Internal dynamics from asteroseismology for two sdB pulsators in close binary systemsVan Grootel, Valérie ; ; et alin Communications in Asteroseismology (2008, December), 157 Since their discovery eleven years ago, short-period pulsating sdB stars have proved their potential for quantitative asteroseismological studies. We have recently updated our astero- seismic diagnostic ... [more ▼] Since their discovery eleven years ago, short-period pulsating sdB stars have proved their potential for quantitative asteroseismological studies. We have recently updated our astero- seismic diagnostic tools in order to incorporate the effects of stellar rotation on pulsations, assuming various internal rotation laws. It is possible, with these new tools, to determine the internal rotation profile of two short-period pulsating sdB stars residing in close binary systems, namely Feige 48 and PG 1336 -018. They exhibit orbital periods of 9.024 h and 2.424 h respectively, as measured from spectroscopy. For the two stars, we show that spin-orbit synchronism is reached from the surface down to ˜ 0.22 R∗ and 0.55 RxE2x88x97 , respectively. The rotation of deeper layers cannot be inferred with the type of modes p-modes observed in short-period pulsating sdB stars. These results can potentially provide new elements to test tidal friction theories, particularly the angular momentum transport, in close binary systems. [less ▲] Detailed reference viewed: 2 (0 ULg) Internal dynamics from asteroseismology for two sdB pulsators residing in close binary systemsVan Grootel, Valérie ; ; et alConference (2008, June) Since their discovery eleven years ago, short-period pulsating sdB stars have proved their potential for quantitative asteroseismological studies. We have recently updated our asteroseismic diagnostic ... [more ▼] Since their discovery eleven years ago, short-period pulsating sdB stars have proved their potential for quantitative asteroseismological studies. We have recently updated our asteroseismic diagnostic tools in order to incorporate the effects of stellar rotation on pulsations, assuming various internal rotation laws. It was possible, with these new tools, to determine the internal rotation profile of two short-period pulsating sdB stars residing in close binary systems, namely Feige 48 and PG 1336−018. They exhibit orbital periods of, respectively, 9.024 h and 2.424 h measured from spectroscopy. For the two stars, we show that spin-orbit synchronism is reached from the surface down to ∼ 0.22 R∗ and 0.55 R∗, respectively. The rotation of deeper layers cannot be inferred with the type of modes observed in short-period pulsating sdB stars. These results could also provide new elements to test tidal friction theories, particularly the angular momentum transport, in close binary systems. [less ▲] Detailed reference viewed: 7 (0 ULg) Internal energy and fragmentation of ions produced in electrospray sourcesGabelica, Valérie ; De Pauw, Edwin ![]() in Mass Spectrometry Reviews (2005), 24(4), 566-587 This review addresses the determination of the internal energy of ions produced by electrospray ionization (ESI) sources, and the influence of the internal energy on analyte fragmentation. A control of ... [more ▼] This review addresses the determination of the internal energy of ions produced by electrospray ionization (ESI) sources, and the influence of the internal energy on analyte fragmentation. A control of the analyte internal energy is crucial for several applications of electrospray mass spectrometry, like structural studies, construction of reproducible and exportable spectral libraries, analysis of non-covalent complexes. Sections II and III summarize the Electrospray mechanisms and source design considerations which are relevant to the problem of internal energy, and Section IV gives an overview of the interrelationships between ion internal energy, reaction time scale, and analyte fragmentation. In these three sections we tried to make the most important theoretical elements understandable by all ESI users, and their understanding requires a minimal background in physical chemistry. We then present the different approaches used to experimentally determine the ion internal energy, as well as various attempts in modeling the internal energy uptake in electrospray sources. Finally, a tentative comparison between electrospray and other ionization sources is made. As the reader will see, although many reports appeared on the subject, the knowledge in the field of internal energy of ions produced by soft ionization sources is still scarce, because of the complexity of the system, and this is what makes this area of research so interesting. The last section presents some perspectives for future research. [less ▲] Detailed reference viewed: 61 (14 ULg) Internal energy build-up in matrix-assisted laser desorption/ionizationGabelica, Valérie ; ; in Journal of Mass Spectrometry [=JMS] (2004), 39(6), 579-593 This paper reports detailed studies on the internal energy of ions formed in matrix-assisted laser desorption/ionization (MALDI) using delayed extraction MALDI-time-of-flight (TOF) and atmospheric ... [more ▼] This paper reports detailed studies on the internal energy of ions formed in matrix-assisted laser desorption/ionization (MALDI) using delayed extraction MALDI-time-of-flight (TOF) and atmospheric pressure (AP) MALDI mass spectrometric (MS) methods. We use benzylpyridinium cations as internal energy probes. Our study reveals three distinct contributions to internal energy build-up in vacuum-MALDI (classical MALDI-TOF), each having different effects on ion fragmentation. Some fragments are formed before ion extraction (i.e. no more than 100 ns after the laser impact), and they are therefore well resolved and recorded as sharp signals in the MALDI-TOFMS scan. This prompt fragmentation can have two origins: (i) in-plume thermal activation, presumably always present, and (ii) in-plume chemical activation, in the course of reactions with hydrogen radicals. In addition to early internal energy build-up associated with these well-resolved promptly formed fragments, a broad peak slightly offset to higher masses could be detected corresponding to fragments formed after the extraction has started. This second signal corresponds to a third source of internal energy in MALDI ions, (iii) the extraction-induced collisional activation of the ions with the neutral components of the plume. These three contributions are difficult to quantify in vacuum-MALDI, because of the combined influence of several parameters (nature of the matrix, spot-to-spot variability, total laser exposure, delay time, acceleration voltage) on extraction-induced fragmentation. AP-MALDI, on the other hand, has two advantages for comparative studies of analyte fragmentation. First, extraction-induced fragmentation is absent, and only the contributions of early plume activation remain. Second, the reproducibility is far better than in vacuum-MALDI. AP-MALDI is therefore expected to shed new light on the early steps of the MALDI process. Copyright (C) 2004 John Wiley Sons, Ltd. [less ▲] Detailed reference viewed: 36 (1 ULg) Internal energy content of ions in a travelling wave ion guideMorsa, Denis ; Gabelica, Valérie ; Rosu, Frédéric et alConference (2010) Travelling wave ion guides (TWIGs) separate of ions according to their mobility and, at constant charge, according to their shape. The ion mobility separation itself should not modify the shape of the ... [more ▼] Travelling wave ion guides (TWIGs) separate of ions according to their mobility and, at constant charge, according to their shape. The ion mobility separation itself should not modify the shape of the systems investigated. It was recently suggested by Shvartsburg et al. that the higher fields used in TWIGs than in traditional drift tubes would cause significant heating of the ions. We present a quantitative analysis of the amount of internal energy imparted to ions as they are separated in TWIGs. Benzylpyridinium ions were chosen as “thermometer” ions. Based on arrival time distributions, the fragment ion population is separated as a function of the place of formation: before, in, or after the TWIG. Fragmentation all along the TWIG was observed. The roles of the travelling wave’s voltage, speed, and of the gas nature and pressure will be discussed in detail as well of the consequences on instruments performances. [less ▲] Detailed reference viewed: 10 (1 ULg) Internal energy of ions in traveling wave ion mobility spectrometry : comparison between Synapt G1 and Synapt G2Morsa, Denis ; Gabelica, Valérie ; De Pauw, Edwin ![]() Poster (2012, May) Detailed reference viewed: 30 (0 ULg) Internal energy of ions inside ion mobility mass spectrometersMorsa, Denis ; Gabelica, Valérie ; De Pauw, Edwin ![]() Conference (2012, April) Detailed reference viewed: 7 (0 ULg) Internal functionalization in hyperbranched polyesters; ; et al in Journal of Polymer Science Part A-Polymer Chemistry (1998), 35(17), 3187-3192 Detailed reference viewed: 11 (4 ULg) The internal market and social rights: friends or foes?Defossez, Alexandre ; Munoz, Rodolphe ![]() in Defossez, Alexandre; Munoz, Rodolphe; El Khadraoui, Said (Eds.) European Union and the Economic Crisis (2011) Analyzing the relationships between the development of the internal market and European social rights faces a major challenge: avoiding caricature. The following example illustrates this point: if, on the ... [more ▼] Analyzing the relationships between the development of the internal market and European social rights faces a major challenge: avoiding caricature. The following example illustrates this point: if, on the one hand, the Laval and Viking cases have rekindled the fear of “social dumping” throughout the Union, on the other hand, the recent developments of European citizenship case law foster the rights of all European citizens. This illustrates that the relationships between the internal market and social rights may rightly be described as “conflicting” or “friendly”, depending the issue at stake and/or the legal basis involved (freedom to provide services versus European citizenship). We’ve therefore decided to focus on what we think are “defining moments” of the relationship between the internal market and the development of social Europe. These choices may appear artificial or incomplete but we think that they encapsulate the basic tension that is going throughout the history of the European Union (EU), since the foundation of the European Economic Community (EEC) to the recent Single Market Act [less ▲] Detailed reference viewed: 39 (2 ULg) Internally Stayed Trusses : The Search for Minimum Weight; Latteur, Pierre ![]() (1999, September) Detailed reference viewed: 14 (0 ULg) Internationaal privaatrecht geannoteerdWautelet, Patrick ; ; et alBook published by La Charte (2012) This collection presents the most important statutory materials useful for the practice in Belgium of private international law. Each instrument (Belgian Acts, European Regulations and International ... [more ▼] This collection presents the most important statutory materials useful for the practice in Belgium of private international law. Each instrument (Belgian Acts, European Regulations and International Conventions in force in Belgium) is reproduced together with comments highlighting the most important case law in relation to the provisions studied. [less ▲] Detailed reference viewed: 13 (1 ULg) Internationaalprivaatrechtelijke aspecten van leasingWautelet, Patrick ![]() in Beselaere, Patrick (Ed.) Handboek leasing (2007) This paper gives a general overview of the legal difficulties raised by the cross-border nature of commercial leasing agreements. The specific focus is on issues of applicable law and jurisdiction and ... [more ▼] This paper gives a general overview of the legal difficulties raised by the cross-border nature of commercial leasing agreements. The specific focus is on issues of applicable law and jurisdiction and also on the particular problems raised by the fact that three parties or more may be involved in the operation. [less ▲] Detailed reference viewed: 44 (2 ULg) The International 4-m Liquid Mirror Telescope ProjectSurdej, Jean ![]() in European Astronomical Society Newsletter (1999), 17 Detailed reference viewed: 13 (7 ULg) International acquisitions and shareholder wealth: evidence from the NetherlandsCorhay, Albert ; in International Review of Financial Analysis (2000), 9(2), 163-174 Detailed reference viewed: 24 (6 ULg) International and European commitments to the export control of nuclear dual-use items: Do the European Union Member States have any room for manoeuvre?Paile, Sylvain ![]() in Cahiers de Sciences Politiques de l'ULg (2013), 26 Detailed reference viewed: 12 (0 ULg) International Arbitration 2009 : BelgiumKohl, Benoît ; in The International Comparative Legal Guide to : International Arbitration 2009 (2009) Detailed reference viewed: 40 (12 ULg) International Arbitration : Should we need specialized construction arbitrators ?Kohl, Benoît ![]() Conference given outside the academic context (2010) Detailed reference viewed: 10 (0 ULg) The International Classification of Headache Disorders, 2nd Edition (ICHD-II)--revision of criteria for 8.2 Medication-overuse headache.; ; et al in Cephalalgia : An International Journal of Headache (2005), 25(6), 460-5 Detailed reference viewed: 30 (4 ULg) International Code of Nomenclature for algae, fungi, and plants (Melbourne Code); ; et al Book published by Koeltz Scientific Books (2012) Règles internationales de nomenclature des algues, champignons et plantes. Nouvelle version. Detailed reference viewed: 46 (0 ULg) An International collaborative study of the Clinical characteristics and Therapeutic Responses in 92 pituitary Adenoma patients with mutations of the Aryl Hydrocarbon Receptor Interacting protein geneDaly, Adrian ; Beckers, Albert ; in 11th International Pituitary Congress : Washington 2009 (2009) Detailed reference viewed: 12 (0 ULg) |
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