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See detailNon-adiabatic effects in photodissociation of bromoacetyl chloride
Bacchus-Montabonel, Marie-Christine; Vaeck, Nathalie; Lasorne, Benjamin et al

in Chemical Physics Letters (2003), 374

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See detailNon-adiabatic interactions in unimolecular decay. I.
Desouter, Michèle ULg; Leclerc, Jean-Claude; Lorquet, Jean-Claude

in Chemical Physics (1975), 9

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See detailNon-adiabatic interactions in unimolecular decay. II. Simplified formalism
Desouter, Michèle ULg; Lorquet, Jean-Claude

in Journal of Chemical Physics (1977), 66

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See detailNon-adiabatic interactions in unimolecular decay. IV. Transition probability as a function of the Massey parameter
Desouter, Michèle ULg; Lorquet, Jean-Claude

in Journal of Chemical Physics (1979), 71

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See detailNon-adiabatic interactions in unimolecular decay. V. Conical and Jahn-Teller intersections
Desouter, Michèle ULg; Galloy, Claudine; Lorquet, Jean-Claude et al

in Journal of Chemical Physics (1979), 71

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See detailNon-adiabatic interactions in wave packet dynamics of the bromoacetyl chloride photodissociation
Lasorne, Benjamin; Bacchus-Montabonel, Marie-Christine; Vaeck, Nathalie et al

in Journal of Chemical Physics (2004), 120(3), 1271-1278

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See detailNon-adiabatic Pulsational Observables in Scuti and Doradus Stars: a Comparison of Different Numerical Codes
Moya, A.; Garrido, R.; Dupret, Marc-Antoine ULg

in Asteroseismology Across the HR Diagram (2003)

Not Available

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See detailNon-adiabatic pulsations in delta Scuti stars
Moya, A.; Garrido, R.; Dupret, Marc-Antoine ULg

in Stellar Structure and Habitable Planet Finding (2004, January 01)

For delta Scuti stars, phase differences and amplitude ratios between the relative effective temperature variation and the relative radial displacement can be derived from multicolor photometric ... [more ▼]

For delta Scuti stars, phase differences and amplitude ratios between the relative effective temperature variation and the relative radial displacement can be derived from multicolor photometric observations. The same quantities can be also calculated from theoretical non-adiabatic pulsation models. We present here these theoretical results, which indicate that non-adiabatic quantities depend on the mixing length parameter alpha used to treat the convection in the standard Mixing Length Theory (MLT). This dependence can be used to test and to constrain, through multicolor observations, the way MLT describes convection in the outermost layers of the star. We will use the equilibrium models provided by the CESAM evolutionary code. The pulsational observables are calculated by using a non-adiabatic pulsation code developed by R. Garridon and A. Moya. In the evolutionary and pulsation codes, a complete reconstruction of the non-grey atmosphere (Kurucz models) is included. The interaction between pulsation and atmosphere, as described by Dupret et al. (2002), is also included in the code. [less ▲]

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See detailNon-adiabatic seismic study of the thin convective envelope of delta Scuti stars
Dupret, Marc-Antoine ULg; Grigahcène, A.; Garrido, R. et al

in IAU Colloq. 193: Variable Stars in the Local Group (2004, May 01)

For delta Sct stars, the theoretical predictions of a non-adiabatic pulsation code are very dependent on the characteristics of the thin convective envelope of the models (Balona and Evers 1999). The ... [more ▼]

For delta Sct stars, the theoretical predictions of a non-adiabatic pulsation code are very dependent on the characteristics of the thin convective envelope of the models (Balona and Evers 1999). The treatment of the non-adiabatic interaction between convection and pulsation also has a significant impact on the results, particularly near the red edge of the instability strip. The non-adiabatic theoretical predictions can be tested upon observations by comparing them to the amplitude ratios and phase differences as observed in different color passbands (Dupret et al. 2003). In the first part of this paper, we compare the results obtained by adopting different treatments of convection in the interior and atmosphere models: mixing-length theory (MLT) and full spectrum of turbulence (FST) (Canuto et al. 1996, CGM). In the second part, we examine the problem of the interaction between convection and pulsation and compare the mode stability obtained with and without including time-dependent convection in our non-adiabatic code. [less ▲]

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See detailNon-adiabatic seismic study of the triple system DG Leo
Grigahcène, A.; Suárez, J. C.; Dupret, Marc-Antoine ULg et al

in Tidal Evolution and Oscillations in Binary Stars (2005, November 01)

The interest in studying multiple systems comes from the fact that they give a good number of constraints on their components. From the multiplicity we have constraints on mass and age. Moreover, if one ... [more ▼]

The interest in studying multiple systems comes from the fact that they give a good number of constraints on their components. From the multiplicity we have constraints on mass and age. Moreover, if one or more components of the system show oscillating properties as the DG Leo triple system, additional constraints provided by seismology can be obtained once the modes are identified. In this work, we consider an equilibrium model of the DG Leo system constrained by its multiplicity properties, we attempt to check our new Time Depending Convection treatment on the modes identification of the DG Leo system. [less ▲]

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See detailNon-adiabatic theoretical observables in delta Scuti stars
Moya, A.; Garrido, R.; Dupret, Marc-Antoine ULg

in Astronomy and Astrophysics (2004), 414

Phase differences and amplitude ratios at different colour photometric bands are currently being used to discriminate pulsation modes to facilitate mode identification of kappa-driven non-radial pulsating ... [more ▼]

Phase differences and amplitude ratios at different colour photometric bands are currently being used to discriminate pulsation modes to facilitate mode identification of kappa-driven non-radial pulsating stars. In addition to physical inputs (e.g., mass, T_eff, etc.), these quantities depend on the non-adiabatic treatment of the atmosphere. This paper presents theoretical results concerning delta Scuti pulsating stars. The envelope of each of these stellar structures possesses a convection zone whose development is determined by various factors. An interacting pulsation-atmosphere physical treatment is introduced which supplies two basic non-adiabatic physical quantities: the relative effective temperature variation and the phase lag phi[SUP]T[/SUP], defined as the angle between effective temperature variation and radial displacement. These quantities can be used to derive the phase differences and amplitude ratios. Numerivalues for these quantities depend critically on the alpha MLT parameter used to calculate the convection in the envelope. The dependence on alpha was analyzed and it was found that the use of colour observations may be of considerable importance in testing the MLT. Finally, examples are given of how alpha introduces uncertainties in the theoretical predictions regarding phases and amplitudes of photometric variations in delta Scuti pulsating stars. [less ▲]

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See detailNon-adiabatic wave packet dynamics for charge exchange processes in ion-atom collisions: application to C4+ + H
Vaeck, Nathalie; Desouter, Michèle ULg; Liévin, Jacques

in Journal of Physics : B Atomic Molecular & Optical Physics (1999), 32

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See detailNon-alcoholic steatohepatitis.
Luyckx, Françoise ULg; Scheen, André ULg; Lefebvre, Pierre ULg

in Lancet (1999), 354(9186), 1298-9

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See detailNon-alcoholic steatohepatitis: association with obesity and insulin resistance, and influence of weight loss.
Luyckx, Françoise ULg; Lefebvre, Pierre ULg; Scheen, André ULg

in Diabètes & Métabolism (2000), 26(2), 98-106

Non-alcoholic steatohepatitis (NASH) is a disease of emerging identity and importance, and is now considered as one of the commonest liver diseases in western countries. It is frequently associated with ... [more ▼]

Non-alcoholic steatohepatitis (NASH) is a disease of emerging identity and importance, and is now considered as one of the commonest liver diseases in western countries. It is frequently associated with severe obesity, especially abdominal adiposity, and is intimately related to various clinical and biological markers of the insulin resistance syndrome. Especially, both the prevalence and the severity of liver steatosis are related to male sex, body mass index, waist circumference, hyperinsulinaemia, hypertriglyceridaemia and impaired glucose tolerance or type 2 diabetes. A substantial weight loss following gastroplasty is accompanied by a marked reduction in the prevalence and the severity of the various biological abnormalities of the metabolic syndrome and, concomitantly, by an important regression of liver steatosis in most obese patients. However, in some patients, this rapid and drastic weight loss may result in a mild increase in inflammatory lesions (hepatitis), despite the regression of steatosis, which might result from the rapid mobilization of fatty acids or cytokines from adipose tissue, especially visceral fat. The intimate relationship between NASH and obesity leads to the concept that NASH may be considered as another disease of affluence, as is the insulin resistance syndrome and perhaps being part of it. [less ▲]

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See detailNON-ANTHOCYANIN POLYPHENOLS QUANTIFICATION IN EUTERPE OLERACEA FRUITS BY A UHPLC−LTQ-ORBITRAP MS METHOD
Dias, Aecio; Rozet, Eric ULg; Chataigné, G et al

Poster (2013, May)

High antioxidant and anti-inflammatory activities have been observed from non-anthocyanin polyphenols of E. oleracea fruits [1-2]. The aim of this work was to quantify major non-anthocyanin polyphenols by ... [more ▼]

High antioxidant and anti-inflammatory activities have been observed from non-anthocyanin polyphenols of E. oleracea fruits [1-2]. The aim of this work was to quantify major non-anthocyanin polyphenols by an accurate UHPLC−LTQ-Orbitrap MS method. Fruits were harvested in Pará state (Brazil), processed to pulp and lyophilised. 0.5g of dry pulp powder was defatted by sonication with petroleum ether. The residue was then extracted five times with 5mL MeOH each time for 30 min (optimized conditions giving recovery rates > 90%). The extract was evaporated to dryness with a RapidVap® evaporator at 35°C. Solubilization of the dried extract was realised using 40% MeOH. For the UHPLC quantification, a HSS C18 column (1.8µm) was used with a gradient elution of MeOH and H2O both with 0.1% HCOOH and the ionisation source (ESI) was operated in NI mode. 26 compounds were identified, among them 7 identified for the first time in this fruit. Total error and accuracy profiles were used as validation criteria. Calibration in the matrix was found to be more accurate than calibration without matrix. Trueness, repeatability, intermediate precision, selectivity, response function, linearity and LOD/LOQ for 12 non-anthocyanin phenolic compounds were evaluated and the quantification method validated. [1] J. Kang et al., Food Chem. 122 (2010) 610–617. [2] J. Kang et al., Food Chem. 128 (2011) 152–157. [less ▲]

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See detailNon-aqueous capillary electrophoretic enantioseparation of N-derivatized amino acids using cinchona alkaloids and derivatives as chiral counter-ions.
Piette, Véronique; Fillet, Marianne ULg; Lindner, W. et al

in Journal of Chromatography. A (2000), 875(1-2), 353-60

A non-aqueous capillary electrophoretic method developed with quinine and tert.-butyl carbamoylated quinine as chiral selectors for the enantioseparation of N-protected amino acids was applied to the ... [more ▼]

A non-aqueous capillary electrophoretic method developed with quinine and tert.-butyl carbamoylated quinine as chiral selectors for the enantioseparation of N-protected amino acids was applied to the investigation of other quinine derivatives as chiral additives. The optimum composition of the background electrolyte was found to be 12.5 mM ammonia, 100 mM octanoic acid and 10 mM chiral selector in an ethanol-methanol (60:40, v/v) mixture. Under these conditions, a series of chiral acids, as various benzoyl, 3,5-dinitrobenzoyl and 3,5-dinitrobenzyloxycarbonyl amino acid derivatives were investigated with regards to selectand-selector relationships and enantioselectivity employing quinine, quinidine, cinchonine, cinchonidine, tert.-butyl carbamoylated quinine, tert.-butyl carbamoylated quinidine, dinitrophenyl carbamoylated quinine and cyclohexyl carbamoylated quinine as chiral selector. [less ▲]

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See detailA non-canonical caleosin from Arabidopsis efficiently epoxidizes physiological unsaturated fatty acids with complete stereoselectivity
Bléé, Elizabeth; Flenet, Martine; Boachon, Benoit et al

in FEBS Journal (2012), 279

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See detailNon-classical Radiation from Two Atoms and Quantum Search Algorithms
Agarwal, G. S.; von Zanthier, J.; Bastin, Thierry ULg

Conference (2005)

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See detailA Non-Cofactor Role of Thiamine Derivatives in Excitable Cells?
Bettendorff, Lucien ULg

in Archives of Physiology & Biochemistry (1996), 104(6), 745-751

Thiamine diphosphate (TDP) is an important cofactor of pyruvate (PDH) and alpha-ketoglutarate (KGDH) dehydrogenases and transketolase. Thiamine deficiency leads to reversible and irreversible brain ... [more ▼]

Thiamine diphosphate (TDP) is an important cofactor of pyruvate (PDH) and alpha-ketoglutarate (KGDH) dehydrogenases and transketolase. Thiamine deficiency leads to reversible and irreversible brain lesions due to impaired oxidative metabolism. A specific non-cofactor role for thiamine has also been proposed in excitable cells and thiamine triphosphate (TTP) might be involved in the regulation of ion channels. Thiamine is taken up by neuroblastoma cells through a high affinity transporter. Inside the cells, it is rapidly phosphorylated to TDP. This high turnover TDP pool is the precursor for TTP. Most of the TDP however has a low turnover and is associated with PDH and KGDH in mitochondria. In excised inside-out patches from neuroblastoma cells, TTP, at a concentration of 1 microM, activates chloride channels of large unitary conductance, the so-called maxi-Cl- channels. These channels are inhibited by oxythiamine from the outide. In addition to the role of TTP in the regulation of chloride channels, thiamine itself, or a presently unknown analog, may have trophic effects on neuronal cells. [less ▲]

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