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See detailElaboration of degradable PCL-based shape memory materials
Defize, Thomas ULg; Thomassin, Jean-Michel ULg; Alexandre, Michaël et al

Poster (2014, September 02)

Shape memory polymers (SMPs) are smart materials presenting the remarkable property to switch from a temporary shape (stressed) to a permanent shape (relaxed) upon exposure to a stimulus, such as heat or ... [more ▼]

Shape memory polymers (SMPs) are smart materials presenting the remarkable property to switch from a temporary shape (stressed) to a permanent shape (relaxed) upon exposure to a stimulus, such as heat or light. SMPs raised a lot of interest, especially for biomedical applications, for the elaboration of suture wires and stents. In the last few years, biodegradable aliphatic polyesters, typically poly(ɛ-caprolactone) (PCL) and poly(lactide) (PLA) were widely studied for the synthesis of SMPs. This communication aims at reporting a new concept for the synthesis of PCL-based SMPs. In order to meet the increasingly stringent requirements of biomedical applications, a metal-free process is proposed occurring at relatively low temperature, which can be compatible with the presence of a drug during implementation. [less ▲]

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See detailElaboration of drug nanocarriers based on a glucosamine labeled amphiphilic polymer
Boyère, Cédric; Duhem, N; Debuigne, Antoine ULg et al

in Polymer Chemistry (2014), 5(8), 3030-3037

A new functional polymer micelle with high loading efficiency of a poorly soluble drug was made of biocompatible and/or biosourced compounds, i.e. cholesterol-poly(ethylene glycol)-glucosamine (Chol-PEG ... [more ▼]

A new functional polymer micelle with high loading efficiency of a poorly soluble drug was made of biocompatible and/or biosourced compounds, i.e. cholesterol-poly(ethylene glycol)-glucosamine (Chol-PEG-GlcNH2). A synthesis strategy combining enzymatic and metal-free click chemistry was developed in order to meet the increasingly stringent requirements of biomedical applications. After the self-assembly of the Chol-PEG-GlcNH2 amphiphilic polymer in water, the presence of glucosamine at the micelle surface confers an active targeting moiety to the nanocarriers whereas protonation of the peripheral primary amine delay their aggregation. The complete characterization of this novel functional amphiphilic bioconjugate is presented as well as its aqueous solution behaviour and encapsulation efficiency using ketoconazole as a model hydrophobic drug. [less ▲]

Detailed reference viewed: 91 (15 ULg)
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See detailElaboration of Magnetic Nanodots by Nanosphere Lithography : a Computerized Method for Order Quantification
Colson, Pierre ULg; Cloots, Rudi ULg; Henrist, Catherine ULg

Conference (2008, December 01)

Nanosphere lithography (NSL) is an ideal inexpensive fabrication tool for producing regular, nearly homogenous arrays of nanoparticules with different sizes. There are many different methods for the ... [more ▼]

Nanosphere lithography (NSL) is an ideal inexpensive fabrication tool for producing regular, nearly homogenous arrays of nanoparticules with different sizes. There are many different methods for the fabrication of the latex monolayer based on electrophoresis, the controlled evaporation of a solvent from the suspension containing latex particles, spincoating etc… We focused our work on this last method. The main problem with formation of 2D latex monolayers is that there are always a high number of different structural defects such as: point defects (vacancies), line defects (dislocations) and also many disordered areas. The influence of the different spincoating parameters on the amount of defects was determined by image analysis of SEM micrographies from the different samples. FePt and Co films were deposited onto quartz substrates through the polystryrene monolayers by magnetron sputtering. The nanopsheres were removed by sonication in toluene. Post-deposition annealing treatment was performed under reductive atmosphere for the FePt nanodots in order to transform the as-deposited chemically disoredered face-centered cubic (fcc) structure into the chemically ordered face-centered tetragonal (fct) phase (L10-phase). DRX , SEM and MFM analysis were performed on the different samples. [less ▲]

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See detailElaboration of new formulations to remove micropollutants in MSWI flue gas
Brasseur, Alain; Gambin, Amandine; Laudet, Alain et al

in Chemosphere (2004), 56(8), 745-756

This study consists in identifying and testing potential inorganic substitutes to carbon based materials commonly used as adsorbents for the removal of organic pollutants such as dioxins and furans ... [more ▼]

This study consists in identifying and testing potential inorganic substitutes to carbon based materials commonly used as adsorbents for the removal of organic pollutants such as dioxins and furans released from Municipal Solid Waste Incinerators (MSWI). Although carbon materials enable to reach the current regulation in terms of dioxins and furans emissions, they exhibit a potential auto ignition risk when present in hot flue gases. Here, the adsorption potential of carbon based products is compared to the one of some inorganic materials. Chlorobenzene was chosen as a reference molecule to compare the removal performance of the different adsorbents. This comparison was based on the determination of the adsorption energies derived from temperature programmed desorption (TPD) experiments. In the first part of this study, five inorganic materials were selected according to their chlorobenzene adsorption performance compared to those of carbon based products currently used to remove micropollutants from MSWI flue gases. In the second part of the study, the influence of the inlet concentration of adsorbate on the adsorption potential of sorbents is investigated. Actually, the organic compound concentration was decreased in order to be closer to those met in MSWI. Furthermore, the adsorption experiments were performed with other adsorbates whose molecular mass or chlorine content are higher. Thanks to these adsorption results a new organic free formulation has been proposed for the removal of micropollutants. Tests carried out on an industrial scale, demonstrated that this product enables to reach the current norm concerning dioxins and furans emissions. (C) 2004 Elsevier Ltd. All rights reserved. [less ▲]

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See detailElaboration of tantalum oxide and carbon nanotubes composite coatings on titanium for biomaterial applications
Maho, Anthony ULg; Linden, Stéphanie; Arnould, Christelle et al

Poster (2011)

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See detailElaboration of Thin Foils in Copper and Zinc by Self-Induced Ion Plating
Giraud, Eliane; Pace, Sergio ULg; Lecomte-Beckers, Jacqueline ULg

in Materials Science (2014), 20(2), 160-164

The aim of this work was to determine the ability to produce thin metallic foils by self-induced ion plating. Foils of pure copper and pure zinc with a thickness of 35 μm have been successfully produced ... [more ▼]

The aim of this work was to determine the ability to produce thin metallic foils by self-induced ion plating. Foils of pure copper and pure zinc with a thickness of 35 μm have been successfully produced and their characteristics have been compared to foils obtained by conventional techniques (i. e. electroplating and rolling). Results show the following: (i) more or less compact microstructures can be obtained by self-induced ion plating depending on gas pressure and substrate temperature; (ii) microstructures obtained by self-induced ion plating are quite different from those obtained by electroplating and rolling; (iii) Young’s modulus depends on foils roughness; (iv) hardness depends on grain size by exhibiting a Hall-Petch behavior in the case of copper foils and an “inverse” Hall-Petch behavior in the case of zinc foils. [less ▲]

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See detailÉlaborer et utiliser des fix maison sur Aleph
Renaville, François ULg; Richelle, Laurence ULg

Learning material (2011)

À côté de toutes les procédures fix standard appelables via tab_fix, il est possible sur Aleph d'élaborer des fix plus personnalisés (simples ou relativement complexes) permettant aux bibliothèques de ... [more ▼]

À côté de toutes les procédures fix standard appelables via tab_fix, il est possible sur Aleph d'élaborer des fix plus personnalisés (simples ou relativement complexes) permettant aux bibliothèques de modifier, enrichir, corriger, voire supprimer des parties de notices (BIB, HOL, AUT...) en Aleph séquentiel. Également combinables avec tab_expand, ces fix maison peuvent aussi se limiter à l'affichage des données dans le GUI ou l'opac. [less ▲]

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See detailL'élagage des arbres d'alignement : adéquation entre physiologie et économie
Toussaint, André ULg; Kervyn de Meerendre, V.; Delcroix, B. et al

Conference given outside the academic context (2003)

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See detailElargir l’Europe jusqu’où et comment ?
Michel, Quentin ULg

Conference given outside the academic context (2011)

Detailed reference viewed: 56 (4 ULg)
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See detailÉlargissement de la base génétique de la principale espèce de cotonnier cultivé Gossypium hirsutum L. par la création et l’exploitation de lignées monosomiques d’addition
Sarr, D.; Mergeai, Guy ULg

in Biotechnologie, Agronomie, Société et Environnement = Biotechnology, Agronomy, Society and Environment [=BASE] (2009), 13(1), 187-201

Detailed reference viewed: 30 (5 ULg)
See detailElargissement du domaine d'application du règlement thermique wallon
Hauglustaine, Jean-Marie ULg; Vandendries, P.; Wauthy, Y.

Book published by CSTC (1988)

Detailed reference viewed: 11 (0 ULg)
See detailL'élargissement vers la Croatie : un succès de la diplomatie européenne
Lika, Liridon ULg

Article for general public (2013)

Ce 1er juillet 2013, après six années de négociations avec l’Union européenne (UE) et de réformes laborieuses, la Croatie deviendra le 28ème État membre à part entière de la famille européenne. Après la ... [more ▼]

Ce 1er juillet 2013, après six années de négociations avec l’Union européenne (UE) et de réformes laborieuses, la Croatie deviendra le 28ème État membre à part entière de la famille européenne. Après la Slovénie, membre depuis 2004, il s’agit du deuxième pays sortant de la dissolution violente de l’ex-Yougoslavie à rejoindre l’UE. Contrairement à son voisin slovène où les hostilités n’ont duré que quelques jours, la Croatie a connu plusieurs années de guerre et de destruction. Raison pour laquelle elle a été confrontée à une longue période de transition. Depuis son indépendance en 1991, tous les gouvernements croates ont engagé, un processus de consolidation de leur État. Ensuite ils ont consacré leur force à l’adhésion de leur pays à l’Organisation du traité de l’Atlantique Nord (OTAN), concrétisée en 2009, enfin ils ont travaillé à leur entrée dans l’UE. Mais quel intérêt l’Union a-t-elle à voir ces pays la rejoindre ? [less ▲]

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See detailElastase-induced pulmonary emphysema in rats: comparison of computed density and microscopic morphometry.
Onclinx, Cecile; De Maertelaer, Viviane; Gustin, Pascal ULg et al

in Radiology (2006), 241(3), 763-70

PURPOSE: To prospectively compare computed tomographic (CT) quantification of pulmonary emphysema in elastase-treated rats with morphometry and to evaluate the information yielded by CT quantification and ... [more ▼]

PURPOSE: To prospectively compare computed tomographic (CT) quantification of pulmonary emphysema in elastase-treated rats with morphometry and to evaluate the information yielded by CT quantification and pulmonary function tests. MATERIALS AND METHODS: This study was approved by the local committee on care and use of animals in research. Thirty-six animals were used. Emphysema was produced by means of one or two tracheal injections of 300 IU of elastase, 8 weeks apart, in seven and 12 rats, respectively. As a control group, 10 rats received an injection of normal saline. The dynamic resistance, dynamic compliance, and static compliance were measured. CT was performed with 1-mm section thickness and 3-mm intervals. Relative areas of lung with attenuation coefficients lower than nine chosen thresholds (from -900 to -980 HU) and eight percentiles (from 1st to 18th percentiles) of the distribution of attenuation coefficients were compared with measurements of alveoli size--that is, mean interwall distance (MIWD) and mean perimeter per field (MP). Correlations between data obtained with thresholds and percentiles and MIWD and MP were investigated by means of Spearman coefficients (r(s)). Values of pulmonary function tests, most appropriate relative area threshold, and percentile were investigated by means of stepwise multiple regressions. RESULTS: For thresholds, relative surface area with attenuation coefficients less than -940 HU (RA(940)) showed the strongest correlations with findings at microscopy (r(s) = 0.676, P < .001 for MIWD; r(s) = -0.720, P < .001 for MP). For percentiles, the 3rd percentile showed the strongest correlations (r(s) = -0.647, P < .001 for MIWD; r(s) = 0.701, P < .001 for MP). Dynamic compliance and RA(940) or 3rd percentile were complementary for predicting microscopic measurements. CONCLUSION: In rats, RA(940) and the 3rd percentile reflect the extent of elastase-induced pulmonary emphysema and are complementary to dynamic compliance to predict microscopic extent. [less ▲]

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See detailElastic and inelastic transmission in guided atom lasers: A truncated Wigner approach
Dujardin, Julien ULg; Argüelles, Arturo; Schlagheck, Peter ULg

in Physical Review A (2015), 91

We study the transport properties of a Bose-Einstein condensate formed by an ultracold gas of bosonic atoms that is coupled from a magnetic trap into a one-dimensional waveguide. Our theoretical approach ... [more ▼]

We study the transport properties of a Bose-Einstein condensate formed by an ultracold gas of bosonic atoms that is coupled from a magnetic trap into a one-dimensional waveguide. Our theoretical approach to tackling this problem is based on the truncated Wigner method for which we assume the system to consist of two semi-infinite noninteracting leads and a finite interacting scattering region with two constrictions modeling an atomic quantum dot. The transmission is computed in the steady-state regime and we find a good agreement between truncated Wigner and matrix-product state calculations. We also identify clear signatures of inelastic resonant scattering by analyzing the distribution of energy in the transmitted atomic-matter wave beam. [less ▲]

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See detailElastic behaviour of bolted connection between cylindrical steel structure and concrete foundation
Hoang, Van Long ULg; Jaspart, Jean-Pierre ULg; Tran Xuan-Hoang et al

in Journal of Constructional Steel Research (2015), 115

Detailed reference viewed: 65 (12 ULg)