References of "Spirlet, Jean-Claude"
     in
Bookmark and Share    
Peer Reviewed
See detailMagnetic anisotropy of U2Pd2In
Prokes, Karel; Nakotte, Heinz; Havela, Ladislav et al

in Physica B: Condensed Matter (1996), 223-224

Magnetic susceptibility studies of the U2Pd2In single crystal show that in the paramagnetic state larger χ-values are found for field along the basal plane than along the c-axis. However, below TN = 37 K ... [more ▼]

Magnetic susceptibility studies of the U2Pd2In single crystal show that in the paramagnetic state larger χ-values are found for field along the basal plane than along the c-axis. However, below TN = 37 K, where U-moments form a non-collinear magnetic structure within the basal plane, a cross-over of the two χ-branches occurs. The single crystal results may explain the origin of the exotic magnetization results obtained on powder samples. [less ▲]

Detailed reference viewed: 22 (3 ULg)
Peer Reviewed
See detailHybridization effects in U2T2X compounds: Magnetic structures of U2Rh2Sn and U2Ni2In
Nakotte, Heinz; Purwanto, A.; Robinson, R. A. et al

in Physical Review. B : Condensed Matter (1996), 53(6), 3263-3271

The tetragonal intermetallic compounds U2Ni2In and U2Rh2Sn have been studied by means of specific-heat, electrical-resistivity, and neutron-diffraction techniques. At low temperatures, both compounds ... [more ▼]

The tetragonal intermetallic compounds U2Ni2In and U2Rh2Sn have been studied by means of specific-heat, electrical-resistivity, and neutron-diffraction techniques. At low temperatures, both compounds order antiferromagnetically in a magnetic unit cell doubled along the c axis, and we find 5f moments of 0.60 and 0.38 Bohr magneton/U atom for U2Ni2In and U2Rh2Sn, respectively. For U2Ni2In, our refinement also indicates a possible Ni moment of 0.37 Bohr magneton perpendicular to the U moments. We discuss the development of the 5f moments together with findings on other isostructural U2T2X (T=transition metal, X=In, Sn) compounds, and confirm that the trends expected due to 5f-ligand hybridization also hold for this family of uranium compounds. Our analysis indicates different arrangements of the 5f moments in the two compounds (noncollinear arrangement within the basal plane for U2Ni2In and collinear arrangement along the c axis for U2Rh2Sn), although both compounds have nearest-neighbor U-U distances along the c axis. This would mean that the magnetocrystalline anisotropy in U2T2X compounds is not determined by nearest-neighbor U-U links alone [less ▲]

Detailed reference viewed: 19 (2 ULg)
See detailMagnetic structures of U2Rh2Sn and U2Ni2In
Nakotte, Heinz; Purwanto, A.; Robinson, R. A. et al

Poster (1995, April)

Detailed reference viewed: 9 (0 ULg)
See detailElectrical resistivity and magnetic susceptibility measurements on Np2T2X compounds
Pereira, Laura C.J.; Seret, Alain ULg; Wastin, Frank et al

Poster (1995, April)

Detailed reference viewed: 22 (0 ULg)
Peer Reviewed
See detailMagnetic properties of Np2T2Sn compounds
Sanchez, Jean-Pierre; Colineau, E.; Jeandey, C. et al

in Physica B: Condensed Matter (1995), 206 & 207

The magnetic properties of the Np2T2Sn series investigated by 237Np Mössbauer spectroscopy are reported. Magnetic ordering is shown to occur for T --- Ni, Pd, Pt, whereas the Np ions do not carry a local ... [more ▼]

The magnetic properties of the Np2T2Sn series investigated by 237Np Mössbauer spectroscopy are reported. Magnetic ordering is shown to occur for T --- Ni, Pd, Pt, whereas the Np ions do not carry a local moment when T --- Co, Ru, Rh. Comparisons are made with the corresponding Np2T2In and U2T2Sn compounds. [less ▲]

Detailed reference viewed: 16 (1 ULg)
Peer Reviewed
See detailElectrical resistivity of AnT2Al3 (An = Np, Pu; T = Ni, Pd)
Seret, Alain ULg; Wastin, Franck; Waerenborgh, Joan-Carlos et al

in Physica B: Condensed Matter (1995), 206 & 207

Structural data and resistivity studies of NpNi2Al3, NpxU1−xPd2Al3 (x = 1, 0.5, 0.3, 0.1) and PuPd2Al3 are reported. The resistivity curves display Kondo features and clear anomalies at the magnetic ... [more ▼]

Structural data and resistivity studies of NpNi2Al3, NpxU1−xPd2Al3 (x = 1, 0.5, 0.3, 0.1) and PuPd2Al3 are reported. The resistivity curves display Kondo features and clear anomalies at the magnetic transition. Moreover, at least two kinds of magnetic structure exist in these compounds, one favouring the electrical conductivity and the other decreasing it. [less ▲]

Detailed reference viewed: 29 (4 ULg)
Peer Reviewed
See detailElectronic properties of U2Ni2Sn
Kindo, Koichi; Fukushima, T.; Kumada, T. et al

in Journal of Magnetism & Magnetic Materials (1995), 140-144(2), 1369-1370

We report on the bulk electronic properties of U2Ni2Sn, which crystallizes in the tetragonal U3Si2 structure. Pronounced anomalies in the temperature dependencies of magnetic susceptibility, specific heat ... [more ▼]

We report on the bulk electronic properties of U2Ni2Sn, which crystallizes in the tetragonal U3Si2 structure. Pronounced anomalies in the temperature dependencies of magnetic susceptibility, specific heat and electrical resistivity indicate magnetic ordering below TN = 26 K. An antiferromagnetic ground state is corroborated by the occurrence of three metamagnetic transitions at about 30, 39 and 51 T in the field dependence of the magnetization. The lack of any saturation tendency in the highest field applied (57 T) may suggest further transition(s) to occur in even higher fields. [less ▲]

Detailed reference viewed: 16 (3 ULg)
Peer Reviewed
See detailMagnetism in U2T2X compounds
Havela, Ladislav; Sechovsky, Vladimir; Svoboda, P. et al

in Journal of Magnetism & Magnetic Materials (1995), 140-144(2), 1367-1368

Magnetic and other electronic properties are presented for the U2T2X compounds (T = late transition metal, X = Sn or In), that crystallize in the tetragonal U3Si2-type structure. They show the formation ... [more ▼]

Magnetic and other electronic properties are presented for the U2T2X compounds (T = late transition metal, X = Sn or In), that crystallize in the tetragonal U3Si2-type structure. They show the formation of 5f magnetic moments and antiferromagnetic ordering in compounds where weak 5f-d hybridization is expected. Near the onset of magnetic ordering strongly enhanced γ-values are found. Neutron-diffraction experiments on U2Pd2Sn and U2Pd2In point to a connection between the mutual coordination of U atoms and the type of magnetic anisotropy [less ▲]

Detailed reference viewed: 18 (1 ULg)
Peer Reviewed
See detailHeavy fermion behavior of U2T2X compounds
Havela, Ladislav; Sechovsky, Vladimir; Svoboda, P. et al

in Journal of Applied Physics (1994), 76(10), 6214-6215

Magnetic and specific-heat studies of U2T2X compounds show a frequent occurrence of the gamma enhancement in conjunction with the onset of antiferromagnetic ordering. The largest value of 830 mJ/mol K**2 ... [more ▼]

Magnetic and specific-heat studies of U2T2X compounds show a frequent occurrence of the gamma enhancement in conjunction with the onset of antiferromagnetic ordering. The largest value of 830 mJ/mol K**2 was observed in U2Pt2In, which is nonmagnetic down to 1.2 K. Variations of electronic structure are documented by optimized relativistic LCAO calculation. [less ▲]

Detailed reference viewed: 11 (1 ULg)
Peer Reviewed
See detailMagnetic ordering in U2Pd2In and U2Pd2Sn
Purwanto, A.; Robinson, R. A.; Havela, Ladislav et al

in Physical Review. B : Condensed Matter (1994), 50(10), 6792-6801

The tetragonal intermetallic compounds U2Pd2In and U2Pd2Sn have been studied by means of magnetic susceptibility, magnetization, specific heat, electrical resistivity, and x-ray- and neutron-diffraction ... [more ▼]

The tetragonal intermetallic compounds U2Pd2In and U2Pd2Sn have been studied by means of magnetic susceptibility, magnetization, specific heat, electrical resistivity, and x-ray- and neutron-diffraction techniques. The compounds order antiferromagnetically at 36 and 41 K, respectively, and have enhanced electronic specific-heat coefficients γ of 393 and 203 mJ/mol f.u. K**2, respectively. At low temperature, the nearest-neighbor U-U spacing is along the c axis in both compounds, though in U2Pd2Sn the in-plane U-U distance is shorter at room temperature. This crossover is due to motion of the U atoms within the cell rather than anisotropy of the thermal contraction. It is now well established in several classes of (1:1:1) uranium ternary intermetallic compounds that the strong magnetic anisotropy is correlated with the direction of nearest-neighbor U-U links; the moments are almost invariably oriented perpendicular to such links. This is also the case for U2Pd2In and U2Pd2Sn, where the moments lie in the tetragonal basal plane in a canted arrangement along [110] and [1¯10] directions. Of four such Shubnikov subgroups of P4/mbm, one is clearly preferred by the data. At 10 K, the magnetic moments extracted are (1.6±0.2) Bohr magneton and (2.0±0.1) Bohr magneton per U atom in U2Pd2In and U2Pd2Sn, respectively. [less ▲]

Detailed reference viewed: 15 (1 ULg)
Peer Reviewed
See detailElectronic properties of U2Ni2Sn
Kindo, Koichi; Fukushima, T.; Kumada, T. et al

Poster (1994, August)

Detailed reference viewed: 17 (4 ULg)
Peer Reviewed
See detailHeavy fermion behavior of U2T2X compounds
Havela, Ladislav; Sechovsky, Vladimir; Svoboda, P. et al

Poster (1994, August)

Detailed reference viewed: 15 (3 ULg)
Peer Reviewed
See detailMagnetism in U2T2X compounds
Havela, Ladislav; Sechovsky, Vladimir; Svoboda, P. et al

Poster (1994, August)

Detailed reference viewed: 4 (2 ULg)
Peer Reviewed
See detailHigh-field magnetization of U2T2X compounds (T = Co, Rh, Ni, Pd, Ir, Pt and X = In, Sn)
Nakotte, Heinz; Prokes, Karel; Brück, E. et al

in Physica B: Condensed Matter (1994), 201

Structure parameters and magnetization in quasistatic fields up to 38 T at 4.2 K are reported for U2T2X compounds with T = Co, Rh, Ni, Pd, Ir, Pt and X = In, Sn, which crystalline in the tetragonal U3Si2 ... [more ▼]

Structure parameters and magnetization in quasistatic fields up to 38 T at 4.2 K are reported for U2T2X compounds with T = Co, Rh, Ni, Pd, Ir, Pt and X = In, Sn, which crystalline in the tetragonal U3Si2 structure. Even the highest applied fields are not sufficient to achieve saturation of the magnetization in any of these compounds of which the majority is antiferromagnetic and some are Pauli paramagnets. The importance of 5f-ligand hybridization for the magnetism in these compounds is discussed. [less ▲]

Detailed reference viewed: 24 (1 ULg)
Peer Reviewed
See detailHeavy fermion behavior of U2T2X compounds
Havela, Ladislav; Sechovsky, Vladimir; Svoboda, P. et al

Poster (1994, June)

Detailed reference viewed: 14 (4 ULg)
See detailElectrical resistivity and magnetic susceptibility of NpNi2Al3 and NpPd2Al3
Seret, Alain ULg; Wastin, Frank; Bednarczyk, Eugène et al

Poster (1994, April)

Detailed reference viewed: 15 (1 ULg)
See detailMagnetic ordering in U2Pd2Sn and U2Pd2In
Ladislav, Havela; Svoboda, P.; Purwanto, A. et al

Conference (1994, April)

Detailed reference viewed: 28 (4 ULg)
Peer Reviewed
See detailHigh-field magnetization of U2T2X compounds (T = Co, Ni, Rh, Pd, Ir, Pt and X = In, Sn)
Nakotte, Heinz; Prokes, Karel; Brück, E. et al

Poster (1993, November)

Detailed reference viewed: 25 (1 ULg)
See detailMagnetic properties of U2T2X compounds
Havela, Ladislav; Sechovsky, Vladimir; Nakotte, Heinz et al

Poster (1993, April)

Detailed reference viewed: 27 (1 ULg)