References of "Lambert, Stéphanie"
     in
Bookmark and Share    
Full Text
Peer Reviewed
See detailDevelopment of an easy aqueous sol-gel synthesis for large-scale film deposition methods for the manufacture of coated steel with self-cleaning properties
Mahy, Julien ULg; Léonard, Géraldine ULg; Pirard, Sophie ULg et al

Conference (2016, May 20)

In this work, a global process has been developed to produce at a large scale pure TiO2 films deposited on steel in order to get an easy-to-clean surface. This large scale process implies an easy aqueous ... [more ▼]

In this work, a global process has been developed to produce at a large scale pure TiO2 films deposited on steel in order to get an easy-to-clean surface. This large scale process implies an easy aqueous sol-gel process for the synthesis of the TiO2 sol. This synthesis [1] has been simplified to make easier the extrapolation towards an industrial scale. Results of TEM, photocatalytic properties, film hydrophilicity, and texture obtained with the simplified aqueous sol-gel synthesis (IsoP-TiO2 synthesis) show similar properties than those obtained with the standard aqueous sol-gel synthesis of TiO2 developed previously (HAc-TiO2 synthesis [2]). Only XRD patterns were slightly different with the presence of anatase-brookite phases in IsoP-TiO2 synthesis while anatase phase only was observed in HAc-TiO2 synthesis. Both the aqueous sol-gel synthesis of pure TiO2 and the film deposition on steel by roll-coating have been successfully extrapolated to a larger scale. Indeed, the deposition was done on a pilot line, the steel substrate is 25 cm width, and the band length is 800 m. The coating was deposited at line speed ranging from 30 to 120 m.min-1.The photocatalytic activity and the hydrophilicity of the film were found to be unchanged compared to the films produced at a laboratory scale, thus validating the production of an efficient easy-to-clean material. Even if some problems have still to be solved, this study is a hopeful first step in the development of a large scale process for self-cleaning steel production. [1] S. Mahshid, M. Askari, M.S. Ghamsari, J. Mater. Process. Technol. 189 (2007) 296–300 [2] C.M. Malengreaux, S. Douven, D. Poelman, B. Heinrichs, J.R. Bartlett, J. Sol-Gel Sci. Technol. 71 (2014) 557–570 [less ▲]

Detailed reference viewed: 25 (2 ULg)
See detailNanoparticles and microorganisms applied in groundwater decontamination
Lambert, Stéphanie ULg; Lavigne, Benoît

Conference (2016, May 13)

Detailed reference viewed: 12 (1 ULg)
See detailTailoring γ-Al2O3 supports with specific silicon precursors
Claude, Vincent ULg; Vilaseca, Miriam; Heinrichs, Benoît ULg et al

Poster (2016, May 13)

Detailed reference viewed: 10 (4 ULg)
Full Text
Peer Reviewed
See detailEfficient P- and Ag-doped titania for the photocatalytic degradation of waste water organic pollutants
Bodson, Céline ULg; Heinrichs, Benoît ULg; Tasseroul, Ludivine ULg et al

in Journal of Alloys & Compounds (2016), 682

In this work, physico-chemical properties and photocatalytic activity of three types of dried or dried and calcined TiO2 materials, synthesized by the cogelation method, were studied: (i) a pure TiO2 ... [more ▼]

In this work, physico-chemical properties and photocatalytic activity of three types of dried or dried and calcined TiO2 materials, synthesized by the cogelation method, were studied: (i) a pure TiO2 xerogel ; (ii) TiO2 xerogels doped with Ag ; (iii) TiO2 xerogels co-doped with Ag and P. The presence of silver nanoparticles was observed by transmission electron microscopy (TEM) and the oxidation state of silver after calcination was examined by temperature-programmed reduction (TPR) measurements. The physico-chemical properties of xerogels were characterized by X-ray diffraction (XRD), diffuse reflectance UV-Vis spectroscopy (DR UV-Vis) and from nitrogen adsorption-desorption isotherms. The photocatalytic activity of the samples was quantified for the p-nitrophenol degradation under visible light. [less ▲]

Detailed reference viewed: 40 (9 ULg)
Full Text
Peer Reviewed
See detailFe3+/Iron Oxide/SiO2 Xerogel Catalysts for p-nitrophenol Degradation by Photo-Fenton Effects: Influence of Thermal Treatment on Catalysts Texture
Mahy, Julien ULg; Tasseroul, Ludivine ULg; Herlitscke, Marcus et al

in Materials Today: Proceedings (2016), 3(2), 464-469

Three iron xerogel catalysts were synthesized by hydrolysis and condensation of tetraethoxysilane (TEOS) and 3-(2-aminoethylamino)propyltrimethoxysilane (EDAS) which is able to form a chelate with iron ... [more ▼]

Three iron xerogel catalysts were synthesized by hydrolysis and condensation of tetraethoxysilane (TEOS) and 3-(2-aminoethylamino)propyltrimethoxysilane (EDAS) which is able to form a chelate with iron ions. Four thermal treatments were applied to catalysts: drying, drying-autoclaving, calcination and calcination-autoclaving. Textural characterizations show that the specific surface area is increased by calcination while materials microporosity completely collapse when using autoclaving. Based on Mössbauer spectroscopy and magnetometry measurements, only Fe3+ species were observed in xerogel catalysts. The photo-Fenton effect of these catalysts was evaluated on the degradation of p-nitrophenol in aqueous media. In the presence of H2O2, results show that this effect reachs 99% of degradation after 24 h. Mössbauer and catalytic tests are presented in another paper. [less ▲]

Detailed reference viewed: 53 (30 ULg)
Full Text
Peer Reviewed
See detailDoped sol–gel films vs. powders TiO2: On the positive effect induced by the presence of a substrate
Léonard, Géraldine ULg; Malengreaux, Charline; Melotte, Quentin et al

in Journal of Environmental Chemical Engineering (2016), 4

SiO2 and Ag–SiO2 doped TiO2 films and powders have been produced using a controlled sol–gel process. The dopant has been introduced using an alkoxysilane-functionalized ligand, with or without complexed ... [more ▼]

SiO2 and Ag–SiO2 doped TiO2 films and powders have been produced using a controlled sol–gel process. The dopant has been introduced using an alkoxysilane-functionalized ligand, with or without complexed silver ions. The influence of dopants on physico-chemical properties of the catalysts is studied by XRD, TEM–EDX, DRUV–vis analyses in the case of powders, while GIXRD, XPS, profilometry, UV–vis absorption analyses have been used for thin films. The photocatalytic activity has been evaluated from the degradation of methylene blue under UV-A light in the presence of the different catalysts over a period of 24 h. The detailed comparison between powders and films highlights a surprising positive effect in the case of films due to the presence of the substrate. In the case of photocatalytic powders, the presence of SiO2 or Ag–SiO2 into the TiO2 matrix has a detrimental effect on the photocatalytic activity while the opposite tendency is observed in the case of films, with best activities obtained with Ag–SiO2 doping. Different factors, in particular crystallinity modification between powders and films, have been studied to explain these opposite behaviors. In the case of powders, crystallization is hindered by SiO2 and Ag particles incorporation into the TiO2 matrix, leading to a decrease of the photocatalytic activity. In the case of thin films, probably because of the presence of a substrate, crystallization is not influenced by the presence of SiO2 and Ag particles. Therefore, the latter ones can fully play their role of electron traps leading to an enhanced photocatalytic activity. [less ▲]

Detailed reference viewed: 52 (11 ULg)
Full Text
Peer Reviewed
See detailPhotocatalytic decomposition of hydrogen peroxide over nanoparticles of TiO2 and Ni(II)-porphyrin doped TiO2: a relationship between activity and porphyrin anchoring mode
Tasseroul, Ludivine ULg; Pàez Martinez, Carlos ULg; Lambert, Stéphanie ULg et al

in Applied Catalysis B : Environmental (2016), 182

The nickel tetra(4-carboxyphenyl)porphyrin (TCPPNi) was chimisorbed on Degussa P25 TiO2 at different concentrations. Diffuse reflectance spectroscopy in the UV/vis region, Fourier transform infrared ... [more ▼]

The nickel tetra(4-carboxyphenyl)porphyrin (TCPPNi) was chimisorbed on Degussa P25 TiO2 at different concentrations. Diffuse reflectance spectroscopy in the UV/vis region, Fourier transform infrared spectroscopy and thermal gravimetry combined with differential scanning calorimetry measurements allowed the determination of the TCPPNi anchoring mode. At low TCPPNi concentrations, this anchoring on Degussa P25 TiO2 took place through all four carboxylic groups, while at higher concentrations the anchoring occurred through one or two carboxylic groups. For the firsttime,the effect of UV/vis light irradiation on the H2O2-degradation activity of TiO2 and TCPPNi-doped TiO2 was studied using the method of following the production of O2 by gas pressure monitoring. The activity of seven different catalysts was related to the TCPPNi anchoring mode and the percentage of TiO2 Degussa P25 coverage. An optimum degradation of H2O2 was observed for 0.0115 mol TCPPNi × g−1 P25. In that case, the TCPPNi was anchored through the four carboxylic groups, corresponding to a strong interaction with Degussa P25 TiO2. Moreover, the TCPPNi did not cover the surface completely, therefore allowing the light to reach and activate the TiO2. [less ▲]

Detailed reference viewed: 46 (10 ULg)
Peer Reviewed
See detailEffet du taux de dopage sur l'activité photocatalytique de ZnO dopé par les métaux alcalins
Benhebal, Hadj; Benrabah, Boulem; Léonard, Angélique ULg et al

Conference (2015, October 16)

Detailed reference viewed: 32 (3 ULg)
Full Text
Peer Reviewed
See detailDegradation of p-nitrophenol and bacteria with TiO2 xerogels sensitized in situ with tetra(4-carboxyphenyl)porphyrins
Tasseroul, Ludivine ULg; Lambert, Stéphanie ULg; Eskenazi, David et al

Poster (2015, September 10)

Heterogeneous photocatalysis is widely studied for environmental applications as oxidative processes can completely destroy organic pollutants such as alkanes, pesticides, dyes, etc. and microorganisms ... [more ▼]

Heterogeneous photocatalysis is widely studied for environmental applications as oxidative processes can completely destroy organic pollutants such as alkanes, pesticides, dyes, etc. and microorganisms. The most used photocatalyst is the commercial TiO2 Degussa P25, which is composed of 80% anatase and 20% rutile and which is active when TiO2 is exposed to UV light ( < 380 nm). Recently, several studies have been performed to extend the light absorption range of TiO2 towards the visible range. In this study, TiO2-based materials doped with porphyrins, a widely used dye for the photosensibilization of TiO2, have been prepared using a sol-gel process. To stabilize the TiO2-dye interactions, free metal tetra(4-carboxyphenyl)porphyrin and nickel tetra(4-carboxyphenyl)porphyrin were introduced in situ into the TiO2 matrix during the sol-gel process rather than by grafting. Samples were thoroughly characterized by TEM, X-ray diffraction, FT-IR, DR-UV/Vis and their texture has been examined by nitrogen adsorption–desorption at 77 K. The photocatalytic activity for the degradation of p-nitrophenol and Escherichia coli and Lactobacillus rhamnosus bacteria cells in aqueous medium, under halogen lamp light have been evaluated in relation with the physico-chemical modifications induced by the doping. The low temperature vacuum drying protocol (150°C) used in the present study enabled to obtain porphyrin doped TiO2 xerogels with a high specific surface area, and containing nanoparticles composed of amorphous- and anatase-TiO2. Diffuse reflectance spectroscopy attest the presence of TCPPH2 and TCPPNi within the TiO2 matrix. In a first step, the photoactivity of the xerogels is tested for p-nitrophenol degradation. Results show that crystallinity and nature and concentration of porphyrin introduced in situ have major impact on the degradation performances. In a second step, the best xerogel for p-nitrophenol degradation has been used to degrade bacteria. This xerogel degrades E. coli and L. rhamnosus bacteria cells in less than 48 and 24 h respectively. The photocatalytic degradation of a pollutant is thus correlated to the degradation of bacteria since a xerogel doped with the TCPPNi degrades both p-nitrophenol, E. coli and L. rhamnosus. [less ▲]

Detailed reference viewed: 158 (7 ULg)
Full Text
Peer Reviewed
See detailEthylene polymerization mediated by nickel(II) covalently anchored to silica xerogels
Lambert, Stéphanie ULg; Sacco, Luigi

Conference (2015, September 08)

Heterogeneous catalysis is generally widely preferred for industrial applications thanks to the well-known advantages of easier product-catalyst separation and recovery of the catalyst process and, often ... [more ▼]

Heterogeneous catalysis is generally widely preferred for industrial applications thanks to the well-known advantages of easier product-catalyst separation and recovery of the catalyst process and, often, to the enhanced stability of the catalyst. But in terms of selectivity, homogeneous catalysis usually provides better results. From this point of view, the grafting of homogeneous catalysts onto a solid support seems the ideal combination in order to achieve the advantages of both heterogeneous and homogeneous catalysis, allowing the developing of more environmentally friendly and economical processes with potential application in the industry. Further, to covalently link a homogeneous onto silica (a support which is thermally, chemically and mechanically resistant, with a well defined structure) is the best way to limit metal leaching and sintering. Nitrogen-based ligands containing one of several Schiff bases have been reported to form active catalysts with “late-metal” (such as Fe, Pd, Ni,…) for the ethylene polymerization [1]. Moreover, substituted pyrazole-based organometallic complexes gave also promising results in this field. These facts let us suggest that the pyrazolylpyridine derivatives bearing a tethered trimethoxysilylated group synthesized in a previous work [2] are potentially good candidate to prepare hybrid catalyst (i.e. soluble organometallic complexes covalently bonded onto an insoluble support, in this case silica) with Ni-II, Fe-II or Pd-II for ethylene polymerization. [less ▲]

Detailed reference viewed: 21 (2 ULg)
Full Text
Peer Reviewed
See detailTailoring γ-Al2O3 supports with specific silicon precursors
Claude, Vincent ULg; Vilaseca, Miriam; Lambert, Stéphanie ULg

Poster (2015, September)

Detailed reference viewed: 19 (0 ULg)
Full Text
See detailNi-Cu/SiO2 cogelled xerogel catalysts for selective hydrodechlorination of 1,2-dichloroethane into ethylene
Lambert, Stéphanie ULg

Conference (2015, August 13)

Hydrodechlorination of chlorinated organics is a particularly attractive alternative compared with incineration of wastes from the chlorine industry from both economic and environmental points of view ... [more ▼]

Hydrodechlorination of chlorinated organics is a particularly attractive alternative compared with incineration of wastes from the chlorine industry from both economic and environmental points of view. Several authors demonstrated the ability of bimetallic catalysts, composed of metals from Groups VIII and IB, to convert chlorinated alkanes selectively into less or not chlorinated alkenes. The purpose of this study is to measure catalytic activity and selectivities of 1,2-dichloroethane hydrodechlorination over Ni-Cu/SiO2 cogelled xerogel catalysts and to study relationships between catalytic activity and surface properties of bimetallic catalysts. To understand the mechanism of hydrodechlorination of 1,2-dichloroethane on a supported alloy, the surface composition of Ni-Cu alloy is measured from H2 chemisorption, XRD and TEM. Values obtained indicate a very pronounced surface enrichment with copper. Samples containing various amounts of nickel and copper are xerogels prepared by a one-step sol-gel procedure, which consists in the cogelation of the silica precursor, tetraethoxysilane (TEOS), with organically substituted alkoxides capable of forming chelates with nickel and copper ions. The resulting alcogels were dried under vacuum at 80°C, calcined in air at 400°C, and finally reduced in hydrogen at 450°C. For each catalytic experiment, 0.11 g of catalyst pellets were tested. The temperature was successively kept at 200, 250, 300, 350 and 300°C. While 1,2-dichloroethane hydrodechlorination over pure nickel mainly produces ethane, increasing copper content in bimetallic catalysts results in an increase in ethylene selectivity. Used alone, copper deactivates rapidly due to their covering by chlorine atoms. When nickel is present, it supplies hydrogen atoms for the regeneration of the chlorinated copper surfaces into metallic copper. The specific consumption rate of 1,2-dichloroethane decreases when copper loading increases. The turnover frequency, that is, the number of catalytic cycle per active site (nickel atom and its surrounding copper atoms) and per second, seems to be independent of surface composition of alloy particles. [less ▲]

Detailed reference viewed: 42 (0 ULg)
Full Text
Peer Reviewed
See detailPhotocatalytic Oxidative Treatment of Waste Water contamined with Pharmaceutical Products
Vreuls, Christelle; Wilmot, Annick; Cludts, Marc et al

Poster (2015, July)

Detailed reference viewed: 43 (4 ULg)
Full Text
Peer Reviewed
See detailDevelopment by the sol–gel process of highly dispersed Ni–Cu/SiO2 xerogel catalysts for selective 1,2-dichloroethane hydrodechlorination into ethylene
Pirard, Sophie ULg; Mahy, Julien ULg; Pirard, Jean-Paul ULg et al

in Microporous and Mesoporous Materials (2015), 209

Ni–Cu/SiO2 xerogel catalysts have been synthesized by cogelation of industrial tetraethoxysilane (Dynasil) and chelates of Ni and Cu with industrial 3-(2-aminoethylamino)propyltrimethoxysilane (Dynasylan ... [more ▼]

Ni–Cu/SiO2 xerogel catalysts have been synthesized by cogelation of industrial tetraethoxysilane (Dynasil) and chelates of Ni and Cu with industrial 3-(2-aminoethylamino)propyltrimethoxysilane (Dynasylan DAMO) in industrial ethanol denatured with diethyl phthalate. Despite the use of industrial grade reagents, highly dispersed bimetallic Ni–Cu/SiO2 xerogel catalysts were obtained. These samples are composed of completely accessible Ni–Cu alloy crystallites with sizes of 1.6–3.4 nm located inside silica particles exhibiting a monodisperse microporous distribution. It appears that the bimetallic complex acts as a nucleation agent in the formation of silica particles. The combination of results obtained from the calculation of the metal ratio in catalysts, H2 chemisorption and transmission electron microscopy allowed calculating the surface composition of the nickel–copper particles in Ni–Cu/SiO2 cogelled xerogel catalysts. Values obtained indicate a very pronounced surface enrichment with copper. While 1,2-dichloroethane hydrodechlorination over pure nickel mainly produces ethane, increasing copper content in bimetallic catalysts results in an increase in ethylene selectivity. The specific consumption rate of 1,2-dichloroethane decreases when copper loading increases. The turnover frequency, that is, the number of catalytic cycle per active site (nickel atom and its surrounding copper atoms) and per second, seems to be independent of surface composition of alloy particles. [less ▲]

Detailed reference viewed: 401 (79 ULg)
Full Text
Peer Reviewed
See detailCatalytic epuration of biogaz
Claude, Vincent ULg; Toye, Dominique ULg; Heinrichs, Benoît ULg et al

Poster (2015, May 08)

Detailed reference viewed: 17 (3 ULg)
Full Text
Peer Reviewed
See detailEffect of iron nanoparticles synthesized by a sol-gel process on Rhodococcus erythropolis T902.1 for biphenyl degradation
Wannoussa, Wissal ULg; Masy, Thibaut ULg; Lambert, Stéphanie ULg et al

in Journal of Water Resource and Protection (2015), 7

Nanoparticles (NPS) are considered as a new generation of compounds to improve environmental remediation and biological processes. The aim of this study is to investigate the effect of iron NPS ... [more ▼]

Nanoparticles (NPS) are considered as a new generation of compounds to improve environmental remediation and biological processes. The aim of this study is to investigate the effect of iron NPS encapsulated in porous silica (SiO2) on the biphenyl biodegradation by Rhodococcus erythropolis T902.1 (RT902.1). The iron NPS (major iron oxide FexOy form) were dispersed in the porosity of a SiO2 support synthesized by sol-gel process. These Fe/SiO2 NPS offer a stimulating effect on the biodegradation rate of biphenyl, an organic pollutant that is very stable and water-insoluble. This positive impact of NPS on the microbial biodegradation was found to be dependent on the NPS concentration ranging from 10−6 M to 10−4 M. After 18 days of incubation the cultures containing NPS at a concentration of 10−4 M of iron improved RT902.1 growth and degraded 35% more biphenyl than those without NPS (positive control) or with the sole SiO2 particles. Though the microorganism could not interact directly with the insoluble iron NPS, the results show that about 10% and 35% of the initial 10−4 M iron NPS encapsulated in the SiO2 matrix would be incorporated inside or adsorbed on the cell surface respectively and 35% would be released in the supernatant. These results suggest that RT902.1 would produce siderophore-like molecules to attract iron from the porous silica matrix. [less ▲]

Detailed reference viewed: 178 (95 ULg)