References of "Abstracts of Papers - American Chemical Society, National Meeting"
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See detailNovel photobioreactors based on microalgae immobilized in silica gels obtained by "Chimie douce" for biofuel production
Léonard, Alexandre ULg; Rooke, J.; Sarmento, H. et al

in Abstracts of Papers - American Chemical Society, National Meeting (2010)

A new generation of photobioreactors for the clean production of green biofuels is described. It is based on the smart combination of living and inanimate, namely microalgae encapsulated in porous silica ... [more ▼]

A new generation of photobioreactors for the clean production of green biofuels is described. It is based on the smart combination of living and inanimate, namely microalgae encapsulated in porous silica gels. Such hybrid materials would allow for the controlled exploitation of photosynthesis to assimilate atmospheric CO2 and convert it into useful energy sources by using sunlight. The use of biocompatible routes for the immobilization of cyanobacteria has extended the duration of survival up to 40 weeks. [less ▲]

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See detailControlled radical polymerization of vinyl monomers catalyzed by ruthenium N-heterocyclic carbene complexes
Demonceau, Albert ULg; Delfosse, Sébastien ULg; Richel, Aurore ULg et al

in Abstracts of Papers - American Chemical Society, National Meeting (2005), 230

As part of our program devoted to the development of new metal-NHC catalyst systems, we have launched a detailed investigation on the catalytic activity of ruthenium-p-cymene complexes bearing NHC ligands ... [more ▼]

As part of our program devoted to the development of new metal-NHC catalyst systems, we have launched a detailed investigation on the catalytic activity of ruthenium-p-cymene complexes bearing NHC ligands for the ring opening metathesis polymerization (ROMP) of cyclic olefins and for the ATRP of vinyl monomers. We report herein on the use for ATRP of [RuCl2(p-cymene)(NHC)] complexes generated in situ by combining the [RuCl2(p-cymene)]2 dimer with an imidazolium salt and a base such as potassium tert-butoxide, cesium carbonate or aluminum isopropoxide. [less ▲]

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See detailAtom-transfer radical polymerization of vinyl monomers mediated by stable ruthenium-carbene complexes.
Demonceau, Albert ULg; Simal, François; Delaude, Lionel ULg et al

in Abstracts of Papers - American Chemical Society, National Meeting (1999), 218(Part 2), 289-

We reported on the exceptional efficacy of new catalytic systems based on well-defined and fully characterized [RuCl2(p-cymene)(PR3)] complexes (p-cymene = 4-isopropyltoluene) to promote the controlled ... [more ▼]

We reported on the exceptional efficacy of new catalytic systems based on well-defined and fully characterized [RuCl2(p-cymene)(PR3)] complexes (p-cymene = 4-isopropyltoluene) to promote the controlled free-radical polymerization of vinyl monomers without cocatalyst activation. It appeared that only phosphines which are both strongly basic and which possess a well-defined steric bulk presented both high catalytic activity and high control of the polymerization process. The most suitable phosphines were triisopropylphosphine and tricyclohexylphosphine (PCy3, Cy = cyclohexyl). Surprisingly, the best catalyst systems for ATRP were also the most active ones for the ring-opening metathesis polymerization (ROMP) of cycloolefins. With this in mind, [RuCl2(=CHPh)(PCy3)2], the Grubbs' ruthenium-carbene complex commonly used for olefin metathesis, was tested and found to be also highly efficient for ATRP. In this paper, we present some studies on the scope and limitations of stable ruthenium-carbene complexes as potential catalysts for the ATRP of vinyl monomers. [less ▲]

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