provided in order to illustrate their potential for macromolecular engineering. [less ▲]

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