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See detailNHC-Ru complexes- Friendly catalytic tools for manifold chemical transformations
Dragutan, Valerian; Dragutan, Ileana; Delaude, Lionel ULg et al

in Coordination Chemistry Reviews (2007), 251(5-6), 765-794

N-Heterocyclic carbenes are now commonly encountered in organometallic and inorganic coordination chemistry. The increasing attention they enjoy is due to their ability to act as ancillary ligands in a ... [more ▼]

N-Heterocyclic carbenes are now commonly encountered in organometallic and inorganic coordination chemistry. The increasing attention they enjoy is due to their ability to act as ancillary ligands in a growing number of transition metal catalysts or even to play the role of nucleophilic reagents and catalysts in diverse organic transformations. As a fine addition to the NHC-Ru-alkylidenes, popular for their tremendous success in metathesis chemistry, an array of robust and stable Ru-NHCs has proven their utility in non-metathetical reactions. The present review surveys different classes of Ru-NHCs and their applications as efficient catalysts (or precatalysts) in several types of fundamental organic processes e.g. hydrogenation, hydrogen transfer, isomerization, cycloisomerization, cyclopropanation, hydrosilylation, allylation and deallylation, enol-ester synthesis, heterocycle synthesis, C-C alkyne coupling, Kharasch addition and ATRP. A special section is devoted to tandem processes some of which include concurrent or sequential metathesis steps. Relevant mechanistic and stereochemical aspects related to NHC-Ru catalysis will be highlighted. (c) 2006 Elsevier B.V. All rights reserved. [less ▲]

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See detailNi fantôme ni zombie. L'émergence de la conscience subjective dans le flux des expériences
Leclercq, Bruno ULg

in Bulletin d'Analyse Phénoménologique (2014), 10(3), 1-28

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See detailNi mécanique, ni rationnel. Un point de vue interactionnel sur la communication animale
Servais, Véronique ULg

in Wittezaele, Jean-Jacques (Ed.) La double contrainte. L'influence des paradoxes de Bateson en sciences humaines (2008)

Detailed reference viewed: 122 (15 ULg)
See detailNi réalisme ni conventionalisme : Edmund Husserl et Ludwig Wittgenstein, philosophes de la logique et des mathématiques
Leclercq, Bruno ULg

in Beets, François; Gillet, Eric (Eds.) Logique en perspective (2000)

Detailed reference viewed: 44 (2 ULg)
See detailNi théoriser les pratiques, ni pratiquer les théories – Une rencontre improbable
Delhalle, Nancy ULg

Conference (2013, October 08)

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See detailNi-doped carbon xerogels for H2 storage
Zubizarreta, Leire; Menénez, J. A.; Pis, J. J. et al

Poster (2009, October 25)

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See detailNi-doped carbon xerogels for H2 storage
Zubizarreta, Leire; Menendez, J. A.; Job, Nathalie ULg et al

in Carbon (2010), 48

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See detailNi/Al2O3 xerogel catalysts for biogas cleaning
Claude, Vincent ULg; Heinrichs, Benoît ULg; Lambert, Stéphanie ULg

Poster (2013, August 29)

This poster summarize the firsts results of the PhD project started on October 2012 about the catalytic purification of biogas. The aim of this project consists in the development of Ni/Al2O3 catalyst in ... [more ▼]

This poster summarize the firsts results of the PhD project started on October 2012 about the catalytic purification of biogas. The aim of this project consists in the development of Ni/Al2O3 catalyst in order to reform the tars present in the outlet gas of biomass gasifier. In order to obtain catalysts with high performance and lifetime, materials need to have optimized specific surface and metal particle dispersion. This poster investigate the effect of different surfactants (Pluronic P123; F127; stéarique acide, EDAS) on the materials properties. [less ▲]

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See detailNi/SiO2 Catalyst Preparation Studies using SBA-15 as a Model Support and quantitative Electron Tomography Characterisation
de Jongh, Petra; Friedrich, Heiner; Gommes, Cédric ULg et al

Poster (2008, September)

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See detailNicardipine Protocol for Cabg Using the Radial Artery Clinical and Angiographic Data
RADERMECKER, Marc ULg; Grenade, Thierry ULg; Cao-Thian, S. K. et al

in Acta Chirurgica Belgica (2001), 101(4, Jul-Aug), 185-9

The routine use of arterial grafts in coronary surgery is facilitated by peroperative adjunction of antispasmodic drug to reduce the event of spasm. Diltiazem has been favoured in most clinical studies ... [more ▼]

The routine use of arterial grafts in coronary surgery is facilitated by peroperative adjunction of antispasmodic drug to reduce the event of spasm. Diltiazem has been favoured in most clinical studies devoted to the radial artery graft. The aim of this study was to assess the efficacy of a spasm preventing protocol associating hydrostatic dilation of the graft with a diluted solution of papaverine and nicardipine infusion, starting preoperatively and continued postoperatively in i.v. and per os forms. Between September 1996 and March 1997, a consecutive series of 50 patients underwent myocardial revascularization using the radial artery. The radial artery was prepared by hydrostatic dilation with papaverine (1%) and nicardipine was administrated at 0.25 microgram/kg/min and titrated according to the arterial systemic pressure. Operative mortality was 4% (sepsis). There was no evidence of perioperative MI nor hypoperfusion syndrome. Mean CKMB level at 18 hours was 36 micrograms/l. No ischaemic anomalies of the ECG were detected. Angiography performed in the last 20 patients showed a 98% (51/52) permeability rate for all graft; 19/20 radial grafts (95%) were patent. One radial graft presented a 50% stenosis at the proximal anastomosis, and another a moderate spasm (40%) in the middle part of the conduit. This study confirms that the radial artery conduit can be used with satisfactory results for routine coronary artery bypass. The use of nicardipine allows the control the vasoreactivity of the radial graft without totally obviating at least angiographic spasm. This drug is easy to titrate, and well tolerated in association to beta-blockers in the routine perioperative management of the coronary patients. [less ▲]

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See detailNiche conservatism and conservation biology of Lepilemur in northwest Madagascar
Wilmet, Leslie ULg; Vermeulen, Cédric ULg; Schwitzer, Christoph et al

Conference (2014, August 14)

The main goals of our study is to verify the existence and extent of niche conservatism in three closely related species within the genus Lepilemur, and to draw conclusions on the applicability of ... [more ▼]

The main goals of our study is to verify the existence and extent of niche conservatism in three closely related species within the genus Lepilemur, and to draw conclusions on the applicability of conservation protocols to a broader array of Lepilemur species. The genus is an exemplary of the mammalian fauna of Madagascar which high biological diversity is under increasingly severe threat from anthropogenic degradation of its forest habitats. This study focuses particularly on three poorly-known Lepilemur taxa: L. sahamalazensis, L. dorsalis and L. mittermeieri, uplisted into one of the threatened categories of the IUCN Red List.The genus is particularly negatively affected by deforestation and habitat fragmentation and all have a small distribution range, fairly small total populations. Their pattern of distribution appears to have been established through vicariant speciation, probably driven by changes in the configuration of the hydrographic system. Such a pattern permits to expect a high level of niche conservatism. We present here our preliminary results of an exploratory mission on 1) evaluation of Lepilemur abundance in forest patches on the Ampasindava Peninsula, the Sahamalaza Peninsula and the Manongarivo Special Reserve 2) sleeping sites characteristics of the three studied species. [less ▲]

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See detailNiche differentiation among neotropical soldierless soil-feeding termites revealed by stable isotope ratios
Bourguignon, Thomas; Sobotnik, Jan; Lepoint, Gilles ULg et al

in Soil Biology & Biochemistry (2009), 41

Termites represent one of the most abundant belowground animal taxa in tropical rainforests, where their species richness is much higher than in any other ecosystem. This high diversity in soil ecosystems ... [more ▼]

Termites represent one of the most abundant belowground animal taxa in tropical rainforests, where their species richness is much higher than in any other ecosystem. This high diversity in soil ecosystems is however difficult to explain by classical Hutchinsonian niche theory, as there is little evidence for spatial or temporal separation between species. Using δ13C and δ15N isotopic ratios, we tested if resource partitioning along the humification gradient occurs in neotropical soldierless termites of the Anoplotermes-group. Two distinct sites were investigated to check if interspecific differences are transposable between sites. Significant differences in δ15N were found between species of the Anoplotermes-group. Although some species displayed higher intersite δ15N variation than others, species-average δ15N values for both sites were highly correlated, showing that sympatric soldierless soil-feeding termites feed on distinct components of the soil. Our data also suggest that some species are more likely to shift along this gradient than others, in response to overall habitat conditions or to the presence of competitors. Feeding niche differentiation can therefore account for the high species richness and diversity of soldierless soil-feeding termites in neotropical rainforests. [less ▲]

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See detailNiche modeling within and between species in the genus Erythrophleum : intergating phylogenetic data and environmental niche models to explore speciation mechanisms
Gorel, Anaïs ULg

Poster (2015, March 21)

In this study we investigated the climatic niche between and within closely related tropical tree species of the Erythrophleum genus (Fabaceae, Caesalpinioideae): E. ivorense, E. suaveolens and E ... [more ▼]

In this study we investigated the climatic niche between and within closely related tropical tree species of the Erythrophleum genus (Fabaceae, Caesalpinioideae): E. ivorense, E. suaveolens and E. africanum. Two major hypotheses, the refuge theory and the ecological gradient hypothesis, have been developed to explain the current distribution of tree clades across tropical Africa. To identify the speciation mechanisms, we used a combination of geographic data and environmental factors to quantify the degree of niche conservatism (or divergence). We used two sets of distribution data for the purpose of this study. Species distribution data for the whole of tropical Africa was gathered from herbarium records. Distribution data of the two sister species E. ivorense and E. suaveolens assigned to genetic cluster were available for the lowland tropical forests of western and central Africa. Using a Species Distribution Model approach based on MaxEnt algorithm we tested for the environmental differences between species and genetic clusters within species. At species level, the climatic niche significantly differed and only slightly overlapped, suggesting a parapatric speciation along a climatic gradient. Within the two sister species, the niche of the parapatric central African genetic clusters suggests mostly a secondary contact following the recolonization from different forest refugia. [less ▲]

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See detailNiche-innovations between breaks and continuities with the regime? A case study into the dairy sector in Belgium
Feyereisen, Marlène ULg; Melard, François ULg; Stassart, Pierre M ULg

Conference (2015, August)

Today, the absolute dichotomy between alternative food networks (AFNs) and the conventional agrofood system tends to be obsolete. Indeed, many AFNs are far from being radical and are more likely to ... [more ▼]

Today, the absolute dichotomy between alternative food networks (AFNs) and the conventional agrofood system tends to be obsolete. Indeed, many AFNs are far from being radical and are more likely to maintain relations with the current socio-technical regime between breaks and continuities. This contribution is a complement to the Transition Theory and the Multi-Level Perspective by underlying the fragile borders between the two levels of the niche-innovations and the socio-technical regime: some imperfect projects, full of contradictions, are participating to the transition of the system. And this is particularly true in the case of highly locked in systems. The dairy sector in Western European countries is one of those highly locked in systems. Our case study, the Belgian fair-trade milk “Fairebel”, is a project built by dairy farmers to react to the 2009 dairy crisis and to the increasingly neoliberal dairy sector; and to get a better price (or fair price) for their activity. However, the concretization of this project brought its share of contradictions regarding the common definition of fair trade milk. As a result, the “Fairebel” project maintains relations between breaks and continuities with the regime. This contribution suggests modes of governance for the stakeholders of these non-radical niches which are precious to engage change in highly locked in system without being picked up by the dominant regime and thus, keep this regime under pressure. [less ▲]

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See detailNicholas Jose's 'Black Sheep'
Delrez, Marc ULg

Conference (2005, September 24)

Detailed reference viewed: 17 (1 ULg)