Browsing
     by title


0-9 A B C D E F G H I J K L M N O P Q R S T U V W X Y Z

or enter first few letters:   
OK
Full Text
See detailHydroélectricité et poissons
Ovidio, Michaël ULg; Florence, Hauregard

Learning material (2009)

Chercheur au Laboratoire de Démographie des Poissons et d’Hydroécologie de l’Université de Liège, Michaël OVIDIO présentait le 30 avril dernier, dans le cadre des Jeudis de l’Aquapôle, un exposé sur l’ « ... [more ▼]

Chercheur au Laboratoire de Démographie des Poissons et d’Hydroécologie de l’Université de Liège, Michaël OVIDIO présentait le 30 avril dernier, dans le cadre des Jeudis de l’Aquapôle, un exposé sur l’ « Impact des barrages et des turbinages hydroélectriques sur la dynamique des populations de poissons et la qualité de leurs habitats » . Sans vouloir être source de conflits avec les producteurs d’hydroélectricité, cet exposé avait pour objectif d’informer le grand public sur cette problématique, car la notion d’énergie verte, largement utilisée pour caractériser l’hydroélectricité, ne doit pas s’arrêter au seul aspect des pollutions. [less ▲]

Detailed reference viewed: 209 (31 ULg)
Full Text
Peer Reviewed
See detailHydrogel nanocomposites: a potential UV/blue light filtering material for ophthalmic lenses
Bozukova, Dimitriya; Pagnoulle, Christophe; De Pauw, Marie-Claire ULg et al

in Journal of Biomaterials Science. Polymer Edition (2011), 22

Poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) (poly(HEMA-co-MMA)) and ZnS hydrogel nanocomposites were prepared and characterized. The chemical composition of the inorganic nanoparticles was ... [more ▼]

Poly(2-hydroxyethyl methacrylate-co-methyl methacrylate) (poly(HEMA-co-MMA)) and ZnS hydrogel nanocomposites were prepared and characterized. The chemical composition of the inorganic nanoparticles was confirmed by X-ray diffraction, and the homogeneity of their distribution within the hydrogel was assessed by transmission electron microscopy. The influence of the content of ZnS nanoparticles on the optical performances of the nanocomposites was investigated by UV-Vis spectroscopy. The ability of the hydrogel nanocomposites to filter the hazardous UV light and part of the blue light was reported, which makes them valuable candidates for ophthalmic lens application. In contrast to the optical properties, the thermo-mechanical properties of neat poly(HEMA-co-MMA) hydrogels were found to be largely independent of filling by ZnS nanoparticles ( 2 mg/ml co-monomer mixture). Finally, in vitro cell adhesion test with lens epithelial cells (LECs), extracted from porcine lens crystalline capsule, showed that ZnS had no deleterious effect on the biocompatibility of neat hydrogels, at least at low content. [less ▲]

Detailed reference viewed: 82 (21 ULg)
Full Text
Peer Reviewed
See detailHydrogen atom loss from the benzene cation. Why is the kinetic energy release so large?
Gridelet, E.; Lorquet, Andrée ULg; Locht, Robert ULg et al

in Journal of Physical Chemistry A (2006), 110(27), 8519-8527

The kinetic energy release distributions (KERDs) associated with the hydrogen loss from the benzene cation and the deuterium loss from the perdeuteriobenzene cation have been remeasured on the metastable ... [more ▼]

The kinetic energy release distributions (KERDs) associated with the hydrogen loss from the benzene cation and the deuterium loss from the perdeuteriobenzene cation have been remeasured on the metastable time scale and analyzed by the maximum entropy method. The experimental kinetic energy releases are larger than expected statistically, in contradistinction to what has been observed for the C-X fragmentations of the halogenobenzene cations. H(D) loss from C6H6+ (C6D6+) occurs via a conical intersection connecting the (2)A(2) and (2)A(1) electronic states. Two models are proposed to account for the experimental data: (i) a modified orbiting transition state theory (OTST) approach incorporating electronic nonadiabaticity; (ii) an electronically nonadiabatic version of the statistical adiabatic channel model ( SACM) of Quack and Troe. The latter approach is found to be preferable. It leads to the conclusion that the larger the energy stored in the transitional modes, which partly convert to the relative interfragment motion, the shorter the value of the reaction coordinate at which the adiabatic channels cross, and the larger the probability of undergoing the (2)A(2) -> (2)A(1) transition required for hydrogen loss. [less ▲]

Detailed reference viewed: 45 (5 ULg)
Full Text
Peer Reviewed
See detailA HYDROGEN BOND INFLUENCES THE 5-HT1A/D4 SELECTIVITY OF WAY-100635 ANALOGUES: AN IN SILICO APPROACH
Dilly, Sébastien ULg; Liégeois, Jean-François ULg

Poster (2013, June)

WAY-100635 is widely used in vitro and in vivo as an antagonist of 5-HT1A receptors. In terms of pharmacological tools and pharmacological investigations, the ideal reference molecule would be highly ... [more ▼]

WAY-100635 is widely used in vitro and in vivo as an antagonist of 5-HT1A receptors. In terms of pharmacological tools and pharmacological investigations, the ideal reference molecule would be highly selective for its target over other related and non-related targets. However WAY-100635 displays affinity for and activity at D4 dopamine receptors, and that "off-target" activity confounds its use in pharmacological studies, particularly when both receptors are present. In this context, we carried out various chemical modifications of the WAY-100635 structure in order to improve its 5-HT1A versus D4 selectivity. An important increase of selectivity was obtained when the basic side chain of WAY-100635 was replaced by a 4-phenylpiperazine or a 4-phenyl-1,2,3,6-tetrahydropyridine moiety. In contrast, the introduction of nitrogen atoms in the acyl group decreased the selectivity by reducing the affinity for 5-HT1A receptors, on the one hand, and enhancing the affinity for D4 receptors on the other hand. In order to explain the reduced 5-HT1A/D4 selectivity of aza-derivatives, the binding modes of the compounds were explored by docking analysis on homology models of the two receptors. It appears that the formation of an additional hydrogen bond within D4 receptors could be the key of the decreased selectivity. These results will be very helpful for developing molecules with an improved 5-HT1A/D4 selectivity. [less ▲]

Detailed reference viewed: 18 (2 ULg)
Full Text
See detailThe Hydrogen Electrode in Ionic Liquids: Acidity Measurements and Titrations
Robert, Thierry ULg; Malherbe, Cédric ULg; Magna, lionel et al

Poster (2010, March)

The acidity level in ILs containing acid was first determined using the Hammett acidity function (H0)1-2 in our laboratory. It was demonstrated that this attainable acidity, extending from -3 to -8, is ... [more ▼]

The acidity level in ILs containing acid was first determined using the Hammett acidity function (H0)1-2 in our laboratory. It was demonstrated that this attainable acidity, extending from -3 to -8, is exclusively depending of the nature of anion and follow the order: PF6 > BF4 > NTf2 > OTf. Nevertheless, the Hammett acidity function is an apparent function in this media and must then be corrected for. Consequently, in a second step, we tried to evaluate directly the proton activity from the determination of a potentiometric acidity function (R0) based on the extrathermodynamic Strehlow assumption.3 Therefore, the equilibrium potential of the H+/H2 couple was measured with an hydrogen electrode versus the ferricinium/ferrocene couple for which the potential is considered as independent of the solvent. [less ▲]

Detailed reference viewed: 124 (5 ULg)
Full Text
Peer Reviewed
See detailHydrogen fluoride total and partial column time series above the Jungfraujoch from long-term FTIR measurements: Impact of the line-shape model, characterization of the error budget and seasonal cycle, and comparison with satellite and model data
Duchatelet, Pierre ULg; Demoulin, Philippe ULg; Hase, Frank et al

in Journal of Geophysical Research. Atmospheres (2010), 115

Time series of hydrogen fluoride (HF) total columns have been derived from ground-based Fourier transform infrared (FTIR) solar spectra recorded between March 1984 and December 2009 at the International ... [more ▼]

Time series of hydrogen fluoride (HF) total columns have been derived from ground-based Fourier transform infrared (FTIR) solar spectra recorded between March 1984 and December 2009 at the International Scientific Station of the Jungfraujoch (Swiss Alps, 46.5°N, 8.0°E, 3580 m asl) with two high resolution spectrometers (one home-made and one Bruker 120-HR). Solar spectra have been inverted with the PROFFIT 9.5 algorithm, using the optimal estimation method. An inter-comparison of HF total columns retrieved with PROFFIT and SFIT-2 – the other reference algorithm in the FTIR community - is performed for the first time. The effect of a Galatry line shape model on HF retrieved total columns and vertical profiles, on the residuals of the fits and on the error budget is also quantified. Information content analysis indicates that, in addition to HF total vertical abundance, three independent stratospheric HF partial columns can be derived from our Bruker spectra. A complete error budget has been established and indicates that the main source of systematic error is linked to HF spectroscopy and that the random error affecting our HF total columns does not exceed 2.5%. Ground-based middle and upper stratospheric HF amounts have been compared to satellite data collected by the HALOE or ACE-FTS instruments. Comparisons of our FTIR HF total and partial columns with runs performed by two 3D numerical models (SLIMCAT and KASIMA) are also included. Finally, FTIR and model HF total and partial columns time series have been analyzed to derive the main characteristics of their seasonal cycles. [less ▲]

Detailed reference viewed: 55 (21 ULg)
Full Text
Peer Reviewed
See detailHydrogen in the atmosphere of the evolved WN3 Wolf-Rayet star WR 3: defying an evolutionary paradigm?
Marchenko, S. V.; Moffat, A. F. J.; Crowther, P. A. et al

in Monthly Notices of the Royal Astronomical Society (2004), 353(1), 153-161

WR 3 is the brightest very early-type WN star in the sky. Based on several years of time-resolved spectroscopy and precision photometry on various time-scales, we deduce that WR 3 is most likely a single ... [more ▼]

WR 3 is the brightest very early-type WN star in the sky. Based on several years of time-resolved spectroscopy and precision photometry on various time-scales, we deduce that WR 3 is most likely a single, weak-lined star of type WN3ha (contrary to its current catalogue-type of WN3 + O4), with H lines occurring both in emission and absorption in its wind. This conclusion is confirmed and strengthened via detailed modelling of the spectrum of WR 3. Given the similarity of WR 3 with numerous H-rich WNE stars in the Large Magellanic Cloud and especially the Small Magellanic Cloud, and its location towards the metal-deficient exterior of the Galaxy, we conclude that rotationally induced meridional circulation probably led to the apparently unusual formation of this hot Galactic WN star with enhanced hydrogen. Although we cannot completely rule out the possibility of a binary with a low orbital inclination and/or long period, we regard this latter possibility as highly unlikely. [less ▲]

Detailed reference viewed: 10 (2 ULg)
Full Text
Peer Reviewed
See detailHydrogen Peroxide Hyperpolarizes Rat Ca1 Pyramidal Neurons by Inducing an Increase in Potassium Conductance
Seutin, Vincent ULg; Scuvée-Moreau, Jacqueline ULg; Massotte, Laurent ULg et al

in Brain Research (1995), 683(2), 275-8

It has been suggested that hydrogen peroxide is involved in cascades of pathological events affecting neural cells. The aim of this study was therefore to examine whether this molecule is able by itself ... [more ▼]

It has been suggested that hydrogen peroxide is involved in cascades of pathological events affecting neural cells. The aim of this study was therefore to examine whether this molecule is able by itself to modify membrane properties of pyramidal neurons in the CA1 region of the rat hippocampus. Intracellular recordings in the slice preparation showed that 3.3 mM hydrogen peroxide hyperpolarized all neurons tested (n = 41) by 11 +/- 3 mV. This effect persisted in the presence of tetrodotoxin. It developed slowly, was reversible and reproducible. In the presence of tetrodotoxin, the extrapolated reversal potential of this effect was -95 +/- 5 mV in 2.5 mM external potassium. This value was not significantly different from the one obtained with the GABAB agonist baclofen (10 microM) (-98 +/- 5 mV). It shifted when the concentration of external potassium was increased to 10.5 mM (from -96 +/- 5 to -62 +/- 4 mV), in close agreement with the Nernst equation potassium ions. The hyperpolarization was significantly reduced (by 65 +/- 22%) by the potassium channel blocker barium (100 microM). We suggest that hydrogen peroxide is able to induce an increase in potassium conductance in rat CA1 pyramidal neurons. The exact mechanism by which it produces this effect (direct action on channels or indirect effect) remains to be determined. [less ▲]

Detailed reference viewed: 28 (15 ULg)
Full Text
Peer Reviewed
See detailHydrogen peroxide increases transforming factor-β3 gene expression in human chondrocytes and reverses interleukin-1β inhibitory effect
Mathy-Hartert, Marianne ULg; Devel, P.; Hoormaert, S. et al

in Osteoporosis International (2002, November), 13(Suppl.3), 52

Detailed reference viewed: 9 (2 ULg)
Peer Reviewed
See detailHydrogen peroxyde in breath condensate as marker of lower airway inflammation in an experimental model of feline asthma
Kirschvink, Nathalie; Malin, D.; Delvaux, Francois et al

Conference (2003)

Detailed reference viewed: 5 (0 ULg)
Full Text
Peer Reviewed
See detailHydrogen photo-evolution upon S deprivation stepwise: An illustration of microalgal photosynthetic and metabolic flexibility and a step stone for future biotechnological methods of renewable H2 production
Ghysels, Bart ULg; Franck, Fabrice ULg

in Photosynthesis Research (2010), 106

The metabolic flexibility of some photosynthetic microalgae enables them to survive periods of anaerobiosis in the light by developing a particular photofermentative metabolism. The latter entails ... [more ▼]

The metabolic flexibility of some photosynthetic microalgae enables them to survive periods of anaerobiosis in the light by developing a particular photofermentative metabolism. The latter entails compounds of the photosynthetic electron transfer chain and an oxygen-sensitive hydrogenase in order to reoxidise reducing equivalents and to generate ATP for maintaining basal metabolic function. This pathway results in the photo-evolution of hydrogen gas by the algae. A decade ago Melis and coworkers managed to reproduce such a condition in a laboratory context by depletion of sulfur in the algal culture media, making the photo-evolution by the algae sustainable for several days (Melis et al. 2000). This observation boosted research in algal H2 evolution. A feature, which due to its transient nature was long time considered as a curiosity of algal photosynthesis suddenly became a phenomenon with biotechnological potential. Although the Melis procedure has not been developed into a biotechnological process of renewable H2 generation so far, it has been a useful tool for studying microalgal metabolic and photosynthetic flexibility and a possible step stone for future H2 production procedures. Ten years later most of the critical steps and limitations of H2 production by this protocol have been studied from different angles particularly with the model organism C. reinhardtii, by introducing various changes in culture conditions and making use of mutants issued from different screens or by reverse genomic approaches. A synthesis of these observations with the most important conclusions driven from recent studies will be presented in this review. [less ▲]

Detailed reference viewed: 107 (13 ULg)
Full Text
Peer Reviewed
See detailHydrogen Storage and Carbon Dioxide Capture in an Iron-Based Sodalite-Type Metal-Organic Framework (Fe-BTT) Discovered via High-Throughput Methods
Sumida, Kenji; Horike, S; Kaye, S.S. et al

in Chemical Science (2010), 1

Using high-throughput instrumentation to screen conditions, the reaction between FeCl2 and H3BTT.2HCl(BTT3-=1,3,5-benzenetristetrazolate) in a mixture of DMF and DMSO was found to afford Fe3[(Fe4Cl)3(BTT ... [more ▼]

Using high-throughput instrumentation to screen conditions, the reaction between FeCl2 and H3BTT.2HCl(BTT3-=1,3,5-benzenetristetrazolate) in a mixture of DMF and DMSO was found to afford Fe3[(Fe4Cl)3(BTT)8]2.22DMF.32DMSO.11H2O. THis compound adopts a porous three-dimensional framework structure consisting of squre [Fe4CL]2+ units linked via triangulat BTT3- bridging ligands to give an anionic 3.8-net. Mossbauer spectroscopy carried out on a DMF-solvated version of the material indicated the framework to contain high-spin Fe2+ with a distribution of local environments and confirmed the presence of extra-framework iron cations. Upon soaking the compound in methanol and heating at 135 C for 24 h under dynamic vacuum, most of the solvent is removed to yield Fe3[(Fe4Cl)3(BTT)8(MeOH)4]2(Fe-BTT), a microporous solid with a BET surface area of 2010 m2g-1 and open Fe2+ coordination sites. Hydrogen adsorption data collected at 77 K show a steep rise in the isotherm, associated with an initial isosteric heat of adsorption of 11.9 kJ/mol, leading to a total storage capacity of 1.1 wt% and 8.4 g/L at 100 bar and 298 K. Powder neutron diffraction experiments performed at 4 K under various D2 loadings enabled identification of ten different adsorption sites. with the strongest binding site residing just 2.17(5) Å from the framework Fe2+ cation. Inelastic neutron scattering spectra are consistent with the strong rotational hindering of the H2 molecules at low loadings, and further reveal the catalytic conversion of ortho-H2 to para-H2 by the paramagnetic iron centers. The exposed Fe2+ cation sites within Fe-BTT also lead to the selective adsorption of CO2 over N2, with isotherms collected at 298 K indicating uptake ratios of 30.7 and 10.8 by weight at 0.1 and 1.0 bar, respectively. [less ▲]

Detailed reference viewed: 21 (1 ULg)
Full Text
See detailHydrogen-Deficient Compact Pulsators: The GW Virginis Stars and the Variable DB White Dwarfs
Quirion, P*-O; Dupret, Marc-Antoine ULg; Fontaine, G. et al

in Hydrogen-Deficient Stars (2008, July 01)

We review briefly the basic properties of the GW Vir stars and of the V777 Her stars. We describe the classical kappa-mechanism operating in the GW Vir stars and the effects of the chemical composition ... [more ▼]

We review briefly the basic properties of the GW Vir stars and of the V777 Her stars. We describe the classical kappa-mechanism operating in the GW Vir stars and the effects of the chemical composition and of the interaction between diffusion and mass loss on the boundaries of the instability domain of these objects in the log g - T[SUB]eff[/SUB] diagram. Because of the presence of an extensive superficial convection zone in pulsating DB (V777 Her) white dwarfs, oscillation modes are not excited through a similar classical kappa-mechanism in those stars but, instead, involve pulsation-convection interactions. We describe the effects of a time-dependent convection (TDC) treatment on the driving mechanism of the V777 Her stars. We show how convection deeply affects the excitation of modes via the entropy transport mechanism or S-mechanism. Provisional blue and red edges are calculated for the V777 Her stars and are found at T[SUB]eff[/SUB] ~= 28,500 K and ~= 20,500 K, respectively, for a 0.6 M[SUB]o[/SUB] star under the assumption of ML2 convection. [less ▲]

Detailed reference viewed: 6 (1 ULg)
Full Text
Peer Reviewed
See detailHydrogen-Saturated Silicon Nanowires Heavily Doped with Interstitial and Substitutional Transition Metals
Durgun, E.; Bilc, Daniel ULg; Ciraci, S. et al

in Journal of Physical Chemistry C: Nanomaterials, Interfaces, and Hard Matter (2012), 116

We report a first-principles systematic study of atomic, electronic, and magnetic properties of hydrogen-saturated silicon nanowires (H-SiNW) that are heavily doped by transition metal (TM) atoms placed ... [more ▼]

We report a first-principles systematic study of atomic, electronic, and magnetic properties of hydrogen-saturated silicon nanowires (H-SiNW) that are heavily doped by transition metal (TM) atoms placed at various interstitial and substitutional sites. Our results obtained within the conventional GGA+U approach have been confirmed using a hybrid functional. To reveal the surface effects, we examined three different possible facets of HSiNW along the [001] direction with a diameter of ∼2 nm. The energetics of doping and resulting electronic and magnetic properties are examined for all alternative configurations. We found that except Ti, the resulting systems have a magnetic ground state with a varying magnetic moment. Whereas H-SiNWs are initially nonmagnetic semiconductor, they generally become ferromagnetic metal upon TM doping. They can even exhibit half-metallic behavior for specific cases. Our results suggest that H-SiNWs functionalized by TM impurities form a new type of dilute magnetic semiconductor potentially attractive for new electronic and spintronic devices on the nanoscale. [less ▲]

Detailed reference viewed: 19 (1 ULg)
Full Text
See detailHydrogeological data requirements for assessment of natural attenuation
Haerens, Bruno; Dassargues, Alain ULg

in Proceedings of the National Colloquium CBGI-BCGI ‘Réhabilitation des zones polluées, inventaire, gestion et assainissement / Herinrichting van verontreinigdde zones, inventaris, beheer en sanering (2002)

Detailed reference viewed: 23 (0 ULg)
Full Text
Peer Reviewed
See detailHydrogeological investigations at the Membach station, Belgium, and application to correct long periodic gravity variations
Van Camp, Michel; Vanclooster, Marnik; Crommen, O. et al

in Journal of Geophysical Research (2006), 111(B10),

A comprehensive hydrogeological investigation regarding the influence of variations in local and regional water mass on superconducting gravity measurements is presented for observations taken near the ... [more ▼]

A comprehensive hydrogeological investigation regarding the influence of variations in local and regional water mass on superconducting gravity measurements is presented for observations taken near the geodynamic station of Membach, Belgium. Applying a regional water storage model, the gravity contribution due to the elastic deformation of the Earth was derived. In addition, the Newtonian gravity effect induced by the local water mass variations was calculated, using soil moisture observations taken at the ground surface (about 48 m above the gravimeters). The computation of the gravimetric effect is based on a digital elevation model with spatially discretized rectangular prisms. The obtained results are compared with the observations of a superconducting gravimeter (SG). We find that the seasonal variations can be reasonably well predicted with the regional water storage model and the local Newtonian effects. Shorter-period effects depend on the local changes in hydrology. This result shows the sensitivity of SG observations to very local water storage changes. [less ▲]

Detailed reference viewed: 83 (12 ULg)