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See detailStimuli-responsive surfaces by electrografting
Jérôme, Christine ULg

Conference (2008, October 28)

The design of stimuli-responsive coatings on a variety of solid surfaces is the topic of increasing researches. In this area, the adhesion of a stimuli-responsive polymer to the inorganic support whatever ... [more ▼]

The design of stimuli-responsive coatings on a variety of solid surfaces is the topic of increasing researches. In this area, the adhesion of a stimuli-responsive polymer to the inorganic support whatever the conditions of pH and temperature, remains a concern. In this field, we have been studying an electrochemical process able to initiate the polymerization of acrylic derivatives together with promoting their chemisorption to the substrate used as electrode. We have demonstrated the versatility of this method that can be applied to a variety of acrylics leading to the possible generation of responsive coatings to either pH or temperature. Reversible anchoring of molecules of interest has also been achieved recently by this method based on the grafting of dienes able to bind a dienophile and release it at higher temperature by retroDiels-Alder reaction. The electroinitiation has been found compatible with a variety of surfaces going from conventional metals (iron, steel, gold) to carbon (fibers and nanotubes) and semi-conductors (doped-silicon), which spreads the applications to various fields such as medical devices, biosensors, catalysis, electronics and photovoltaics. Particularly, the application of this process to AFM tips allows the straightforward functionalization of these devices allowing not only the handling of polymers at the molecular level but also the elaboration of various temperature, pH or analyte sensitive sensors at the nanometer scale. [less ▲]

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See detailStimuli-responsive triblock copolymer for biomedical applications
Sibret, Pierre ULg; Jérôme, Christine ULg

Conference (2011, April 29)

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See detailStimuli-responsive triblock copolymer for biomedical applications
Sibret, Pierre ULg; Croisier, Florence ULg; Zhao, J. et al

Poster (2010, May 25)

Detailed reference viewed: 14 (2 ULg)
See detailStimulus range effects in temporal bisection by humans.
Wearden, John H; Ferrara, André ULg

in Quarterly Journal of Experimental Psychology. B, Comparative & Physiological Psychology (1996), 49(1), 24-44

Two experiments with human subjects, using short-duration tones as stimuli to be judged, investigated the effect of the range of the stimulus set on temporal bisection performance. In Experiment 1, six ... [more ▼]

Two experiments with human subjects, using short-duration tones as stimuli to be judged, investigated the effect of the range of the stimulus set on temporal bisection performance. In Experiment 1, six groups of subjects were tested on a temporal bisection task, where each stimulus had to be classified as "short" or "long". For three groups, the difference between the longest (L) and shortest (S) durations in the to-be-bisected stimulus set was kept constant at 400 msec, and the L/S ratio was varied over values of 5:1 and 2:1. For three other groups, the L/S ratio was kept constant at 4:1 but the L-S difference varied from 300 to 600 msec. The bisection point (the stimulus value resulting in 50% "long" responses) was located closer to the arithmetic mean of L and S than the geometric mean for all groups except that for which the L/S ratio was 2:1, in which case geometric mean bisection was found. In Experiment 2, stimuli were spaced between L and S either linearly or logarithmically, and the L/S ratio took values of either 2:1 or 19:1. Geometric mean bisection was found in both cases when the L/S ratio was 2:1, but effects of stimulus spacing were found only when the L/S ratio was 19:1. Overall, the results supported a previous conjecture that the L/S ratio used in a bisection task played a critical role in determining the behaviour obtained. A theoretical model of bisection advanced by Wearden (1991) dealt appropriately with bisection point shifts discussed above but encountered difficulties with stimulus spacing effects. [less ▲]

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See detailStimulus spacing effects in temporal bisection by humans
Wearden, J. H.; Ferrara, André ULg

in Quarterly Journal of Experimental Psychology (1995), 48B(4), 289-310

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See detailStimulus-response curve of human motor nerves: multicenter assessment of various indexes.
Boerio, D.; Hogrel, J.-Y.; Lefaucheur, J.-P. et al

in Neurophysiologie Clinique = Clinical Neurophysiology (2008), 38(1), 31-8

The value of various indexes to characterize the stimulus-response curve of human motor nerves was assessed in 40 healthy subjects recruited from four European centers of investigation (Creteil, Lausanne ... [more ▼]

The value of various indexes to characterize the stimulus-response curve of human motor nerves was assessed in 40 healthy subjects recruited from four European centers of investigation (Creteil, Lausanne, Liege, Marseille). Stimulus-response curves were established by stimulating the right median and ulnar motor nerves at the wrist, with stimulus durations of 0.05 and 0.5 ms. The following parameters were studied: the threshold intensity of stimulation to obtain 10% (I 10), 50% (I 50), and 90% (I 90) of the maximal compound muscle action potential, the ratios I 10/I 50, I 90/I 50, (I 90 - I 10)/I 10, (I 90-I 50)/I 50, and (I 50 - I 10)/I 10, and the slopes of the stimulus-response curves with or without normalization to I 50. For each parameter, within-center variability and reproducibility (in a test-retest study) were assessed and between-center comparisons were made. For most of the parameters, the results varied significantly within and between the centers. Within the centers, only the ratios I 10/I 50 and I 90/I 50 were found constant and reproducible. Between the centers, the absolute intensity thresholds (I 10, I 50, I 90) and the ratio I 90/I 50 did not show significant differences at stimulus duration of 0.5 ms, whatever the stimulated nerve. The reduced variability and good reproducibility of the ratios I 10/I 50 and I 90/I 50 open perspectives in neurophysiological practice for the use of these indexes of the stimulus-response curve, a rapid and noninvasive test. [less ▲]

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See detailStochastic analysis of a stadium roof from deterministic wind tunnel measurements
Blaise, Nicolas ULg; Denoël, Vincent ULg

in 13th International Conference on Wind Engineering (2010)

Dynamic analyses of structures under buffeting wind loads can be performed in a deterministic (Clough and Penzien, 1997) or stochastic (Preumont, 1994) context, both with a modal approach for ... [more ▼]

Dynamic analyses of structures under buffeting wind loads can be performed in a deterministic (Clough and Penzien, 1997) or stochastic (Preumont, 1994) context, both with a modal approach for computational efficiency reasons. In the first option, the forces are deterministically given, and the uncoupled modal equations of motion are solved either in the time domain with a stepby- step method, either in the frequency domain, with Fourier transformation. In the second option, the analysis relies on the determination of the Power Spectral Density (PSD) matrix of the structural response given that of the loading. The choice of one or another method usually depends on whether the loading is provided in the time or frequency domain and as a deterministic (a single time history) or stochastic manner. From a designer’s point of view, the wind loading can be defined using design codes (e.g. Eurocode, 2005) where analytical expressions of (i) the PSD of wind velocities (Davenport, Von Karman, etc) (ii) the coherence functions and (iii) the pressure coefficients are given to compute, finally, (iv) the PSD of the aerodynamic pressures. Design engineers are usually familiar with this probabilistic approach. Alternatively, the design may be conducted from aerodynamic pressures measured in a wind tunnel. This approach is more realistic than the aforementioned codified procedure since a number of phenomena as (a) the aerodynamic instabilities, (b) aerodynamic admittance (Scanlan and Jones, 1999), (c) site effects are taken into account. Pressures are thus given as unique (deterministic) time histories at each sensor. In a Finite Element context and a modal analysis, the generalized forces are computed from the measured pressures. With the firm wish to perform the analysis in a stochastic manner (for a number of good reasons mentioned next), we suggest to fit a probabilistic model to the measured data. Such a model could be fitted to the measured pressures right away, or any other subsequent quantity such as the generalized forces. The following discussion is about the most favorable quantity that has to be fitted and how to do it appropriately in view of typical measurement imperfections. [less ▲]

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See detailStochastic analysis of the effect of heterogeneity and fractures on radionuclide transport in a low-permeability clay layer
Huysmans, Marijke; Dassargues, Alain ULg

in Environmental Geology (2005), 48(7), 920-930

Deep low-permeability clay layers are considered as safe environments for disposal of high-level radioactive waste. In Belgium, the Boom Clay is a candidate host rock for deep geological disposal. In this ... [more ▼]

Deep low-permeability clay layers are considered as safe environments for disposal of high-level radioactive waste. In Belgium, the Boom Clay is a candidate host rock for deep geological disposal. In this study, we analyze the effects of fractures and spatially variable hydraulic conductivity on radionuclide migration through the clay. Fracture geometry and properties are simulated with Monte Carlo simulation. The heterogeneity of hydraulic conductivity is simulated by direct sequential co-simulation using measurements of hydraulic conductivity and four types of secondary variables. The hydraulic conductivity and fracture simulations are used as input for a transport model. Radionuclide fluxes computed with this heterogeneous model are compared with fluxes obtained with a homogeneous model. The output fluxes of the heterogeneous model differ at most 8% from the homogeneous model. The main safety function of the Boom Clay is thus not affected by the fractures and the spatial variability of hydraulic conductivity. [less ▲]

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See detailStochastic analysis of the effect of spatial variability of diffusion parameters on radionuclide transport in a low permeability clay layer
Huysmans, Marijke; Dassargues, Alain ULg

in Hydrogeology Journal (2006), 14(7), 1094-1106

Most studies that incorporate subsurface heterogeneity in groundwater flow and transport models only analyze and simulate the spatial variability of hydraulic conductivity. Heterogeneity of the other flow ... [more ▼]

Most studies that incorporate subsurface heterogeneity in groundwater flow and transport models only analyze and simulate the spatial variability of hydraulic conductivity. Heterogeneity of the other flow and transport parameters are usually neglected. This approach is often justified, but there are, however, cases in which disregarding the heterogeneity of the other flow and transport parameters can be questionable. In low permeability media, for instance, diffusion is often the dominant transport mechanism. It therefore seems logical to incorporate the spatial variability of the diffusion parameters in the transport model. This study therefore analyses and simulates the spatial variability of the effective diffusion coefficient and the diffusion accessible porosity with geostatistical techniques and incorporates their heterogeneity in the transport model of a low permeability formation. The formation studied was Boom clay (Belgium), a candidate host rock for the deep geological disposal of high-level radioactive waste. The calculated output radionuclide fluxes of this model are compared with the fluxes calculated with a homogeneous model and a model with a heterogeneous hydraulic conductivity distribution. This analysis shows that the heterogeneity of the diffusion parameters has a much larger effect on the calculated output radionuclide fluxes than the heterogeneity of hydraulic conductivity in the low permeability medium under study. [less ▲]

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See detailStochastic analysis of the effect of spatial variability of diffusion parameters on radionuclide transport in low permeability clay layer
Huysmans, Marijke; Dassargues, Alain ULg

in Calibration and Reliability in Groundwater Modelling: From Uncertainty to Decision Making (2006)

Most studies that incorporate subsurface heterogeneity in groundwater flow and transport models only analyze and simulate the spatial variability of hydraulic conductivity. Heterogeneity of the other flow ... [more ▼]

Most studies that incorporate subsurface heterogeneity in groundwater flow and transport models only analyze and simulate the spatial variability of hydraulic conductivity. Heterogeneity of the other flow and transport parameters is usually neglected. This approach is often justified, but there are however cases in which disregarding the heterogeneity of the other flow and transport parameters can be questionable. In low permeability media, for instance, diffusion is often the dominant transport mechanism. It therefore seems logical to incorporate the spatial variability of the diffusion parameters in the transport model. This study therefore analyzes and simulates the spatial variability of the effective diffusion coefficient and the diffusion accessible porosity with geostatistical techniques and incorporates their heterogeneity in the transport model of a low permeability formation. The calculated output radionuclide fluxes of this model are compared with the fluxes calculated with a homogeneous model and a model with a heterogeneous hydraulic conductivity distribution. This analysis shows that the heterogeneity of the diffusion parameters has a much larger effect on the calculated output radionuclide fluxes than the heterogeneity of hydraulic conductivity. [less ▲]

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See detailStochastic analysis of the recharge uncertainty of a regional aquifer in extreme arid conditions
Rojas, Rodrigo; Dassargues, Alain ULg

in Stauffer, Fr.; Dassargues, Alain (Eds.) Quantitative Geology from Multiple Sources: S10 Use of multiple sources in conditioning/calibrating groundwater flow and transport models (2006)

The Pampa del Tamarugal Aquifer (PTA) is an important source of groundwater in northern Chile. Since the study area is situated in the Atacama Desert, the estimation of groundwater recharge based on ... [more ▼]

The Pampa del Tamarugal Aquifer (PTA) is an important source of groundwater in northern Chile. Since the study area is situated in the Atacama Desert, the estimation of groundwater recharge based on conventional hydrological methods is subject to large uncertainties. To account for variations in the groundwater balance, caused by uncertainties in the average recharge rates, randomly generated recharge values with different levels of uncertainty are simulated using a groundwater flow model. Results show that evaporation and groundwater outflows are insensitive to the recharge uncertainty, while the storage terms can vary considerably. Considering current groundwater abstraction and random recharge rates, it is unlikely that the cumulative discharged volume from the aquifer, after a 45 years simulation period, will be larger than 12% of the estimated groundwater reserve. Simulated groundwater heads fluctuations due to uncertainties in the average recharge rates are more noticeable in certain areas. These fluctuations could explain anomalies in the observed groundwater heads in these areas. [less ▲]

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See detailStochastic Behaviour of European Stock Indices
Corhay, Albert ULg; Tourani Rad, Alireza

in Flavell, Richard (Ed.) Modelling Reality and Personal Modelling (1993)

Detailed reference viewed: 5 (2 ULg)
See detailStochastic Dimension Reduction of Multi Physics Systems through Measure Transformation
Phipps, Eric; Constantine, Paul; Red-Horse, John et al

Conference (2013, February 26)

Uncertainty quantification of multiphysics systems represents numerous mathematical and computational challenges. Indeed, uncertainties that arise in each physics in a fully coupled system must be ... [more ▼]

Uncertainty quantification of multiphysics systems represents numerous mathematical and computational challenges. Indeed, uncertainties that arise in each physics in a fully coupled system must be captured throughout the whole system, the so-called curse of dimensionality. We present techniques for mitigating the curse of dimensionality in network-coupled multiphysics systems by using the structure of the network to transform uncertainty representations as they pass between components. Examples from the simulation of nuclear power plants will be discussed. [less ▲]

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See detailStochastic Dimension Reduction Techniques for Uncertainty Quantification of Multiphysics Systems
Phipps, Eric; Arnst, Maarten ULg; Constantine, Paul et al

Conference (2012, April 02)

Uncertainty quantification of multiphysics systems represents numerous mathematical and computational challenges. Indeed, uncertainties that arise in each physics in a fully coupled system must be ... [more ▼]

Uncertainty quantification of multiphysics systems represents numerous mathematical and computational challenges. Indeed, uncertainties that arise in each physics in a fully coupled system must be captured throughout the whole system, the so-called curse of dimensionality. We present techniques for mitigating the curse of dimensionality in network-coupled multiphysics systems by using the structure of the network to transform uncertainty representations as they pass between components. Examples from the simulation of nuclear power plants will be discussed. [less ▲]

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See detailStochastic excitation of gravity modes in massive main-sequence stars
Samadi, R.; Belkacem, Kevin ULg; Goupil, M. J. et al

in Astrophysics & Space Science (2010), 328

We investigate the possibility that gravity modes can be stochastically excited by turbulent convection in massive main-sequence (MS) stars. We build stellar models of MS stars with masses M=10 M [SUB]ȯ ... [more ▼]

We investigate the possibility that gravity modes can be stochastically excited by turbulent convection in massive main-sequence (MS) stars. We build stellar models of MS stars with masses M=10 M [SUB]ȯ[/SUB],15 M [SUB]ȯ[/SUB], and 20 M [SUB]ȯ[/SUB]. For each model, we then compute the power supplied to the modes by turbulent eddies in the convective core (CC) and the outer convective zones (OCZ). We found that, for asymptotic gravity modes, the major part of the driving occurs within the outer iron convective zone, while the excitation of low n order modes mainly occurs within the CC. We compute the mode lifetimes and deduce the expected mode amplitudes. We finally discuss the possibility of detecting such stochastically-excited gravity modes with the CoRoT space-based mission. [less ▲]

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See detailStochastic excitation of non-radial modes. I. High-angular-degree p modes
Belkacem, Kevin ULg; Samadi, R.; Goupil, Marie-José et al

in Astronomy and Astrophysics (2008), 478

Context: Turbulent motions in stellar convection zones generate acoustic energy, part of which is then supplied to normal modes of the star. Their amplitudes result from a balance between the efficiencies ... [more ▼]

Context: Turbulent motions in stellar convection zones generate acoustic energy, part of which is then supplied to normal modes of the star. Their amplitudes result from a balance between the efficiencies of excitation and damping processes in the convection zones. Aims: We develop a formalism that provides the excitation rates of non-radial global modes excited by turbulent convection. As a first application, we estimated the impact of non-radial effects on excitation rates and amplitudes of the high-angular-degree modes that are observed on the Sun. Methods: A model of stochastic excitation by turbulent convection was developed to compute the excitation rates and then successfully applied to solar radial modes. We generalise this approach to the case of non-radial global modes. This enables us to estimate the energy supplied to high-(l) acoustic modes. Qualitative arguments, as well as numerical calculations, are used to illustrate the results. Results: We find that non-radial effects for p modes are non-negligible: - For high-n modes (i.e. typically n > 3) and for high values of l, the power supplied to the oscillations depends on the mode inertia. - For low-n modes, independent of the value of l, the excitation is dominated by the non-radial components of the Reynolds stress term. Conclusions: Our numerical investigation of high-l p modes shows that the validity of the present formalism is limited to l < 500 due to the spatial separation of scale assumption. Thus, a model for very high-l p-mode excitation rates calls for further theoretical developments; however, the formalism is valid for solar g modes, which will be investigated in a paper in preparation. [less ▲]

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See detailStochastic excitation of nonradial modes. II. Are solar asymptotic gravity modes detectable?
Belkacem, Kevin ULg; Samadi, R.; Goupil, M. J. et al

in Astronomy and Astrophysics (2009), 494

Context: Detection of solar gravity modes remains a major challenge to our understanding of the inner parts of the Sun. Their frequencies would enable the derivation of constraints on the core physical ... [more ▼]

Context: Detection of solar gravity modes remains a major challenge to our understanding of the inner parts of the Sun. Their frequencies would enable the derivation of constraints on the core physical properties, while their amplitudes can put severe constraints on the properties of the inner convective region. Aims: Our purpose is to determine accurate theoretical amplitudes of solar g modes and estimate the SOHO observation duration for an unambiguous detection of individual modes. We also explain differences in theoretical amplitudes derived from previous works. Methods: We investigate the stochastic excitation of modes by turbulent convection, as well as their damping. Input from a 3D global simulation of the solar convective zone is used for the kinetic turbulent energy spectrum. Damping is computed using a parametric description of the nonlocal, time-dependent, convection-pulsation interaction. We then provide a theoretical estimation of the intrinsic, as well as apparent, surface velocity. Results: Asymptotic g-mode velocity amplitudes are found to be orders of magnitude higher than previous works. Using a 3D numerical simulation from the ASH code, we attribute this to the temporal-correlation between the modes and the turbulent eddies, which is found to follow a Lorentzian law rather than a Gaussian one, as previously used. We also find that damping rates of asymptotic gravity modes are dominated by radiative losses, with a typical life time of 3 × 10[SUP]5[/SUP] years for the ell=1 mode at nu=60 muHz. The maximum velocity in the considered frequency range (10-100 muHz) is obtained for the ell=1 mode at nu=60 muHz and for the ell=2 at nu=100 muHz. Due to uncertainties in the modeling, amplitudes at maximum i.e. for ell=1 at 60 muHz can range from 3 to 6 mm s[SUP]-1[/SUP]. The upper limit is too high, as g modes would have been easily detected with SOHO, the GOLF instrument, and this sets an upper constraint mainly on the convective velocity in the Sun. [less ▲]

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See detailStochastic Fertility, Moral Hazard, and the Design of Pay-As-You-Go Pension Plans
Pestieau, Pierre ULg; Cremer, H., Gahvari, F.

in CESifo Economic Studies (2011), 57(2), 332348

This article models a two-period overlapping generations economy in the steady state where the realization of the quantity/quality number of children depends on an initial investment in children and on a ... [more ▼]

This article models a two-period overlapping generations economy in the steady state where the realization of the quantity/quality number of children depends on an initial investment in children and on a random shock. It shows that the implementation of the first-best allocation, in which the effort level is publicly observable, requires a subsidy on the investment in children. There should also be full insurance with respect to second-period consumption and pensions must be invariant to the number of children. On the other hand, when investment is unobservable and one cannot subsidize it, the full insurance property goes away. In this case, pensions must be linked positively to the number of children. [less ▲]

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See detailStochastic Finite Element Analysis of Thermoelastic Effects in Micro-Resonators
Lepage, Séverine; Golinval, Jean-Claude ULg

Conference (2006, July 17)

In the design of micro-electromechanical systems (MEMS) such as micro-resonators, dissipation mechanisms may have detrimental effects on the quality factor. One of the major dissipation phenomena to ... [more ▼]

In the design of micro-electromechanical systems (MEMS) such as micro-resonators, dissipation mechanisms may have detrimental effects on the quality factor. One of the major dissipation phenomena to consider in such systems is thermoelastic damping. Hence, the performance of such MEMS is directly related to their thermoelastic quality factor which has to be predicted accurately. Moreover, the performance of MEMS can vary because manufacturing processes may leave substantial uncertainty in the geometry and in the material properties of the device. The reliability of MEMS devices is affected by the inability to accurately predict the stochastic behavior of the system due to the presence of these uncertainties. The aim of this paper is to provide a framework to account for uncertainties in the finite element analysis of the thermoelastic quality factor. The present work focuses on second moment approaches, in which the first two statistical moments, i.e. the mean and the variance, are estimated. The perturbation stochastic finite element method is used in order to determine the mean and the variance of the thermoelastic quality factor of MEMS. The perturbation SFEM [1] consists in a deterministic analysis complemented by a sensitivity analysis with respect to the random parameters. This enables the development of a Taylor series expansion of the response, from which the mean and variance of the response can be derived knowing the mean and variance of the random parameters. The perturbation SFEM is applied on the analysis of the thermoelastic quality factor of a micro-beam whose elastic modulus is considered as a random variable. Due to the nature of the thermoelastic problem, this study involves the calculation of eigenvalue sensitivities of a non-symmetric damped system [2]. The mean and variance of the quality factor are compared to the results obtained by Monte-Carlo simulations. References: [1] Kleiber, M., Hien, T.D., The stochastic finite element method: basic perturbation technique and computer implementation. Wiley & Sons, Chichester, 1992. [2] Choi, K.M., Jo, H.K., Kim, W.H., Lee, I.W., Sensitivity analysis of non-conservative eigensystems, Journal of Sound and Vibration, v. 274, p. 997-1011, 2004. [less ▲]

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