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See detailNew Economy, New Myths ? The American Media Industry in Perspective
Geuens, Geoffrey ULg

Scientific conference (2008, October 16)

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See detailNew efficient bicomponent organocatalysts for the chemical fixation of CO2 onto epoxides: a theoretical study
Alves, Margot ULg; Méreau, Raphaël; Grignard, Bruno ULg et al

Poster (2015, May 18)

Regarding the economic and environmental issues, valorising CO2 as a C1 feedstock for producing useful building blocks is seducing as it is a free and abundant waste resulting from the human activity ... [more ▼]

Regarding the economic and environmental issues, valorising CO2 as a C1 feedstock for producing useful building blocks is seducing as it is a free and abundant waste resulting from the human activity. Cyclic carbonates are useful compounds that found application as green solvents, electrolytes for lithium battery or monomers for polycarbonates or polyurethanes synthesis. These cyclocarbonates can be synthesized with a total atom economy by chemical fixation of CO2 onto epoxides using organometallic complexes or organocatalysts. To date, although this area of research has been the subject of many studies, the identification and development of (organo)catalysts highly efficient under mild experimental conditions still remains challenging. In this context, we developed a new organocatalytic platform based on the use of ammonium salts in combination with single or double hydrogen bond donor activators derived from fluorinated alcohols that showed unexpected booster effect. In this contribution, the ammonium/fluoroalcohol promoted CO2/propylene oxide coupling was investigated through detailed kinetic studies by IR spectroscopy under pressure and results were compared to the most efficient organocatalysts based on ammonium salts and (multi)phenolic derivatives that were reported in the literature. In order to finely understand the reaction mechanism, this study was completed by molecular modeling. DFT calculations showed that the addition of H-bond donors (HBD) with hexafluoroisopropanol functionalities modified the mechanism of the ammonium promoted coupling of CO2 with epoxides. HBDs dramatically decreased the epoxide ring-opening step barrier which highlights the key role of the fluorinated activators in stabilizing the intermediates and transitions states by inter- and intra-molecular hydrogen bonds. [less ▲]

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See detailA new elastic-visco-plastic damage model for annealed aluminium: theory, calibration and validation
Habraken, Anne ULg; Zhang, Lihong ULg; Wang, X. C. et al

in Benallal, A. (Ed.) Proceedings of the Continuous Damage and Fracture Symposium (2000)

This article describes an energy based, two variables, isotropic damage model merged with Bodner's elasto-visco-plastic model and implemented in a non-linear finite element code. The procedure to identify ... [more ▼]

This article describes an energy based, two variables, isotropic damage model merged with Bodner's elasto-visco-plastic model and implemented in a non-linear finite element code. The procedure to identify the parameters of the model and its experimental validation are presented and applied to an annealed aluminium. [less ▲]

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See detailNew emission lines in Mira Ceti
Swings, Polydore ULg

in Publications of the Astronomical Society of the Pacific [=PASP] (1940), 52

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See detailNew Energy Levels in Ne II deduced from FTS spectra in the Infrared Region (1800-9000 cm-1)
Quinet, Pascal ULg; Palmeri, P.; Biémont, Emile ULg

in Physica Scripta (1994), 49

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See detailA New Energy-Dissipative Momentum-Conserving Time Integration Scheme Using the Variational Updates Framework.
Noels, Ludovic ULg; Stainier, Laurent ULg; Ponthot, Jean-Philippe ULg

(2007)

Although they are the most widely used time integration algorithms for finite-element discretizations, algorithms based on the Newmark family are numerically stable only for linear models. To overcome ... [more ▼]

Although they are the most widely used time integration algorithms for finite-element discretizations, algorithms based on the Newmark family are numerically stable only for linear models. To overcome that drawback, researches have recently focused on time integration algorithms stable in the non-linear range, leading to the development of Energy Momentum Conserving Algorithms or EMCA. A new Energy Momentum Conserving Algorithm was recently presented by the authors for elasto-plastic material models. This algorithm is based on a variational formulation of elasto-plastic updates for which the stress tensor always derives from an incremental potential, even when plastic behavior is considered. In this work this formalism is used to develop Energy-Dissipative Momentum-Conserving time integration algorithms, which have property of being stable in non-linear range, but also dissipate high-frequency numerical modes to improve the convergence properties. Using the potential existence of the variational updates framework, the verification of the numerical dissipation of energy in the non-linear range can easily be demonstrated. [less ▲]

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See detailA new ent-clerodane diterpenoid from Crassocephalum bauchiense Huch. (Asteraceae).
Tchinda, Alembert T.; Mouokeu, Simplice R.; Ngono, Rosalie A. N. et al

in Natural product research (2015)

A phytochemical investigation of the whole plant of Crassocephalum bauchiense Huch. resulted in the isolation of a new clerodane diterpenoid, ent-2beta,18,19-trihydroxycleroda-3,13-dien-16,15-olide (1 ... [more ▼]

A phytochemical investigation of the whole plant of Crassocephalum bauchiense Huch. resulted in the isolation of a new clerodane diterpenoid, ent-2beta,18,19-trihydroxycleroda-3,13-dien-16,15-olide (1), together with two known flavonoids 3',5-dihydroxy-4',5',6,7,8-pentamethoxyflavone (2) and 4',5-dihydroxy-3',5',6,7,8-pentamethoxyflavone (3). The compounds were tested against the chloroquine-sensitive 3D7 strain of Plasmodium falciparum. Compound 2 showed weak activity (IC50 = 10.1 g/mL) whilst compounds 1 and 3 were inactive. The structures of the compounds were elucidated by using detailed spectral analyses, especially 1H and 13C NMR, 1H-1H COSY, NOESY, HMBC and HR-ESI-MS. [less ▲]

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See detailA New Equilibrium Cell with Variable Cell Volume for Static Vapour-Pressure Measurements
Gaube, J; Hammer, S; Pfennig, Andreas ULg

in Fluid Phase Equilibria (1996), 123((1-2)), 245-257

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See detailA new era of coma and consciousness science.
Owen, Adrian M.; Schiff, Nicholas D.; Laureys, Steven ULg

in Progress in Brain Research (2009), 177

In the past ten years, rapid technological developments in the field of neuroimaging have produced a cornucopia of new techniques for examining both the structure and function of the human brain in vivo ... [more ▼]

In the past ten years, rapid technological developments in the field of neuroimaging have produced a cornucopia of new techniques for examining both the structure and function of the human brain in vivo. In specialized centers, many of these methods are now being employed routinely in the assessment of patients diagnosed with disorders of consciousness, mapping patterns of residual function and dysfunction and helping to reduce diagnostic errors between related conditions such as the vegetative and minimally conscious states. Moreover, such efforts are beginning to provide important new prognostic indicators, helping to disentangle differences in outcome on the basis of a greater understanding of the underlying mechanisms responsible and providing information that will undoubtedly contribute to improved therapeutic choices in these challenging populations. Of course, these emerging technologies and the new information that they provide will bring new ethical challenges to this area and will have profound implications for clinical care and medical-legal decision-making in this population of patients. We review the most recent work in this area and suggest that the future integration of emerging neuroimaging techniques with existing clinical and behavioral methods of assessment will pave the way for new and innovative applications, both in basic neuroscience and in clinical practice. [less ▲]

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See detailA new era of improving progression-free survival with dual blockade in postmenopausal HR, HER2 advanced breast cancer.
Jerusalem, Guy ULg; Bachelot, Thomas; Barrios, Carlos et al

in Cancer treatment reviews (2014)

Disease progression despite existing endocrine therapies remains a major challenge to the effective management of hormone-receptor-positive (HR+), human epidermal growth factor receptor-2-negative (HER2 ... [more ▼]

Disease progression despite existing endocrine therapies remains a major challenge to the effective management of hormone-receptor-positive (HR+), human epidermal growth factor receptor-2-negative (HER2-), advanced breast cancer. Recent advances in elucidating the molecular mechanisms of disease progression have identified the existence of adaptive "cross-talk" between the estrogen receptor (ER) and various growth factor receptor and intracellular signaling pathways, allowing breast cancer cells to escape the inhibitory effects of endocrine therapy. These findings provide the clinical rationale for enhancing or extending endocrine sensitivity by combining endocrine therapy with a targeted agent against a compensatory pathway. In BOLERO-2, adding the mTOR inhibitor everolimus to endocrine therapy significantly improved progression-free survival (PFS) in patients with HR+ advanced breast cancer previously treated with nonsteroidal aromatase inhibitor therapy. Notably, PFS benefits were comparable in subgroup analyses of first- and later-line settings. These results contrast with those of the large first-line HORIZON study, wherein adding the mTOR inhibitor temsirolimus to endocrine therapy did not improve PFS. Therefore, it is unclear whether a targeted agent should only be combined with endocrine therapy to restore endocrine sensitivity or whether it may also prevent or delay resistance in hormone-sensitive advanced breast cancer. Numerous additional targeted agents are currently being evaluated in combination with endocrine therapies, including PI3K, cyclin-dependent kinase 4/6, SRC, and histone deacetylase inhibitors. Appropriate patient selection based on prior treatment history will become increasingly important in maximizing the incremental benefit derived from these new agents combined with existing endocrine therapies in HR+ advanced breast cancer. [less ▲]

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See detailNew estimate of the carbon sink strength of EU forests integrating flux measurements, field surveys, and space observations: 0.17-0.35 Gt(C)
Martin, Philippe; Valentini, R.; Jacques, M. et al

in AMBIO : A Journal of the Human Environment (1998), 27(7), 582-584

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See detailNew evaluation therapies for sepsis.
Deby; Damas, Pierre ULg; Lamy, Maurice ULg

in Current Opinion in Anaesthesiology (1999), 12(2), 121-7

This article presents an analysis of the literature of the last 2 years on the treatment of sepsis and septic shock. It appears that most of the antimediator therapies applied in phase II or III clinical ... [more ▼]

This article presents an analysis of the literature of the last 2 years on the treatment of sepsis and septic shock. It appears that most of the antimediator therapies applied in phase II or III clinical trials yielded disappointing results. But, many other therapeutic approaches are proposed or are ongoing, and many papers report critical analysis of the reasons for the lack of success of past clinical trials. [less ▲]

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See detailA new Event- stratigraphical marked bed in the uppermost Devonian of the Ardenno-Rhenish Massif.
Dreesen, R; Streel, Maurice ULg

in Annales de la Société Géologique de Belgique (1985), 108

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See detailNew evidence against the existence of very massive stars
Heydari-Malayeri, M.; Remy, M.; Magain, Pierre ULg

in Astronomy and Astrophysics (1988), 201

The most luminous stars are our first probes for exploring the stellar content of distant galaxies. They have also been used as standard candles for extragalactic distance determinations. The authors show ... [more ▼]

The most luminous stars are our first probes for exploring the stellar content of distant galaxies. They have also been used as standard candles for extragalactic distance determinations. The authors show that Sk -66°41, one of the brightest stars in the Large Magellanic Cloud (LMC), is a multiple system consisting of at least six components. This result has important consequences for the understanding of star formation mechanisms, especially the upper limit to stellar masses. Moreover, when primary distance indicators are not available, care should be taken in using the brightest blue stars. The derived distances, depending on the number of cluster members, can easily be underestimated by more than a factor 2, leading to larger values for the Hubble constant. [less ▲]

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See detailNew evidence for a non-cofactor role of thiamine phosphate derivatives
Bettendorff, Lucien ULg

Scientific conference (2007)

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See detailNew evidence for a ring around Neptune
Manfroid, Jean ULg; Haefner, R.; Bouchet, P.

in Astronomy and Astrophysics (1986), 157

This paper presents an account of observations of the 1984 July 22 appulse of Neptune to SAO 186001. An occultation of 0.8 s duration (FWHM) was detected from La Silla at 05:40:08.6 UTC by two telescopes ... [more ▼]

This paper presents an account of observations of the 1984 July 22 appulse of Neptune to SAO 186001. An occultation of 0.8 s duration (FWHM) was detected from La Silla at 05:40:08.6 UTC by two telescopes operating in I and K bands. This, combined with earlier observations led to the recognition of the existence of an irregular ring around Neptune. [less ▲]

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See detailNew evidence for the fracture-reducing effectiveness of monofluorophosphate: practical implications
Reginster, Jean-Yves ULg

in Osteoporosis International (1998), 8(S3), 148

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See detailNew evidence of a relationship between PCB and the cause of death of North Sea harbour porpoises
Jauniaux, Thierry ULg; Das, Krishna ULg; Haelters, Jan et al

in proceeding of the annual conference (2011)

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See detailNew Evidence of Human Activities during the Holocene in the Lowland Forests of the Northern Congo Basin
Morin-Rivat, Julie ULg; Fayolle, Adeline ULg; Gillet, Jean-François ULg et al

in Radiocarbon (2014), 56(1), 209-220

In the last decade, the myth of the pristine tropical forest has been seriously challenged. In central Africa, there is a growing body of evidence for past human settlements along the Atlantic forests ... [more ▼]

In the last decade, the myth of the pristine tropical forest has been seriously challenged. In central Africa, there is a growing body of evidence for past human settlements along the Atlantic forests, but very little information is available about human activities further inland. In this study, we aimed at determining the temporal and spatial patterns of human activities in an archaeologically unexplored area of 110,000 km² located in the northern Congo Basin and currently covered by dense forest. Fieldwork involving archaeology as well as archaeobotany was undertaken in 36 sites located in southeastern Cameroon and in the northern Republic of Congo. Evidence of past human activities through either artifacts or charred botanical remains was observed in all excavated test pits across the study area. The set of 43 radiocarbon dates extending from 15,000 BP to the present time showed a bimodal distribution in the Late Holocene which was interpreted as two phases of human expansion with an intermediate phase of depopulation. The 2300–1300 BP phase is correlated with the migrations of supposed farming populations from northwestern Cameroon. Between 1300 and 670 BP, less material could be dated. This is in agreement with the population collapse already reported for central Africa. Following this, the 670–20 BP phase corresponds to a new period of human expansion known as the Late Iron Age. These results bring new and extensive evidence of human activities in the northern Congo Basin and support the established chronology for human history in central Africa. [less ▲]

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See detailNew evidence on beta stationarity and forecast for belgian common stocks
Hawawini, Gabriel A; Michel, Pierre-Armand ULg; Corhay, Albert ULg

in Journal of Banking & Finance (1985), 9(4), 553-560

Based on a comprehensive sample of 170 securities traded continuously on the Brussels Stock Exchange from December 1966 to December 1983 this paper presents evidence which indicates that the stationarity ... [more ▼]

Based on a comprehensive sample of 170 securities traded continuously on the Brussels Stock Exchange from December 1966 to December 1983 this paper presents evidence which indicates that the stationarity of beta-coefficients is not as strong as reported in previous studies which were based on smaller samples. It is shown, however, that beta forecast can be generally improved using an adjustment method and that the improvement is highest for portfolios of increasing size. [less ▲]

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