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See detailLight-front interpretation of Proton Generalized Polarizabilities
Gorchtein, M.; Lorce, Cédric ULg; Pasquini, B. et al

in Physical Review Letters (2010), 104

We extend the recently developed formalism to extract light-front quark charge densities from nucleon form factor data to the deformations of these quark charge densities when applying an external ... [more ▼]

We extend the recently developed formalism to extract light-front quark charge densities from nucleon form factor data to the deformations of these quark charge densities when applying an external electric field. We show that the resulting induced polarizations can be extracted from proton generalized polarizabilities. The available data for the generalized electric polarizability of the proton yield a pronounced structure in its induced polarization at large transverse distances, which will be pinned down by forthcoming high precision virtual Compton scattering experiments. [less ▲]

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See detailLight-induced gas exchanges in shortly illuminated intact etiolated leaves measured by mass spectrometry
Franck, Fabrice ULg; Peltier, Gilles

in Colloque de Photosynthèse (1986)

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See detailLight-induced Hetero-Diels Alder cycloaddition as a new coupling method to biomolecule radiolabeling
Dammicco, Sylvestre ULg; Luxen, André ULg; Thonon, David et al

Poster (2013, May 16)

The formation of a C-18F bond requires hard conditions which is problematic for the biomolecule radiolabelling. The alternative method which has been developed since a few decades consists in ... [more ▼]

The formation of a C-18F bond requires hard conditions which is problematic for the biomolecule radiolabelling. The alternative method which has been developed since a few decades consists in incorporating the 18F on a prosthetic group and coupling it to the biomolecule. The copper (I)-catalysed 1,2,3-triazole formation involving azides and terminal alkynes is a powerful and rapid method of coupling but present the inconvenient of the employment of cytotoxic reagents. The photoclick conjugation is a promising alternative with no need of catalyst[1]. Recently, a light-induced hetero-Diels Alder cycloaddition involving a 3-(hydroxymethyl)-2-naphthol derivative and an electron-rich olefin has been developed[2]. This reaction seems well adapted for the fast conjugation of radionuclides to biomolecules. Herein we report the synthesis of a [18F]fluoronaphtoquinone derivative as prosthetic group and its reaction with vinyl ethers. [less ▲]

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See detailLight-induced quenching of photosystem II fluorescence at 77 K
Kyle, D. J.; Arntzen, C. J.; Franck, Fabrice ULg et al

in Photochemistry & Photobiology (1983), 38

Light-induced quenching of the low temperature fluorescence emission from photosystem II (PS II) at 695 nm (F695) has been observed in chloroplasts and whole leaves of spinach. Photosystem I (PS I ... [more ▼]

Light-induced quenching of the low temperature fluorescence emission from photosystem II (PS II) at 695 nm (F695) has been observed in chloroplasts and whole leaves of spinach. Photosystem I (PS I) fluorescence emission at 735 nm (F735) is quenched to a lesser degree but this quenching is thought to originate from PS II and is manifest in a reduced amount of excitation energy available for spillover to PS I. Differential quenching of these two fluorescence emissions leads to an increase in the F735/F685 ratio on exposure to light at 77 K. Rewarming the sample from -196°C discharges the thermoluminescence Z-band and much of the original unquenched fluorescence is recovered. The relationship between the thermoluminescence Z-band and the quenching of the low temperature fluorescence emission (F695) is discussed with respect to the formation of reduced pheophytin in the PS II reaction center at 77 K. [less ▲]

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See detail« Le lignage de Guillaume d’Orange dans la tradition italienne : l’exemple du Libro del Povero Avveduto, roman chevaleresque florentin du Quattrocento »
Moreno, Paola ULg

in Moreno, Paola; Palumbo, Giovanni (Eds.) Autour du XVe siècle. Journées d’études en l’honneur d’Alberto Varvaro. Actes du Symposium international L’automne du Moyen Âge. Textes, histoire, iconographie. (2008)

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See detailLes Lignées Climaciques de Wallonie
Hendrickx, Sébastien ULg; Van Der Kaa, Claire ULg

Book published by CPDT (2014)

En lien direct avec la cartographie des climax écosystémiques de la wallonie, réalisée dans le cadre de la recherche d'initiative I4 CPDT ayant pour thème "la biodiversité sous l'angle des dynamiques ... [more ▼]

En lien direct avec la cartographie des climax écosystémiques de la wallonie, réalisée dans le cadre de la recherche d'initiative I4 CPDT ayant pour thème "la biodiversité sous l'angle des dynamiques écosystémiques co-évolutive", cet ouvrage facilite la lecture de celle-ci et la rend opérationnelle. Il rassemble une série de fiches, une par lignée climacique identifiée par la cartographie des climax, qui décrivent ces lignées sur le plan biologique mais également en terme d'occupation et d'affectation du territoire. Elles donnent en outre une analyse de la situation existante pour chaque lignée et des recommandations par rapport aux mesures à mettre en oeuvre pour améliorer celle-ci. [less ▲]

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See detailLignées de carcinome prostatique et apoptose: état de la question
Califice, Stéphane ULg; Waltregny, David ULg; Castronovo, Vincenzo ULg et al

in Revue Médicale de Liège (2004), 59(12), 704-10

Prostate cancer is a major pathology in industrialized countries. Tumor growth usually results from increased cell proliferation, conjugated with an inhibition of programmed cell death (apoptosis). In ... [more ▼]

Prostate cancer is a major pathology in industrialized countries. Tumor growth usually results from increased cell proliferation, conjugated with an inhibition of programmed cell death (apoptosis). In this paper, after a short description of the apoptotic mechanisms and their methods of investigation, we review the present knowledge of the implication of different molecular actors in the regulation of apoptosis in prostate cancer cells. This review notably summarizes the present knowledge of the (de)regulation of the effects of androgens, p53, Bcl-2, Bcl-xL, Bax, Akt, PTEN, Par-4, clusterine, caspases and NF-kappaB in prostate adenocarcinoma cell lines and provides an appraisal of their therapeutic potential. A better knowledge of the apoptotic pathways in these cells could indeed allow the development of new selective and effective anti-cancer strategies. [less ▲]

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See detailLes lignes de force de l'accord interprofessionnel pour 2003-2004
Michiels, Olivier ULg

in Journal du Juriste (2003), 23

Plan: Les dispositions relatives aux groupes à risque et aux jeunes auxquels s'applique un parcours d'insertion; La convention de premier emploi; La prépension; Les cotisations et retenues sur les ... [more ▼]

Plan: Les dispositions relatives aux groupes à risque et aux jeunes auxquels s'applique un parcours d'insertion; La convention de premier emploi; La prépension; Les cotisations et retenues sur les avantages complémentaires. [less ▲]

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See detailLes lignes de force du Code pénal social
Kefer, Fabienne ULg

in Peeters, Johan (Ed.) Het Sociaal Strafwetboek gewikt en gewogen (2011)

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See detailLignes de vie
Tomasovic, Dick ULg

in APCVL (Ed.) Lycéens au cinéma en Région Centre - 2003 (2003)

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See detailLigniculture et maintien de la fertilité des sols dans l'Ouest-Cameroun
Njoukam, Raphaël; Bock, Laurent ULg; Hebert, Jacques ULg et al

in Bois et Forêts des Tropiques (1996), (249), 33-49

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See detailLignin as a raw material for industrial materials applications
Richel, Aurore ULg; Vanderghem, Caroline ULg; Jacquet, Nicolas ULg et al

Poster (2013, October)

Native lignin is an abundant biopolymer on earth and represents 15-30% by weight of the lignocellulosic biomass. Lignin is a heterogeneous cross-linked polymer composed of phenylpropane units (guaiacyl ... [more ▼]

Native lignin is an abundant biopolymer on earth and represents 15-30% by weight of the lignocellulosic biomass. Lignin is a heterogeneous cross-linked polymer composed of phenylpropane units (guaiacyl, syringyl or p-hydroxyphenyl) linked together by a panel of specific ether or carbon-carbon bonds.[1] Nowadays, large amounts of lignins and lignin-based wastes are available and originate either from the pulp and paper manufacturing or from the production of bioethanol from lignocellulose. [2] Typically, these lignins are dedicated to energetic purposes by combustion. In recent years however, novel axes for high added value applications have emerged and concern, notably, the use of lignin as performance products (e.g. polymer additives, binders) or specialty chemicals (e.g. surface-active agents) for materials applications.[3] Herein, several applications of lignin in materials sciences with industrial issues are presented. A correlation is established between the extraction processes from lignocellulosic materials and the chemical structure and physico-chemical properties of lignins.[4] Our research group has also developed new methodologies for the extraction of highly pure lignins from several starting materials, including food wastes, herbaceous raw materials and wood biomass. These methodologies include microwave-assisted extraction and two-step conventional pretreatment involving steam explosion. These methodologies are described in this presentation. [less ▲]

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See detailLignin as a raw material for industrial materials applications
Richel, Aurore ULg; Vanderghem, Caroline ULg; Jacquet, Nicolas ULg et al

Poster (2014)

Native lignin is an abundant biopolymer on earth and represents 15-30% by weight of the lignocellulosic biomass. Lignin is a heterogeneous cross-linked polymer composed of phenylpropane units (guaiacyl ... [more ▼]

Native lignin is an abundant biopolymer on earth and represents 15-30% by weight of the lignocellulosic biomass. Lignin is a heterogeneous cross-linked polymer composed of phenylpropane units (guaiacyl, syringyl or p-hydroxyphenyl) linked together by a panel of specific ether or carbon-carbon bonds.[1] Nowadays, large amounts of lignins and lignin-based wastes are available and originate either from the pulp and paper manufacturing or from the production of bioethanol from lignocellulose. [2] Typically, these lignins are dedicated to energetic purposes by combustion. In recent years however, novel axes for high added value applications have emerged and concern, notably, the use of lignin as performance products (e.g. polymer additives, binders) or specialty chemicals (e.g. surface-active agents) for materials applications.[3] Herein, several applications of lignin in materials sciences with industrial issues are presented. A correlation is established between the extraction processes from lignocellulosic materials and the chemical structure and physico-chemical properties of lignins.[4] Our research group has also developed new methodologies for the extraction of highly pure lignins from several starting materials, including food wastes, herbaceous raw materials and wood biomass. These methodologies include microwave-assisted extraction and two-step conventional pretreatment involving steam explosion. These methodologies are described in this presentation. [less ▲]

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See detailLignin extraction from Mediterranean agro-wastes: Impact of pretreatment conditions on lignin chemical structure and thermal degradation behavior
Manara, Panagiota; Zabaniotou, Anastasia; Vanderghem, Caroline ULg et al

in Catalysis Today (2014), 223

Three different types of Mediterranean, agro-industrial wastes (olive kernels, grape pomace/seeds, peach kernels), were subjected to two pretreatment processes, a chemical/organosolv and a physicochemical ... [more ▼]

Three different types of Mediterranean, agro-industrial wastes (olive kernels, grape pomace/seeds, peach kernels), were subjected to two pretreatment processes, a chemical/organosolv and a physicochemical one. The organosolv process included lignocellulosic biomass treatment with formic acid/acetic acid/water (30/50/20, v/v%), for 3 h at 107 °C, while the physicochemical method was conducted by immersing the biomass in a water/ethanol (8/92, v/v%), H2SO4 0.32 M, solvent and further exposing the slurry to microwave irradiation (maximum 250 W) for 1/2 h at 150 °C. Both processes were evaluated regarding the achieved delignification and the purity of the extracted lignins. The effect of the pretreatment processes onto the structure and thermal decomposition behavior of the extracted lignins was investigated via FT-IR and TGA analysis, respectively. The objective of the research work was to investigate potential valorization routes for these biomass agro-residues in the context of a biorefinery, focusing on lignin extraction. The pretreatment results showed that the obtained lignins, derived from both procedures, were of high purity (>82 wt%). Under the organosolv procedure, peach kernel delignification showed the maximum value (∼16 wt%), while under microwave pretreatment, olive kernel delignification showed the maximum value (∼35 wt%). Grape pomace/seeds appeared to be the most resistant in both treatments. [less ▲]

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See detailLa lignine, une molécule d'intérêt issue du bioraffinage lignocellulosique
Richel, Aurore ULg

Conference (2012, November)

La mise sur pied d’initiatives de bioraffinage lignocellulosique génère des quantités importantes de lignines sous-exploitées. La lignine, l’une des molécules renouvelables les plus abondantes sur terre ... [more ▼]

La mise sur pied d’initiatives de bioraffinage lignocellulosique génère des quantités importantes de lignines sous-exploitées. La lignine, l’une des molécules renouvelables les plus abondantes sur terre, est un biopolymère fortement ramifié constitué d’unités aromatiques. La composition de ce polymère est fortement influencée par la nature du substrat lignocellulosique et par les conditions de cracking appliquées. Généralement destinée à des fins énergétiques, la lignine se voit aujourd’hui ouvrir de nouvelles pistes de valorisation à plus haute valeur ajoutée telles que des applications comme gaz de synthèse, additif dans le secteur de la plasturgie ou comme source de composés aromatiques destinés au secteur chimique. [less ▲]

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See detailLa lignine, une molécule d'intérêt issue du bioraffinage
Richel, Aurore ULg

in Chimie Nouvelle (2012), 111

The implementation of lignocellulosic biorefinery initiatives generates significant amounts of underexploited lignins. Lignin, one of the most abundant renewable molecules on earth, is a highly branched ... [more ▼]

The implementation of lignocellulosic biorefinery initiatives generates significant amounts of underexploited lignins. Lignin, one of the most abundant renewable molecules on earth, is a highly branched biopolymer consisting of aromatic units. Generally intended for energy purposes, lignin has nowadays opened new vistas for higher added-value applications such as syngas, additive in the plastics industry or as a source of aromatic compounds dedicated to the chemical sector. This article provides an update on this molecule and its potential applications. [less ▲]

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See detailLignocellulosic biomass pretreatment impact on the extracted lignins chemical structure
Manara, Panagiota; Zabaniotou, Anastasia; Vanderghem, Caroline ULg et al

Poster (2013, October)

Detailed reference viewed: 25 (6 ULg)