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See detailVacuolar H+-ATPase d2 subunit: molecular characterization, developmental regulation, and localization to specialized proton pumps in kidney and bone.
Smith, Annabel N.; JOURET, François ULg; Bord, Sharyn et al

in Journal of the American Society of Nephrology [=JASN] (2005), 16(5), 1245-56

The ubiquitous multisubunit vacuolar-type proton pump (H+- or V-ATPase) is essential for acidification of diverse intracellular compartments. It is also present in specialized forms at the plasma membrane ... [more ▼]

The ubiquitous multisubunit vacuolar-type proton pump (H+- or V-ATPase) is essential for acidification of diverse intracellular compartments. It is also present in specialized forms at the plasma membrane of intercalated cells in the distal nephron, where it is required for urine acidification, and in osteoclasts, playing an important role in bone resorption by acid secretion across the ruffled border membrane. It was reported previously that, in human, several of the renal pump's constituent subunits are encoded by genes that are different from those that are ubiquitously expressed. These paralogous proteins may be important in differential functions, targeting or regulation of H+-ATPases. They include the d subunit, where d1 is ubiquitous whereas d2 has a limited tissue expression. This article reports on an investigation of d2. It was first confirmed that in mouse, as in human, kidney and bone are two of the main sites of d2 mRNA expression. d2 mRNA and protein appear later during nephrogenesis than does the ubiquitously expressed E1 subunit. Mouse nephron-segment reverse transcription-PCR revealed detectable mRNA in all segments except thin limb of Henle's loop and distal convoluted tubule. However, with the use of a novel d2-specific antibody, high-intensity d2 staining was observed only in intercalated cells of the collecting duct in fresh-frozen human kidney, where it co-localized with the a4 subunit in the characteristic plasma membrane-enhanced pattern. In human bone, d2 co-localized with the a3 subunit in osteoclasts. This different subunit association in different tissues emphasizes the possibility of the H+-ATPase as a future therapeutic target. [less ▲]

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See detailThe vacuum Ultraviolet Photoabsorption and Photoelectron Spectroscopy of Fluoroethylenes. The 1,1-, cis- and trans-C2H2FCl.
Tornow, G.; Locht, Robert ULg; Kaufel, R. et al

in Chemical Physics (1990), 146

The vacuum ultraviolet absorption spectra of the three fluorochloroethene isomers were measured in the 6-13 eV photon energy range. Additionally, the HeI and NeI photoelectron spectra were recorded. The ... [more ▼]

The vacuum ultraviolet absorption spectra of the three fluorochloroethene isomers were measured in the 6-13 eV photon energy range. Additionally, the HeI and NeI photoelectron spectra were recorded. The assignment of the various photoelectron bands is based on MNDO calculations. The vaccum UV absorption spectral features were classified in terms of Rydberg series converging to the first and second ionization energy. Besides the typical pi-pi* transition, other valence transitions were observed and tentatively assigned. In the geminal isomer spectrum the dominant Rydberg series converge to the first ionization limit at 10.02 eV, in the cis and trans isomers the most intense Rydberg transitions converge to the second ionization energy at 11.87 and 12.03 eV respectively. The first ionization energies of these latter compounds, obtained by Rydberg series analysis, are 9.89 and 9.87 eV respectively. An assignment of the vibrational structure observed in both spectra is proposed. [less ▲]

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See detailThe Vacuum UV Photoabsorption Spectra of the three Dichloroethylene Isomers.
Locht, Robert ULg; Leyh, Bernard ULg; Jochims, H.-W. et al

Book published by Berliner Elektronen Speicherring für Synchrotron Strahlung m.b.H (1996)

The vacuum UV photoabsorption spectra of the three isomers of dichloroethylene, as measured with synchrotron radiation, are reported.

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See detailThe Vacuum UV photoabsorption spectroscopy of the geminal ethylene difluoride (1,1-C2H2F2). The vibrational structure and its analysis.
Locht, Robert ULg; Jochims, H.W.; Leyh, Bernard ULg

in Chemical Physics (2012), 405

The vacuum UV photoabsorption spectrum of 1,1-C2H2F2 has been examined in detail between 6 eV and 25 eV photon energy by using synchrotron radiation. The broad band observed at 7.52 eV includes the →∗ and ... [more ▼]

The vacuum UV photoabsorption spectrum of 1,1-C2H2F2 has been examined in detail between 6 eV and 25 eV photon energy by using synchrotron radiation. The broad band observed at 7.52 eV includes the →∗ and the 2b1→3s Rydberg transitions. An analysis is proposed and applied to the fine structure belonging to these transitions. For the (2b1)→∗ transition, one long vibrational progression is observed with ω2=1 475±80 cm-1 combined with one quantum of vibration of ω4= 976±24 cm-1 and its adiabatic excitation energy is determined at 6.742 eV. The 2b1→3s Rydberg transition is characterized by a single progression with ω2=1532±80 cm-1 starting at 6.957 eV. These vibrations are ascribed to the C=C and C-F stretching motions respectively. The abundant structure observed between 8.2 eV and 11.2 eV has been analyzed in terms of vibronic transitions to ns (δ= 0.98) and two different np (δ= 0.50 and 0.31) and nd (δ= 0.13 and 0.044) Rydberg series all converging to the 1,1-C2H2F2+(B1) ionic ground state. An analysis of the associated vibrational structure of the individual Rydberg states has been attempted providing average values of the wavenumbers ω2= 1 549±16 cm-1, ω4= 839±40 cm-1 and ω5= 589±16 cm-1. Eight other Rydberg states were also analyzed. The vacuum UV spectrum of 1,1-C2H2F2 has been recorded for the first time above 11.2 eV and up to 25 eV. Several broad and strong bands are tentatively assigned to transitions to Rydberg states which are members of Rydberg series converging to excited ionic states of 1,1-C2H2F2. For several of these Rydberg states vibrational, structures are observed and assignments are proposed. [less ▲]

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See detailThe Vacuum UV Photoabsorption Spectroscopy of the Three membered Ring Systems C3H6, C2H4O and C2H4S and their open Chain Isomers.
Locht, Robert ULg; Leyh, Bernard ULg; Jochims, H.-W. et al

Book published by Berliner Elektronen Speicherring für Elektronen Synchrotron Strahlung m.b.H - on CD-ROM (2004)

The vacuum UV photoabsorption spectrum of C3H6, C2H4O and C2H4S have been measured using synchrotron radiation and are reported.

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See detailThe Vacuum UV photoabsorption spectroscopy of Vinyl Fluoride (C2H3F): The vibrational fine structure and its analysis.
Locht, Robert ULg; Leyh, Bernard ULg; Dehareng, Dominique ULg et al

in Chemical Physics (2009), 362(3), 97-108

The vacuum UV photoabsorption spectrum of C2H3F has been examined in detail between 6 eV and 25 eV photon energy by using synchrotron radiation. The analysis of the data is supported by ab initio quantum ... [more ▼]

The vacuum UV photoabsorption spectrum of C2H3F has been examined in detail between 6 eV and 25 eV photon energy by using synchrotron radiation. The analysis of the data is supported by ab initio quantum mechanical calculations applied to valence and Rydberg excited states of C2H3F. At 7.6 eV the pi-pi* and the 2a"->3s transitions are observed. An analysis is proposed and applied to the mixed fine structure belonging to these transitions. For the pi->pi* transition one single long vibrational progression is observed with hcwe= 95±7 meV (766±56 cm-1) and its adiabatic excitation energy is 6.892 eV (55 588 cm-1). The 2a"->3s transition is characterized by a single short progression with hc e= 167±10 meV (1 350±80 cm-1)starting at 6.974 eV (56 249 cm-1). From the present ab initio calculations these two wavenumbers best correspond to the vibrational modes v9 (CH2 rock in-plane, FCCbend) and v6 (CH2 rock in-plane, CF stretch) calculated at 615 cm-1 in the pi* state and 1 315 cm-1 in the (2A")3s Rydberg state respectively. The C=C stretching could not be excluded. The dense structured spectrum observed between 8.0 eV and 10.5 eV has been analyzed in terms of vibronic transitions to Rydberg states all converging to the C2H3F+(X2A") ionic ground state. An analysis of the associated complex fine structure of the individual Rydberg states has been attempted providing average values of the wavenumbers, e.g., for the (2A")3p Rydberg state hcw9= 60±1 meV (or 484±8 cm-1), hcw7= 151±7 meV (or 1 218±60 cm-1), hcw4= 191±3 meV (or 1 540±24 cm-1). The assignment of hcw= 105±5 meV (or 823±40 cm-1) is discussed. These experimental values are in good agreement with the theoretical predictions for C2H3F+ [R. Locht, B. Leyh, D. Dehareng, K. Hottmann, H. Baumgärtel, Chem.Phys. (in press)]. Above 10.5 eV and up to 25 eV several broad and strong bands are tentatively assigned to transitions to valence (V-V) and/or Rydberg (V-R) states converging to excited ionic states of C2H3F. [less ▲]

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See detailThe vacuum UV photoabsorption spectrum of methyl bromide (CH3Br) and its perdeuterated isotopomer CD3Br: a Rydberg series analysis
Locht, Robert ULg; Leyh, Bernard ULg; Jochims, H.-W. et al

in Chemical Physics (2005), 317(1), 73-86

The vacuum UV photoabsorption spectrum of CH3Br has been recorded between 6 and 25 eV. A large number of vibronic bands are observed. They were partly ascribed to vibrationless Rydberg transitions. In the ... [more ▼]

The vacuum UV photoabsorption spectrum of CH3Br has been recorded between 6 and 25 eV. A large number of vibronic bands are observed. They were partly ascribed to vibrationless Rydberg transitions. In the high photon energy range of 12-25 eV, very weak diffuse bands are mostly assigned to transitions from the 3a(1), 1e and (2a(1) + 1a(1)) to 3s orbitals. In the 6-12 eV photon energy range, numerous weak to strong bands are observed. The sharpness is very variable over the entire spectral region. In a first step, the interpretation of the spectrum and the assignment of the Rydberg transitions is based on the simple Rydberg formula. The observed features are classified in two groups of four series, each converging to one of the two spin-orbit components of the (X) over tilde E-2 state of CH3Br+. Rydberg series of nsa(1), npa(1), npe, nd and possibly nf characters are observed. The same measurements have been made for the first time on CD3Br in the 6-12 eV photon energy range. The observed features are classified into the same Rydberg series characterized by nearly the same delta values. Ionization energies for CD3Br (X) over tilde (2) E-3/2 at 10.565 eV and (X) over tilde (2) E-1/2 at 10.902 eV are deduced. In a second step, we fitted the experimental data to an energy expression taking into account both the exchange interaction and the spin-orbit coupling. Already states with n = 6 are found to correspond to Hund's case (c). Constant values of the quantum defects are deduced. (C) 2005 Elsevier B.V. All rights reserved. [less ▲]

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See detailThe vacuum UV photoabsorption spectrum of methyl bromide (CH3Br) and its perdeuterated isotopomer CD3Br: a vibrational analysis
Locht, Robert ULg; Leyh, Bernard ULg; Dehareng, Dominique ULg et al

in Chemical Physics (2005), 317(1), 87-102

The fine structure of the vacuum UV photoabsorption spectrum of CH3Br and CD3Br has been analyzed in the 6.9-10.2 eV photon energy range. A large number of lines have been observed, classified and ... [more ▼]

The fine structure of the vacuum UV photoabsorption spectrum of CH3Br and CD3Br has been analyzed in the 6.9-10.2 eV photon energy range. A large number of lines have been observed, classified and assigned to the vibrational excitation accompanying a series of Rydberg transitions. The effects of the Jahn-Teller distortion and of the spin-orbit splitting of the ground electronic state of the ion have been considered. The former effect has been evaluated by ab initio calculations, showing that the E-2 state (in the C-3v symmetry group) splits into (2)A' and (2)A" states in the C-s symmetry group. Even though the energy difference of about 1 meV is extremely small, the (2)A' state is energetically the lowest component whereas the (2)A" is found to be a transition state. The Jahn-Teller stabilization energy and the wavenumbers associated with all vibrational modes have been calculated. Experimentally, the entire fine structure could be described in terms of three vibrational modes, i.e., hc omega(4) = 146 +/- 6 meV (1178 +/- 48 cm(-1)), hc omega(5) = 107 +/- 6 meV (863 +/- 48 cm(-1)) and hc omega(6) = 71 +/- 4 meV (572 +/- 32 cm(-1)), respectively, as resulting from an average over all analyzed Rydberg states. In CD3Br the corresponding energies are hc omega(4) = 104 +/- 3 meV (839 +/- 24 cm(-1)), hc omega(5)=82 +/- 4 meV (661 +/- 32 cm(-1)) and hc omega(6) = 62 +/- 4 meV (500 +/- 32 cm(-1)). These values are in fairly good agreement with those predicted by the present ab initio calculations for the ionic ground state. The experimental isotopic ratio rho(i) = [omega/omega(isot)](i) is 1.15 +/- 0.14, 1.31 +/- 0.14 and 1.39 +/- 1.0 and is predicted to be 1.04, 1.34 and 1.36, respectively, for omega(6), omega(5) and omega(4). On the basis of the present study an alternative assignment of the CH3Br+((X) over tilde E-2) photoelectron band structure is proposed. (C) 2005 Elsevier B.V. All rights reserved. [less ▲]

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See detailThe Vacuum UV Photoabsorption Spectrum of Methyl Chloride (CH3Cl) and its perdeuterated Isotopomer CD3Cl. I. A Rydberg Series Analysis.
Locht, Robert ULg; Leyh, Bernard ULg; Hoxha, A. et al

in Chemical Physics (2001), 272

The vacuum UV photoabsorption spectrum of CH3Cl has been recorded between 6 and 25 eV. A large number of vibronic bands are observed. These were partly ascribed to vibrationless Rydberg transitions. In ... [more ▼]

The vacuum UV photoabsorption spectrum of CH3Cl has been recorded between 6 and 25 eV. A large number of vibronic bands are observed. These were partly ascribed to vibrationless Rydberg transitions. In the higher energy range of 12-25 eV very weak diffuse bands are mostly assigned to transitions from the 3a1, 1e and 2a1 to 3s orbitals. In the 6-12 eV photon energy range, numerous weak to strong bands are observed. The sharpness of the features is very variable over the entire spectral region. In a first step, the interpretation of the spectrum and the assignment of the Rydberg transitions is based on the simple Rydberg formula. The observed features are classified in two groups of four series, each converging to one of the two spin-orbit components of the X2E state of CH3Cl+. Rydberg series of nsa1 (delta=1.069 and 1.064), npa1 (delta= 0.68 and 0.66), npe (delta= 0.438 and 0.427) and nd (delta= -0.040 and -0.092) characters are observed. The same measurements have been made for the first time on CD3Cl in the 6-12 eV photon energy range. The same Rydberg transitions are observed. Analogous series are characterized by about the same delta values: nsa1 (delta= 1.038 and 0.968), npa1 (delta= 0.65 and 0.61), npe (delta= 0.458 and 0.462) and nd (delta= -0.004 and -0.082). Ionization energies for CD3Cl X2E3/2 at 11.320 eV and X2E1/2 at 11.346 eV are deduced. In a second step, we fitted the experimental data for the nsa1 and npa1 states to an energy expression taking into account both the exchange interaction and the spin-orbit coupling. This accounts for the progressive switching from Hund's case (a) to Hund's case (c). [less ▲]

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See detailThe Vacuum UV Photoabsorption spectrum of Methyl Chloride (CH3Cl) and its perdeuterated Isotopomer CD3Cl. II. A vibrational Analysis.
Locht, Robert ULg; Leyh, Bernard ULg; Hoxha, A. et al

in Chemical Physics (2001), 272

The fine structure of the vacuum UV photoabsorption spectrum of CH3Cl and CD3Cl has been analyzed in the 7.5-10.5 eV photon energy range. A large number of lines have been observed, classified and ... [more ▼]

The fine structure of the vacuum UV photoabsorption spectrum of CH3Cl and CD3Cl has been analyzed in the 7.5-10.5 eV photon energy range. A large number of lines have been observed, classified and assigned to vibrational excitation accompanying a series of Rydberg transitions. The vibronic transitions involve both Jahn-Teller distortion and spin-orbit splitting. The former effect has been evaluated by ab initio calculations showing that the 2E state (in the C3v symmetry group) splits into 2A' and 2A" states in the Cs symmetry group. The 2A' state is energetically the lowest component whereas the 2A" is found to be a transition state. The Jahn-Teller stabilisation energy and the wavenumbers associated with all vibrational modes have been calculated. Experimentally, the entire fine structure could be described by using the vibrational modes, i.e. hcomega5= 104+/-7 meV, hcomega6= 77+/-7 meV and homega=162+/-3 meV respectively, as resulting from an average over all the analyzed Rydberg states. In CD3Cl the corresponding energies are hcomega5= 81+/-4 meV, hcomega6= 66+/-5 meV and hcomega= 124+/-4 meV. These values are in good agreement with those predicted by the present ab initio calculations for the ion ground state. However, the agreement is not so good for the wavenumber omega which could be assigned to the nu3 or nu4 vibrational modes. Though some arguments favour nu4 (the CH3 umbrella mode), within the error limits on the present measurements it is formally not possible to ascribe this wavenumber to one of these two vibrations. [less ▲]

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See detailThe Vacuum UV Photoabsorption Spectrum of Methyl Fluoride (CH3F). A vibrational Analysis.
Locht, Robert ULg; Hoxha, A.; Leyh, Bernard ULg et al

Book published by Berliner Elektronen Speicherring für Synchrotron Strahlung m.b.H (1999)

The vacuum photoabsorption spectrum of CH3F has been recorded using synchrotron radiation dispersed at medium resolution. Special data handling has been applied. The vibrational structure of about 70 ... [more ▼]

The vacuum photoabsorption spectrum of CH3F has been recorded using synchrotron radiation dispersed at medium resolution. Special data handling has been applied. The vibrational structure of about 70 features has been analyzed for the first time. [less ▲]

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See detailVade Mecum des bonnes pratiques environnementales
Ozer, Pierre ULg

Learning material (2008)

Trop longtemps, les environnementalistes prédisant les évolutions préoccupantes que sont le réchauffement climatique, la réduction de la biodiversité, l’avancée de l’étendue de zones impropres à ... [more ▼]

Trop longtemps, les environnementalistes prédisant les évolutions préoccupantes que sont le réchauffement climatique, la réduction de la biodiversité, l’avancée de l’étendue de zones impropres à l’adaptation humaine, etc. ont été considérés comme des hâbleurs… Maintenant que leurs prévisions, toujours plus solides scientifiquement, se vérifient au cours des décennies, la société civile leur donne progressivement de plus en plus de crédit. En effet, médias, individus et politiques tiennent compte de leurs mises en garde. Cependant, il appert que la pandémie de polyphagie aiguë reste la principale menace pour l’homo sapiens. Et pour que tous les être humains de la planète ne suivent pas la même démarche autodestructrice, nous n’avons pas d’autres choix que de consommer « moins, mieux et autrement » de manière à optimiser notre relation à la Nature qui nous permet de (sur)vivre. Mais comment mettre en oeuvre des actions respectueuses de l’environnement ? Comment orienter les comportements individuels et collectifs vers un mieux soutenable ? Comment intégrer ces contraintes dans des choix politiques durables sans avoir d’effets collatéraux peu souhaitables ? Comment, finalement, sélectionner les solutions vertueuses adéquates ? Pour répondre – partiellement – à ces questions, l’Université de Liège met ci-après à disposition de la société civile un Vade Mecum des bonnes pratiques environnementales pour réduire notre action négative directe ou indirecte sur notre Terre nourricière. Ce recueil sera alimenté durant toute l’année académique par les résultats de diverses équipes de recherche, toutes disciplines confondues, et a pour objectif de proposer des solutions à différentes strates de la société civile – de l’individu aux politiques internationales – vers un équilibre soutenable entre l’Homme et la Nature. Je tiens ici à remercier vivement les personnes qui ont apporté leur contribution à cette première version, à savoir Mmes Bernadette BABILONE, Marie-Claire DOMASIK-BILOCQ, Bernadette MERENNE-SCHOUMAKER et Vinciane SCHOCKERT ; et MM. Gwénaël DEVILLET, Claude DOPAGNE, Mathieu JASPARD, Roland LIBOIS, Jean MARCHAL, Philippe MATHIEU, André OZER, Francis ROSILLON, Marc SALMON et Claude SCHEUREN. Pour que l’environnement qui nourrira nos enfants ne souffre pas d’emphysème irrémédiable… [less ▲]

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See detailVade-Mecum à l'usage des gestionnaires de mosquée en Région de Bruxelles-Capitale
Husson, Jean-François ULg; De Greef, Christine; Jurfest, Sophie et al

Learning material (2010)

This handbook was elaborated at the request of the Brussels-Capital Region in order to help the administrators of the newly recognised mosques on its territory. It covers the general background of church ... [more ▼]

This handbook was elaborated at the request of the Brussels-Capital Region in order to help the administrators of the newly recognised mosques on its territory. It covers the general background of church-state relations in Belgium and presents more specific aspects (budgeting, accounting, procurements, internal organisation, ...). [less ▲]

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See detailVade-Mecum à l'usage des gestionnaires de mosquées en Région wallonne
Husson, Jean-François ULg; Beckers, Paul; Berger, Cécile et al

Learning material (2011)

Ensuing various ad hoc training sessions organized for mosque administrators with governmental support, this vade mecum is aimed at administrators of officially recognized mosques in Wallonia. It presents ... [more ▼]

Ensuing various ad hoc training sessions organized for mosque administrators with governmental support, this vade mecum is aimed at administrators of officially recognized mosques in Wallonia. It presents the general environment relating to mosques in Wallonia and deals various specific aspects such as recognition procedure, budgets, accounts, public tendering, etc. [less ▲]

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See detailVade-Mecum de la fonction de Bourgmestre
Durviaux, Ann-Lawrence ULg

Book published by La Charte (2009)

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See detailVADE-MECUM des mammites bovines
Durel, Luc; Guyot, Hugues ULg; Theron, Léonard ULg

Book published by MED'COM (2012)

La mammite demeure la pathologie la plus préjudiciable à l'élevage des bovins laitiers. C'est une maladie multifactorielle fortement pénalisante pour l'éleveur: baisse de production, baisse de prix d ... [more ▼]

La mammite demeure la pathologie la plus préjudiciable à l'élevage des bovins laitiers. C'est une maladie multifactorielle fortement pénalisante pour l'éleveur: baisse de production, baisse de prix d'achat du lait, réformes anticipées, frais médicaux... Le lait étant par ailleurs au coeur de l'industrie alimentaire, la question de sa qualité reste primordiale et le vétérinaire a un rôle important à jouer. Ce Vade-Mecum des mammites bovines a pour vocation d'être un outil à la disposition du vétérinaire sur le terrain. Il aidera le praticien à analyser la situation pour laquelle il a été appelé, à proposer des solutions adaptées, tout en communiquant les connaissances nécessaires à l'éleveur pour emporter son adhésion et faire évoluer ses pratiques. L'ouvrage est divisé en 11 chapitres interdépendants explorant de façon approfondie chaque aspect du contrôle de la maladie, en s'appuyant sur les données les plus récentes: caractéristiques des mammites, approche clinique du troupeau, bâtiments, système de traite, alimentation et troubles métaboliques, traite, diagnostic étiologique, traitement en lactation, traitement hors lactation, réformes et gestion du troupeau, ou encore biosécurité. Ce livre raisonné et pragmatique trouvera sa place dans tous les véhicules des praticiens. [less ▲]

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See detailVade-Mecum des marchés publics :entreprise de travaux, de fournitures et de services
Cabuy, Yves; De Koninck, Constant; De Pessemier, Raf et al

Book published by Kluwer (2006)

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See detailVade-mecum sur les stratégies de communication.
Doppagne, Véronique ULg; Hertay, Alain; Seron, Nathalie et al

Learning material (2002)

Ce vade-mecum comprend une introduction présentant les fondements théoriques de la séquence didactique expérimentale (16 pages), une retranscription des extraits-vidéo (9 pages), un dossier d'activités ... [more ▼]

Ce vade-mecum comprend une introduction présentant les fondements théoriques de la séquence didactique expérimentale (16 pages), une retranscription des extraits-vidéo (9 pages), un dossier d'activités (36 pages) et un "carnet de bord" pour les enseignants (12 pages). [less ▲]

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See detailVademecum AESS-CAPAES en sciences de la santé
Henrotin, Yves ULg

Learning material (2007)

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